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781.
Nomura M Nakamura M Soeda R Kikawada Y Fukushima M Oi T 《Isotopes in environmental and health studies》2012,48(3):434-438
Vanadium (V) in the sea squirt (Ciona savignyi) from Onagawa Bay, Miyagi, Japan, was isolated and purified through adsorption on a diamine resin and anion and cation exchanges after the dissolution of sea squirt samples with nitric acid and hydrogen peroxide. The (50)V/(51)V isotope ratio of V thus obtained was mass-spectrometrically determined to be from 2.51×10(-3) to 2.55×10(-3) with the average of 2.53×10(-3) by the thermal ionisation technique. This value agreed with those of vanadyl chloride and vanadyl nitrate both prepared from vanadyl sulphate (Wako Pure Chemical Industries, Ltd., Japan) and of V in coastal seawater (Shimokita Peninsula, Aomori, Japan) within experimental uncertainties (standard deviation of±0.04), which suggested that no appreciable V isotope fractionation occurs accompanying V uptake by the sea squirt from sea water. 相似文献
782.
Matsukuma D Yamamoto K Aoyagi T 《Langmuir : the ACS journal of surfaces and colloids》2006,22(13):5911-5915
To develop stimuli-responsive ultrathin polymer films on a solid substrate, a novel photo-cross-linkable polymer with both temperature- and pH-responsive properties was prepared. The photoreactive 4-aminobenzophenone (BP) was introduced onto the side groups of poly(N-isopropylaclylamide-co-2-carboxyisopropylaclylamide) [poly(NIPAAm-co-CIPAAm)]. This copolymer was designed for highly random sequences of comonomers. After the formation of spin-coated polymer films on a solid substrate, UV-light irradiation started the cross-linking reaction. The spin-coating processes and stability of the polymer films were quantitatively monitored by a quartz crystal microbalance (QCM), and the thickness was estimated using an atomic force microscope (AFM). These measurements confirmed the formation of a very plain polymer film, and the film thickness was precisely controlled by the concentration of the polymer solution used for spin coating. Moreover, the obtained films showed a high stability due to the cross-liking reaction and UV irradiation. Cyclic voltammetry using potassium ferricyanide revealed that the ions could permeate the photo-cross-linked ultrathin polymer films. The permeability of the ultrathin hydrogel films was dramatically changed by varying the pH and temperature of the aqueous media. These observations suggest that the preparation of isopropylacrylamide-based stimuli-responsive ultrathin hydrogel films is possible. 相似文献
783.
Takeshi Suzuyama Hiroki Yamamoto Masakazu Ito Takao Nakama Shoichi Nagata 《Journal of solid state chemistry》2006,179(1):140-144
Ferromagnetic-phase transition in spinel-type CuCr2Te4 has been clearly observed. CuCr2Te4 is a telluride-spinel with the lattice constant , which has been synthesized successfully. The heat capacity exhibits a sharp peak due to the ferromagnetic-phase transition with the Curie temperature . This value of TC corresponds exactly to that of the negative peak of dM/dT in low field of 1.0 Oe. The magnetic susceptibility shows the Curie-Weiss behavior between 380 and 650 K with the effective magnetic moment /Cr-ion and the Weiss constant . The low temperature magnetization indicates the spin-wave excitations, where the existence of first term of Bloch T3/2 law and the next T5/2 term are verified experimentally. This spin-wave excitation is detected up to approximately 250 K which is a fairly high temperature. 相似文献
784.
785.
Vassão DG Gang DR Koeduka T Jackson B Pichersky E Davin LB Lewis NG 《Organic & biomolecular chemistry》2006,4(14):2733-2744
Propenyl- and allyl-phenols, such as methylchavicol, p-anol and eugenol, have gained importance as flavoring agents and also as putative precursors in the biosynthesis of 9,9'-deoxygenated lignans, many of which have potential medicinal applications. In spite of several decades of investigation, however, the complete biosynthetic pathway to a propenyl/allylphenol had not yet been reported. We have subjected a Thai basil variety accumulating relatively large amounts of the simplest volatile allylphenol, methylchavicol, to in vivo administration of radiolabeled precursors and assays of protein preparations in vitro. Through these experiments, the biosynthesis of chavicol was shown to occur via the phenylpropanoid pathway to p-coumaryl alcohol. Various possibilities leading to deoxygenation of the latter were examined, including reduction of the side-chain double bond to form p-dihydrocoumaryl alcohol, followed by dehydration to afford chavicol, as well as formation of p-methoxycinnamyl alcohol, with further side-chain modification to afford methylchavicol. A third possibility studied was activation of the side-chain alcohol of p-coumaryl alcohol, e.g.via esterification, to form a more facile leaving group via reductive elimination. The latter was shown to be the case using p-coumaryl esters as potential substrates for a NAD(P)H-dependent reductase to afford chavicol, which is then O-methylated to afford methylchavicol. 相似文献
786.
