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121.
An optically active α‐ethylated α,α‐disubstituted amino acid, (S)‐butylethylglycine (=(2S)‐2‐amino‐2‐ethylhexanoic acid; (S)‐Beg; (S)‐ 2 ), was prepared starting from butyl ethyl ketone ( 1 ) by the Strecker method and enzymatic kinetic resolution of the racemic amino acid. Homooligopeptides containing (S)‐Beg (up to hexapeptide) were synthesized by conventional solution methods. An ethyl ester was used for the protection at the C‐terminus, and a trifluoroacetyl group was used for the N‐terminus of the peptides. The structures of tri‐ and tetrapeptides 5 and 6 in the solid state were solved by X‐ray crystallographic analysis, and were shown to have a bent planar C5‐conformation (tripeptide) and a fully planar C5‐conformation (tetrapeptide) (see Figs. 1 and 2, resp.). The IR and 1H‐NMR spectra of hexapeptide 8 revealed that the dominant conformation in CDCl3 solution was also a fully planar C5‐conformation. These results show for the first time that the preferred conformation of homopeptides containing a chiral α‐ethylated α,α‐disubstituted amino acid is a planar C5‐conformation. 相似文献
122.
123.
Quinone dimers connected with acetylene (QAQ) and diacetylene linkages (QAAQ) have been synthesized and their structure and electronic properties studied. X-ray analysis, DFT calculations, and UV-vis measurements showed that, unlike directly connected quinone dimers (QQ), they had planar and thus efficiently extended π conjugation systems. The respective reduction potentials of QAQ and QAAQ were considerably raised, and QAQ thereby behaved as a mild oxidizing agent. 相似文献
124.
Ohkawa K Hayashi S Kameyama N Yamamoto H Yamaguchi M Kimoto S Kurata S Shinji H 《Macromolecular bioscience》2009,9(1):79-92
A synthetic route is described for collagen-like polypeptides constructed from O-phospho-L-hydroxyproline [Hyp(PO(3)H(2))] residues. Using the synthetic polypeptides and a natural protein, gelatin, fine fibers and their network structures (ESNWs) were prepared via electrospinning. The composite ESNWs can induce the mineralization of calcium phosphate. The phosphoryl groups of the Hyp(PO(3)H(2)) residues affect both the crystalline phase and amount of the calcium phosphate, depending on the chemical structure in the repeating sequence. The composite ESNWs can be developed as a biocompatible replacement of the extracellular matrix of hard tissues, and thus can be applied as dental materials for restoration of dental cavities or as a sealant for pits and fissures. 相似文献
125.
Hitoshi Sugiyama Chiriki Watanabe Naoto Kato 《International Journal of Computational Fluid Dynamics》2013,27(8):335-348
A numerical analysis has been performed for a developing turbulent flow in a rotating U-bend of strong curvature with rib-roughened walls using an anisotropic turbulent model. In this calculation, an algebraic Reynolds stress model is used to precisely predict Reynolds stresses, and a boundary-fitted coordinate system is introduced as a method of coordinate transformation to set the exact boundary conditions along the complicated shape of U-bend with rib-roughened walls. Calculated results for mean velocity and Reynolds stresses are compared to the experimental data in order to validate the proposed numerical method and the algebraic Reynolds stress model. Although agreement is certainly not perfect in all details, the present method can predict characteristic velocity profiles and reproduce the separated flow generated near the outer wall, which is located just downstream of the curved duct. The Reynolds stresses predicted by the proposed turbulent model agree well with the experimental data, except in regions of flow separation. 相似文献
126.
127.
Watanabe Hayato Omura Takuya Okaichi Naoto Kano Masanori Sasaki Hisayuki Arai Jun 《Optical Review》2022,29(4):366-374
Optical Review - Light field displays can display three-dimensional (3D) images with smooth motion parallax without the use of special glasses, by reproducing light ray information from objects.... 相似文献
128.
The combination of carbaboranylmercuric chloride (new type of bulky Lewis acid) and silver triflate efficiently catalyzes cycloisomerization of 1,3-dienes at room temperature. The catalytic system gives allyl-substituted azacycles and cycloalkanes in excellent yields with high to complete regioselectivity. 相似文献
129.
Despite significant advances in the catalytic direct arylation of heteroarenes, the application of this reaction to pyridines has been met with limited success. An oxidative nucleophilic arylation strategy has been developed to overcome this problem. Pyridine, pyrazine, quinolone, and related electron‐deficient N‐heteroarenes can be arylated at the most electrophilic site using the developed nickel‐catalyzed reaction. This protocol serves as a complementary method to catalytic direct arylation reactions. 相似文献
130.
We used hybrid density-functional calculations to clarify the effect of substituting chromium for titanium (Cr(Ti)) on photocatalytic activities of Cr-doped SrTiO(3). A singly negative Cr(Ti)?, which is relevant to a lower oxidation state of Cr, is advantageous for the visible light absorption without forming electron trapping centers, while other charge states are inactive for the photocatalytic reaction. Stabilizing the desirable charge state (Cr(Ti)?) is feasible by shifting the Fermi level towards the conduction band. Our theory sheds light on the photocatalytic properties of metal-doped semiconductors. 相似文献