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71.
72.
Pan Huang Dawen Xu Robert M. Reich Felix Kaiser Boping Liu Fritz E. Kühn 《Tetrahedron letters》2019,60(24):1574-1577
A first example of an Et2Zn mediated silylation of 1-aklynes is reported. A series of functional groups are tolerated in this reaction. Mechanistic studies support Zn alkynilides as intermediates in the reaction. This reaction protocol provides a practical method for the preparation of alkynylsilanes and expands the application of organometallic zinc in organic synthesis. 相似文献
73.
W. L. Liang B. K. A. Ngoi L. E. N. Lim K. Venkatakrishnan C. W. Hee 《Optics & Laser Technology》2003,35(4):285-290
In this paper, integration of interference phenomenon into femtosecond laser micromachining was reported as the femtosecond laser pulses were reshaped spatially to perform ablation. The generation of circular interference pattern was demonstrated by overlapping infrared femtosecond laser pulses. The interference pattern was subsequently focused on a copper substrate to ablate microstructures of concentric circular rings. The present technique is expected to open up new applications in the areas of rapid fabrication of micro-Fresnel lenses, hybrid microlenses and lens arrays. 相似文献
74.
A combination of 1,3-dihalo-5,5-dimethylhydantoin (X = Br, Cl) and sodium nitrite in the presence of wet SiO2 was used as an effective nitrosating agent for the nitrosation of N,N-dialkyl amines to their corresponding nitroso derivatives under mild and heterogeneous conditions in good to excellent yields. 相似文献
75.
The paper discusses the applicability of quasi-crystalline approximation to describing the thermal motion of water molecules in their normal and supercooled states. The problem is subjected to the critical analysis of experimental data on incoherent scattering of slow neutrons based on theories developed by Singwi-Sjolander [1] and Oskotsky [2] modified to duly take into account the limited applicability range of diffusion approximation. The applicability conditions of quasi-crystalline approximation are shown to be consistently satisfied only when water is in supercooled state and within a narrow temperature range above the melting temperature. 相似文献
76.
D. J. Plazek C. A. Bero S. Neumeister G. Floudas G. Fytas K. L. Ngai 《Colloid and polymer science》1994,272(11):1430-1438
By making creep and recoverable creep measurements of a nearly monodisperse low molecular weight poly(methyl phenyl siloxane) sample, we have found on decreasing temperature towardsT
g that there is continuously a change in the viscoelastic spectrum concomitant with a decrease of the steadystate recoverable compliance. This behavior is exactly the same as previously observed in low molecular weight poly(styrene), proving that this spectacular anomaly in the viscoelasticity of low molecular weight polymers is general and deserves an explanation. Photon correlation spectroscopic measurements performed on the same sample have extended the observation of the viscoelastic response to shorter times and the result corroborates the trend of variation established by the creep data.Dedicated to Prof.Dr. E. W. Fischer on his 65th Birthday. Prof.Dr. Fischer is known for his valuable contribution to fosterine, international collaboration of research in polymer science. This work is an example of his contribution because it would not be possible without him bringing us together. One of us (KLN) would like to take this opportunity to thank Prof. Dr. Fischer for his unwaiving support of the 1st (Crete) and the 2nd (Alicante) International Discussion Meeting on Relaxations in Complex Systems 相似文献
77.
Experimental data on the effect of thallium and sodium impurities on the lattice heat conductivity of PbTe at room temperature
are reported. Because the lattice of lead chalcogenides is strongly polarized near charged impurities, the effect of impurities
on the lattice heat conductivity depends substantially on their charge state. This property of the material has been used
to determine the charge state of the thallium impurity in PbTe. The results obtained argue for a model of quasi-local thallium-impurity
states which assumes low electron-correlation energy at an impurity center.
Fiz. Tverd. Tela (St. Petersburg) 40, 1206–1208 (July 1998) 相似文献
78.
P. Seelig A. Dax S. Faber M. Gerlach G. Huber T. Kühl D. Marx P. Merz W. Quint F. Schmitt H. Winter M. Würtz 《Hyperfine Interactions》1998,114(1-4):135-139
The investigation of the 1s HFS provides a good possibility for testing QED effects in a combination of a strong electric
and magnetic field. Here, we report about the laserspectroscopic measurements of the ground state hyperfine splitting in 207Pb81+. To handle this M1-transition in the infrared optical regime with its long lifetime, we developed a new detection technique
using a bunched ion beam. For the observation of fluorescence light, a new mirror system is adapted to the emission characteristics
from an ion beam at relativistic velocities.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
79.
E. Jackiewicz M. Lukasiak M. Kopcewicz K. Szpila N. Bakun-Czubarow 《Hyperfine Interactions》1992,70(1-4):993-996
Terrestrial basalt rocks considered to be a good analogues of the Martian regolith were studied by using the Mössbauer spectroscopy and X-ray diffraction. The weathering of basalts was followed by the changes of the Fe2+/Fe3+ ratio. The basalt rock undergoes alteration from primary mineral composition (olivine+pyroxene+plagioclase) through smectite to kaolinite clay with oxides and hydroxides with the increase of the Fe2+/Fe3+ ratio. 相似文献
80.
The three-band two-dimensional repulsive Hubbard model in the formalism of the temperature Green function is investigated.
The applicability of the weak coupling approach at the values of the dimensionless coupling constant U/t≈10–11 is justified.
The normal state, the antiferromagnetic state with Neel magnetic ordering on the “copper” sublattice, and the superconducting
state with nontrivial Cooper pairing in channels with odd angular momenta are studied. The possibility of other magnetic states
in the model is discussed. Bibliography: 20 titles.
Translated fromZapiski Nauchnykh Seminarov POMI, Vol. 209, 1994, pp. 194–228.
Translated by K. Malyshev. 相似文献