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91.
92.
In this article, we consider the maximum cocliques of the 211: M24 ‐graph Λ. We show that the maximum cocliques of size 24 of Λ can be obtained from two Hadamard matrices of size 24, and that there are exactly two maximum cocliques up to equivalence. We verify that the two nonisomorphic designs with parameters 5‐(24,9,6) can be constructed from the maximum cocliques of Λ, and that these designs are isomorphic to the support designs of minimum weights of the ternary extended quadratic residue and Pless symmetry [24,12,9] codes. Further, we give a new construction of Λ from these 5‐(24,9,6) designs. © 2009 Wiley Periodicals, Inc. J Combin Designs 17: 323–332, 2009 相似文献
93.
Koji Ishizu Naoyuki Kobayakawa Satoshi Takano Yoko Tokuno Masaaki Ozawa 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1771-1777
The crosslinked polystyrene particles possessing photofunctional N,N‐diethyldithiocarbamate groups on their surface were prepared by free‐radical emulsion copolymerization of a mixture of styrene, divinylbenzene and 4‐vinylbenzyl N,N‐diethyldithiocarbamate with redox system as an initiator under UV irradiation. In this copolymerization, the inimer 4‐vinylbenzyl N,N‐diethyldithiocarbamate acted the formation of hyperbranched structures by living radical photopolymerization. The particle sizes (number‐average particle diameter = 214–523 nm) were controlled by varying the feed amount of surfactant and size distributions were relatively narrow. Subsequently, core–shell particles were synthesized by photoinduced atom transfer radical polymerization approach of methyl methacrylate initiated by photofunctional polystyrene particles as a macroinitiator. Such core–shell particles were stabilized sterically by grafted chains in organic solvents. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1771–1777, 2007 相似文献
94.
Dr. Naoyuki Toriumi Kazuya Yamashita Prof. Dr. Nobuharu Iwasawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(49):12635-12641
A metal-free photoredox-catalyzed hydrodefluorination of fluoroarenes was achieved by using N,N,N’,N’-tetramethyl-para-phenylenediamine ( 1 ) as a strong photoreduction catalyst. This reaction was applicable not only to electron-rich monofluoroarenes but also to polyfluoroarenes to afford non-fluorinated arenes. The experimental mechanistic studies indicated that the amide solvent NMP plays an important role for regeneration of the photocatalyst, enabling additive-free photoreduction catalysis. 相似文献
95.
Through the analyses on the irreversibility lines (ILLs) under H||c for various high-Tc superconducting (HTSC) single-crystalline samples, we found two universal functions representing ILLs. In these functions, the electromagnetic anisotropy factor γ2 plays a crucial role. The appropriate chemical substitution, such as Bi(Pb)2212, is an effective method to improve flux pinning properties via decreasing γ2. 相似文献
96.
S. Horii M. Yamaki H. Ogino T. Maeda J. Shimoyama 《Physica C: Superconductivity and its Applications》2010,470(20):1056-1059
We report the grain-orientation effects under a modulated rotation magnetic field for Y-based cuprate superconductors and LaFeAsO (La1111). Tri-axial orientation has been successfully achieved only for orthorhombic Y2Ba4Cu7Oy and YBa2Cu4O8 powders without a twin microstructure, while separation of three crystallographic axes could not be observed in twinned YBa2Cu3Oy (Y123) and tetragonal La1111 powders. The morphology of grains, in addition to the symmetry of crystal structures, seriously affects the degrees of tri-axial orientation, which means that the control of twin microstructures is required for the tri-axial magnetic orientation in Y123. 相似文献
97.
98.
The solubilities and selectivities for CO2, N2 and CH4 in ionic liquid were predicted using a COSMO based activity coefficient model, COSMO-SAC method. The 1-alkyl-3-methylimidazolium cations were focused in this work. The anion species include tetrafluoroborate [BF4], hexafluorophosphate [PF6], triflate [OTf], dicyanamide [dca] and bis(trifluoromethane)-sulfonimide [Tf2N]. The predicted results of the solubilities of CO2 in the ionic liquids by COSMO-SAC method are in agreement with the experimental data within the averaged deviation of 0.0017 in mole fraction. The predicted results of selectivities for CO2/N2 and CO2/CH4 represent the effects of anion species qualitatively. Permeability through supported liquid membrane can be presented by solubility and diffusion coefficients in the liquid. The permeabilities of CO2 through the ionic liquid membranes were also predicted by a solution-diffusion model with COSMO-SAC method. The predicted results of the CO2 permeabilities through the ionic liquids represent the experimental data within the order of the permeabilities. 相似文献
99.
Masahiro Kikuchi Mohammad S. Hussain Norio Morishita Mitsuko Ukai Yasuhiko Kobayashi Yuhei Shimoyama 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2010,75(1):310-313
An electron spin resonance (ESR) spectroscopic study of radicals induced in irradiated fresh mangoes was performed. Mangoes in the fresh state were irradiated with γ-rays, lyophilized and then crushed into a powder. The ESR spectrum of the powder showed a strong main peak at g = 2.004 and a pair of peaks centered at the main peak. The main peak was detected from both flesh and skin specimens. This peak height gradually decreased during storage following irradiation. On the other hand, the side peaks showed a well-defined dose–response relationship even at 9 days post-irradiation. The side peaks therefore provide a useful means to define the irradiation of fresh mangoes. 相似文献
100.
Hanashima S Inamori K Manabe S Taniguchi N Ito Y 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(13):3449-3462
Bisubstrate-type inhibitors for N-acetylglucosaminyltransferase (GnT)-V and -IX were designed and synthesized. These compounds carry both an acceptor trisaccaride and an UDP-GlcNAc component tethered by a linker of variable length. The acceptor trisaccharide unit was constructed using a combination of a polymer support and a resin capture-release strategy. Namely, starting with a beta-mannoside bound to low molecular weight monomethyl PEG (MPEG), successive glycosylations with donors having chloroacetyl group produced the trisaccharide, which was subjected to the capture-release purification using cysteine loaded resin. UDP-GlcNAc units carrying phosphate moieties were separately synthesized from the bromoacetamide-containing glucosamine derivative. Ligation between the acceptor thiol and each alkyl bromide on the donor unit readily proceeded, and produced the coupling product. The introduction of the UMP component gave target compounds. All of the synthesized compounds had significant activities to GnT-V and -IX. Their potencies were dependent upon the linkers length. GnT-IX was more sensitive to these inhibitors and optimum linker length was clearly different between these GnTs. The most potent inhibitor of GnT-V had Ki=18.3 microM, while that of GnT-IX had Ki = 4.7 microM. 相似文献