全文获取类型
收费全文 | 301篇 |
免费 | 15篇 |
国内免费 | 1篇 |
专业分类
化学 | 214篇 |
晶体学 | 5篇 |
力学 | 8篇 |
数学 | 36篇 |
物理学 | 54篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 7篇 |
2020年 | 4篇 |
2019年 | 7篇 |
2018年 | 3篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 11篇 |
2014年 | 14篇 |
2013年 | 18篇 |
2012年 | 14篇 |
2011年 | 25篇 |
2010年 | 14篇 |
2009年 | 14篇 |
2008年 | 21篇 |
2007年 | 17篇 |
2006年 | 21篇 |
2005年 | 18篇 |
2004年 | 22篇 |
2003年 | 8篇 |
2002年 | 14篇 |
2001年 | 9篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1989年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有317条查询结果,搜索用时 15 毫秒
91.
18π‐Electron Tautomeric Benziphthalocyanine: A Functional Near‐Infrared Dye with Tunable Aromaticity 下载免费PDF全文
Naoyuki Toriumi Dr. Atsuya Muranaka Dr. Keiichi Hirano Kengo Yoshida Dr. Daisuke Hashizume Prof. Dr. Masanobu Uchiyama 《Angewandte Chemie (International ed. in English)》2014,53(30):7814-7818
Dihydroxybenziphthalocyanine 1 , with bulky aryloxy groups, has been synthesized and characterized by X‐ray crystallography, NMR and UV/Vis‐NIR spectroscopy, and theoretical calculations. Macrocycle 1 is the first example of an aromatic benziphthalocyanine with an 18π‐electron structure, and was found to exist as an equilibrium mixture of weakly aromatic and strongly aromatic tautomers. The aromaticity and near‐IR absorption can be controlled by chemical modification at the reactive resorcinol moiety and by variation of the solvent. 相似文献
92.
Dr. Naoyuki Toriumi Kazuya Yamashita Prof. Dr. Nobuharu Iwasawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(49):12635-12641
A metal-free photoredox-catalyzed hydrodefluorination of fluoroarenes was achieved by using N,N,N’,N’-tetramethyl-para-phenylenediamine ( 1 ) as a strong photoreduction catalyst. This reaction was applicable not only to electron-rich monofluoroarenes but also to polyfluoroarenes to afford non-fluorinated arenes. The experimental mechanistic studies indicated that the amide solvent NMP plays an important role for regeneration of the photocatalyst, enabling additive-free photoreduction catalysis. 相似文献
93.
Naoyuki Harada Yoichi Sasaki Masanori Hosoyamada Nobuo Kimizuka Nobuhiro Yanai 《Angewandte Chemie (International ed. in English)》2021,60(1):142-147
While many studies have been done on triplet–triplet annihilation‐based photon upconversion (TTA‐UC) to produce visible light with high efficiency, the efficient TTA‐UC from visible to UV light, despite its importance for a variety of solar and indoor applications, remains a challenging task. Here, we report the highest visible‐to‐UV TTA‐UC efficiency of 20.5 % based on the discovery of an excellent UV emitter, 1,4‐bis((triisopropylsilyl)ethynyl)naphthalene (TIPS‐Nph). TIPS‐Nph is an acceptor with desirable features of high fluorescence quantum yield and high singlet generation efficiency by TTA. TIPS‐Nph has a low enough triplet energy level to be sensitized by Ir(C6)2(acac), a superior donor that does not quench UV emission. The combination of TIPS‐Nph and Ir(C6)2(acac) realizes the efficient UV light production even with weak light sources such as an AM 1.5 solar simulator and room LEDs. 相似文献
94.
Takashi Azuma Norihide Nakada Naoyuki Yamashita Hiroaki Tanaka 《International journal of environmental analytical chemistry》2013,93(9):853-862
We optimised the simultaneous analysis of four analytes, namely three anti-influenza drugs (oseltamivir (OS), zanamivir (ZAN) and amantadine (AMN)) and one metabolite of OS (oseltamivir carboxylate (OC)), in sewage treatment plant (STP) influent and effluent by verifying the types and conditions of solid phase extraction (SPE) appropriate for LC-MS/MS analysis. In summary, these target analytes were extracted from aqueous samples (30–50 mL) by using strong cation-exchange SPE cartridges (500 mg adsorbent) under acidic conditions (pH 3–4). After washing of the cartridges with acidified water (pH 3.0, 3 mL) and methanol (3 mL), the analytes were eluted with a mixed solvent (2 mL) of 10% (v/v) triethylamine in a 1:1 (v/v) mixture of acetone and water. Application of this technique to the target compounds should yield a comprehensive understanding of the occurrence and fate of anti-influenza drugs in the water environment. 相似文献
95.
Kato D Sekioka N Ueda A Kurita R Hirono S Suzuki K Niwa O 《Journal of the American Chemical Society》2008,130(12):3716-3717
We describe the quantitative nonlabel electrochemical detection of both cytosine (C) and methylcytosine (mC) in oligonucleotides using newly developed nanocarbon film electrodes. The film consists of nanocrystalline sp2 and sp3 mixed bonds formed by employing the electron cyclotron resonance (ECR) sputtering method. We successfully used this film to develop a simple electrochemical DNA methylation analysis technique based on the measurement of the differences between the oxidation currents of C and mC since our ECR nanocarbon film electrode can directly measure all DNA bases more quantitatively than conventional glassy carbon or boron-doped diamond electrodes. The excellent properties of ECR nanocarbon film electrodes result from the fact that they have a wide potential window while maintaining the high electrode activity needed to oxidize oligonucleotides electrochemically. Proof-of-concept experiments were performed with synthetic oligonucleotides including different numbers of C and mC. This film allowed us to perform both C- and mC-positive assays solely by using the electrochemical oxidation of oligonucleotides without bisulfite or labeling processes. 相似文献
96.
Naoyuki Kotoku 《Tetrahedron letters》2008,49(49):7078-7081
Stereoselective synthesis of the CD-ring structure of cortistatin A (1), a novel anti-angiogenic steroidal alkaloid from Indonesian marine sponge, was achieved. The stereogenic tertiary carbon center bearing the isoquinoline moiety was constructed by 1,3-chiral transfer method using Johnson-Claisen rearrangement of the chiral allylic alcohol 5. Subsequent intramolecular Michael-aldol reaction afforded the targeted trans-hydrindane skeleton with moderate stereoselectivity. 相似文献
97.
98.
99.
We prove a convergence theorem for a family of value functions associated with
stochastic control problems whose cost functions are defined by backward stochastic
differential equations. The limit function is characterized as a viscosity solution
to a fully nonlinear partial differential equation of second order. The key
assumption we use in our approach is shown to be a necessary and sufficient assumption
for the homogenizability of the control problem. The results generalize partially
homogenization problems for Hamilton–Jacobi–Bellman equations treated recently by
Alvarez and Bardi by viscosity solution methods. In contrast to their approach, we
use mainly probabilistic arguments, and discuss a stochastic control interpretation
for the limit equation. 相似文献
100.