Takao Watanabe 《Archiv der Mathematik》2006,87(4):320-329
Let V be a vector space over a global field k, g an element of the adele group
and Hg the twisted height defined on the k-subspaces of V . We show that the square root of the generalized Hermite-Rankin constant for k gives the best upper bound of the function
, where
runs over all m-dimensional k-subspaces of V and
runs over all n-dimensional k-subspaces of
.
Received: 17 June 2005 相似文献
787.
Koike S Takahashi H Yonezawa H Takei N Braunstein SL Aoki T Furusawa A 《Physical review letters》2006,96(6):060504
We demonstrate unconditional telecloning for the first time. In particular, we symmetrically and unconditionally teleclone coherent states of light from one sender to two receivers, achieving a fidelity for each clone of F = 0.58 +/- 0.01, which surpasses the classical limit. This is a manipulation of a new type of multipartite entanglement whose nature is neither purely bipartite nor purely tripartite. 相似文献
788.
Okyay AK Nayfeh AM Saraswat KC Yonehara T Marshall A McIntyre PC 《Optics letters》2006,31(17):2565-2567
We demonstrate extremely efficient germanium-on-silicon metal-semiconductor-metal photodetectors with responsivities (R) as high as 0.85 A/W at 1.55 microm and 2V reverse bias. Ge was directly grown on Si by using a novel heteroepitaxial growth technique, which uses multisteps of growth and hydrogen annealing to reduce surface roughness and threading dislocations that form due to the 4.2% lattice mismatch. Photodiodes on such layers exhibit reverse dark currents of 100 mA/cm2 and external quantum efficiency up to 68%. This technology is promising to realize monolithically integrated optoelectronics. 相似文献
789.
Fujii K Fujimori T Takamuku T Kanzaki R Umebayashi Y Ishiguro S 《The journal of physical chemistry. B》2006,110(16):8179-8183
The structure of bis(trifluoromethanesulfonyl) imide (TFSI-) in the liquid state has been studied by means of Raman spectroscopy and DFT calculations. Raman spectra of 1-ethyl-3-methylimidazolium (EMI+) TFSI- show relatively strong bands arising from TFSI- at about 398 and 407 cm(-1). Interestingly, the 407 cm(-1) band, relative to the 398 cm(-1) one, is appreciably intensified with raising temperature, suggesting that an equilibrium is established between TFSI- conformers in the liquid state. According to DFT calculations followed by normal frequency analyses, two conformers of C2 and C1 symmetry, respectively, constitute global and local minima, with an energy difference 2.2-3.3 kJ mol(-1). The wagging omega-SO2 vibration appears at 396 and 430 cm(-1) for the C1 conformer and at 387 and 402 cm(-1) for the C2 one. Observed Raman spectra over the range 380-440 cm(-1) were deconvoluted to extract intrinsic bands of TFSI- conformers, and the enthalpy of conformational change from C2 to C1 was evaluated. The enthalpy value is in good agreement with that obtained by theoretical calculations. We thus conclude that a conformational equilibrium is established between the C1 and C2 conformers of TFSI- in the liquid EMI+TFSI-, and the C2 conformer is more favorable than the C1 one. 相似文献
790.
Hasegawa Y Okada Y Kataoka T Sakata T Mori H Wada Y 《The journal of physical chemistry. B》2006,110(18):9008-9011
EuS nanoparticles were synthesized by the thermal reduction of single source precursor (SSP), (PPh4)[Eu(S2CNEt2)4].2H2O, under microwave irradiation. The average size of the EuS nanoparticles was found to be 8 nm (3-16 nm in size). The organic products on the EuS surface were observed by using FT-IR, NMR, and MS analyses. We have found that these are resulted from the chemical reactions of SSP and cover the nanocrystal surface. A thermal reaction of SSP gave EuS nanoparticles and the organic product (*SCN(Et)2). The organic product would make a dimmer, (Et)2NC(S)-(S)CN(Et)2, by the couping of the radicals formed in the thermal reaction and/or thiopolymer in the solution through the polymerization of the radicals. The effective surface modification by the organic products led to protection of the EuS surface, resulting in the formation of the strongly luminescent EuS nanoparticles at room temperature (emission peak = 350 nm, fwhm = 58 nm, emission quantum yield = 27 +/- 5%). 相似文献