原子相干态中的压缩现象

计算表明,与场的相干态类似的原子相干态,具有不同于场的相干态的压缩行为;进一步证明:直接类比于(?)(ξ)不能得到“原子压缩算符”.     

离子色谱法测定蓝藻培养液中有机酸和无机阴离子

建立了一种利用阴离子交换色谱柱分离,电导检测器同时测定17种有机酸和7种阴离子的方法。采用Ionpac AS11-HC阴离子交换柱,KOH溶液作为淋洗液,梯度洗脱,流量为1.0mL/min,柱温为30℃,进样体积为25μL。24种分析物测定结果的相对标准偏差在0.31%~2.67%之间,线性相关系数均大于0.996,平均加标回收率在80.3%~108.5%之间。该方法可用于微生物培养液中有机酸和阴离子的同时测定。     

Nonlinear dynamics in a Fabry-Perot resonator

We develop a general formalism to describe the dynamical behavior of an ensemble of two-level systems in a Fabry-Perot cavity. Our main result is a set of space and time-dependent, integro-differential equations for the slowly varying radiation and atomic variables, which we derive through a precise analysis of the slowly-varying amplitude approximation in the presence of counter-propagating fields. With the help of new and properly chosen variables we recast these equations in a form that makes their boundary conditions formally identical to those of an ideal Fabry-Perot resonator, and introduce in a natural way a modal structure even for systems with arbitrary mirror reflectivity. We derive simplified forms of these equations in the uniform field limit and within the more general single-frequency approximation. Finally, we extend our formulation to include driven systems such as optically bistable devices and the laser with an injected signal.     

Light intensity correlation measurements in the presence of multiple scattering

We discuss the results of a model calculation of the intensity correlation function for multiply scattered light and compare our analytic predictions with experiments.     

Transverse effects in superfluorescence

We demonstrate that off-axial emission can be responsible for the pulse envelope ringing, transverse effects, and large shot-to-shot pulse shape fluctuations observed in recent superfluorescence experiments.     

Generation of highly directional beams from a globally incoherent source

We have carried out a series of observations of the far field intensity distribution produced by a class of partially coherent planar sources. Our results confirm that, under the Collett-Wolf quasi-homogeneity conditions, highly directional beams can be produced even from a source which is globally incoherent. The far-zone pattern is shown to be largely independent of the intensity profile in the source plane and that the beam radius varies as predicted by Foley and Zubairy in the paraxial approximation. We show experimentally how the coherence length in the source plane can be measured directly from the far zone intensity distribution.     

氮氧自由基研究:XXI,水溶液中哌啶氮氧自由基单电子还原反应机理的极谱研究

本文采用取样直流极谱, 常规脉冲极谱, 微分脉冲极谱和交流极谱考察了,2,2,6,6-四甲基-4-羟基哌啶 -1-氧和2,2,6,6-四甲基-4-氧哌啶 -1-氧由基及2,2,6,6-四甲基哌啶 -1-氧自由基在水溶液中的还原反应, 并研究了它们的还原经历电化学过程 。     

一类单完备李代数

确定了代数Va,b.c的导子代数,其中Va.b.c是由非交换代数Ca,b,c[X±1,Y±1,Z±1]的所有内导子所张成的李代数,证明了导子代数数Va.b,c是由所有内导子和3个外导子D1,0,0,DO,1,0,D0,0,1张成的,同时还给出了一类无限维的单完备李代数.     

Directed synthesis of noncentrosymmetric molybdates using composition space analysis

A systematic investigation of the factors governing the reaction product composition, hydrogen bonding, and symmetry was conducted in the MoO3/3-aminoquinuclidine/H2O system. Composition space analysis was performed through 36 individual reactions under mild hydrothermal conditions using racemic 3-aminoquinuclidine. Single crystals of three new compounds, [C7H16N2][Mo3O10] x H2O, [C7H16N2]2[Mo8O26] x H2O, and [C7H16N2]2[Mo8O26] x 4 H2O, were grown. The relative phase stabilities for these products are dependent upon the reactant mole fractions in the initial reaction gel. This phase stability information was used to direct the synthesis of two new noncentrosymmetric compounds, using either (S)-(-)-3-aminoquinuclidine dihydrochloride or (R)-(+)-3-aminoquinuclidine dihydrochloride. [(R)-C7H16N2]2[Mo8O26] and [(S)-C7H16N2]2[Mo8O26] both crystallize in the noncentrosymmetric space group P2(1) (No. 4), which has the polar crystal class 2 (C2). The second-harmonic generation activities were measured on sieved powders. The structure-directing properties of the molybdate components in each compound were determined using bond valence sums. The structures of all five compounds were determined using single-crystal X-ray diffraction.     

Geometric preferences in iron(II) and zinc(II) model complexes of peptide deformylase

A combination of experimental and theoretical studies on (N,S(thiolate))M(II)-formate complexes (M = Fe, Zn) suggests a rationale for the metal ion dependence of peptide deformylase.