Pseudo-hyperbolic Gauss maps of Lorentzian surfaces in anti-de Sitter space

In this paper, we determine the type numbers of the pseudo-hyperbolic Gauss maps of all oriented Lorentzian surfaces of constant mean and Gaussian curvatures and non-diagonalizable shape operator in the 3-dimensional anti-de Sitter space. Also, we investigate the behavior of type numbers of the pseudo-hyperbolic Gauss map along the parallel family of such oriented Lorentzian surfaces in the 3-dimensional anti-de Sitter space. Furthermore, we investigate the type number of the pseudo-hyperbolic Gauss map of one of Lorentzian hypersurfaces of B-scroll type in a general dimensional anti-de Sitter space.     

Intrinsic versus extrinsic anomalous Hall effect in ferromagnets

A unified theory of the anomalous Hall effect (AHE) is presented for multiband ferromagnetic metals with dilute impurities. In the clean limit, the AHE is mostly due to extrinsic skew scattering. When the Fermi level is located around anticrossing of band dispersions split by spin-orbit interaction, the intrinsic AHE to be calculated ab initio is resonantly enhanced by its nonperturbative nature, revealing the extrinsic-to-intrinsic crossover which occurs when the relaxation rate is comparable to the spin-orbit coupling.     

Enhancement of Higgs to diphoton decay width in non-perturbative Higgs model

We investigate a possibility if a loop diagram via Higgsino can enhance the Higgs to diphoton decay width in supersymmetric models with an extension of Higgs sector. A model with an additional non-renormalizable term of Higgs fields is firstly analyzed where the higher order term can introduce the Higgs coupling to Higgsinos as well as charged Higgs bosons. We point out that a choice of the Higgs coupling to obtain a significant size of enhancement of diphoton decay width reduces the Higgs mass and/or a size of non-renormalizable term needs to be large and a cutoff scale is around the weak scale. Another model in which the Higgsino mass term is generated by a non-perturbative instanton effect via a strong dynamics in a context of SUSY QCD is also suggested. It is shown that the sign of the Higgs coupling to fermions is opposite from perturbative models due to an operator including bosonic fields in the denominator and a constructive contribution to the diphoton decay amplitude can be easily obtained in this kind of model.     

Design of Photostable,Activatable Near‐Infrared Photoacoustic Probes Using Tautomeric Benziphthalocyanine as a Platform

Near‐infrared (NIR) imaging techniques have attracted significant attention for biological and medicinal applications due to the ability of NIR to penetrate deeply into tissues. However, there are very few stable, activatable molecular probes that can utilize NIR light in the wavelength range beyond 800 nm. Herein, we report a new activatable NIR system for photoacoustic imaging based on tautomeric benziphthalocyanines (BPcs). We found that the existence of a free hydroxyl group is crucial for NIR absorption of BPcs. Synthesized water‐soluble hydroxy BPcs exhibited high photostability and no fluorescence, which are desirable features for photoacoustic imaging. We synthesized BPcs in which the free hydroxyl group was masked by an esterase‐labile or an H₂O₂‐labile group. The photoacoustic signals of these hydroxy‐masked BPcs were increased upon NIR excitation at 880 nm in the presence of esterase or H₂O₂, respectively. These are rare examples of activatable probes utilizing NIR light at around 900 nm.     

Master-oscillator power-amplifier scheme for efficient green-light generation in a planar MgO:PPLN waveguide

We developed a new master-oscillator power-amplifier scheme consisting of a tapered semiconductor amplifier and a fiber-grating-stabilized laser diode for efficient green-light generation in a planar MgO:PPLN waveguide, and demonstrated cw green-light generation of 346 mW.     

Thermo-optic properties of B2O3 doped Li2O-Al2O3-SiO2 glass-ceramics

Reduction in the temperature coefficient of the optical path length, dS/dT of Li₂O-Al₂O₃-SiO₂ glass-ceramics with near-zero thermal expansion coefficient was attempted using control of the temperature coefficient of electronic polarizability, ?, and the thermal expansion coefficient, α. The dS/dT value of 2.6 mol% B₂O₃-doped glass-ceramic was 12.5  × 10⁻⁶/°C, which was 0.9 ×  10⁻⁶/°C smaller than that of B₂O₃-free glass-ceramic. On the other hand, reduction in dS/dT through B₂O₃ doping was not confirmed in precursor glasses. Results showed that reduction in dS/dT of the glass-ceramic through B₂O₃ doping is caused by the reduction in ?. The reduction in ? from B₂O₃ doping was probably attributable to numerical reduction in non-bridging oxide ions with larger ? value by the concentration of boron ions in the residual glass phase. In addition, application of hydrostatic pressure during crystallization was effective to inhibit precipitation of β-spodumene solid solution, which thereby decreases dS/dT. The dS/dT value of B₂O₃-doped glass-ceramic crystallized under 196 MPa was 11.7 ×  10⁻⁶/°C. That value was slightly larger than that of silica glass. The α value of this glass-ceramic was smaller than that of silica glass.     

Asymmetric Total Synthesis of (−)‐Englerin A through Catalytic Diastereo‐ and Enantioselective Carbonyl Ylide Cycloaddition

An asymmetric total synthesis of the guaiane sesquiterpene (?)‐englerin A, a potent and selective inhibitor of the growth of renal cancer cell lines, was accomplished. The basis of the approach is a highly diastereo‐ and enantioselective carbonyl ylide cycloaddition with an ethyl vinyl ether dipolarophile under catalysis by dirhodium(II) tetrakis[N‐tetrachlorophthaloyl‐(S)‐tert‐leucinate], [Rh₂(S‐TCPTTL)₄], to construct the oxabicyclo[3.2.1]octane framework with concomitant introduction of the oxygen substituent at C9 on the exo‐face. Another notable feature of the synthesis is ruthenium tetraoxide‐catalyzed chemoselective oxidative conversion of C9 ethyl ether to C9 acetate.