Role of Ti 3d carriers in mediating the ferromagnetism of Co∶TiO2 anatase thin films

We study the surface and bulk electronic structure of the room-temperature ferromagnet Co∶TiO(2) anatase films using soft- and hard-x-ray photoemission spectroscopy with probe sensitivities of ～1 and ～10 nm, respectively. We obtain direct evidence of metallic Ti(3+) states in the bulk, which get suppressed to give a surface semiconductor, thus indicating the difference in electronic structure between surface and bulk. X-ray absorption and resonant photoemission spectroscopy reveal Ti(3+) electrons at the Fermi level (E(F)) and high-spin Co(2+) electrons occurring away from E(F). The results show the importance of the charge neutrality condition: Co(2+)+V(O)(2-)+2Ti(4+)?Co(2+)+2Ti(3+) (V(O) is oxygen vacancy), which gives rise to the elusive Ti 3d carriers mediating ferromagnetism via the Co 3d-O 2p-Ti 3d exchange interaction pathway of the occupied orbitals.     

Practical techniques for a three‐dimensional FEM analysis of incompressible fluid flow contained with slip walls and a downstream tube bundle

Two practical techniques are proposed in this paper to simulate a flow contained in a plenum with a downstream tube bundle under a PC environment. First, a technique to impose slip wall conditions on smooth‐faced planes and sharp edges is proposed to compensate for the mesh coarseness relative to boundary layer thickness. In particular, a new type of Poisson equation is formulated to simultaneously satisfy both such velocity boundary conditions on walls and the incompressibility constraint. Second, a numerical model for a downstream tube bundle is proposed, where hydraulic resistance in a tube is imposed as a traction boundary condition on a fluid surface contacting the tube bundle end. The effectiveness of the techniques is numerically demonstrated in the application to a flow in a condenser water box. Copyright © 2001 John Wiley & Sons, Ltd.     

Large‐scale SPH simulations of droplet impact onto a liquid surface up to the consequent formation of Worthington jet

In this study, the whole process of liquid droplet impact onto a liquid surface up to the consequent formation of the central column was simulated using the smoothed particle hydrodynamics method (SPH), and compared with an experiment using a high‐speed video camera. The surface tension tensor for the particle‐based expression was adequately included as the gradient of the surface tension and that enabled the simulation leading to the formations of crater and crown as well as the consequent central column. The simulated time series of the crater depth and diameter and crown height corresponded quantitatively well with the experimental result up to the rebound motion while discrepancies remained as a lower central column height in the simulation, and this seemed to be ascribed to the difficulty in realizing the complex surface structure that inevitably appeared in the fast rebound motion. Copyright © 2009 John Wiley & Sons, Ltd.     

A new positive‐definite regularization of incompressible Navier–Stokes equations discretized with Q1/P0 finite element

A new regularization method is proposed for the Galerkin approximation of the incompressible Navier–Stokes equations with Q1/P0 element, by newly introducing a square‐type linear form into the variational divergence‐free constraint regularized with the global pressure jump (GPJ) method. The addition of the square‐type linear form is intended to eliminate the hydrostatic pressure mode appearing in confined flows, and to make the discretized matrix positive definite and then non‐singular without the pressure pegging trick. Effects of the free parameters for the regularization on the solutions are numerically examined with a 2‐D driven cavity flow problem. Furthermore, the convergences in the conjugate gradient iteration for the solution of the pressure Poisson equation are compared among the mixed method, the GPJ method and the present method for both leaky and non‐leaky 3‐D driven cavity flows. Finally, the non‐leaky 3‐D cavity flows at different Re numbers are solved to compare with the literature data and to demonstrate the accuracy of the proposed method. Copyright © 2003 John Wiley & Sons, Ltd.     

On streamline diffusion arising in Galerkin FEM with predictor/multi‐corrector time integration

In the present paper, the author shows that the predictor/multi‐corrector (PMC) time integration for the advection–diffusion equations induces numerical diffusivity acting only in the streamline direction, even though the equations are spatially discretized by the conventional Galerkin finite element method (GFEM). The transient 2‐D and 3‐D advection problems are solved with the PMC scheme using both the GFEM and the streamline upwind/Petrov Galerkin (SUPG) as the spatial discretization methods for comparison. The solutions of the SUPG‐PMC turned out to be overly diffusive due to the additional PMC streamline diffusion, while the solutions of the GFEM‐PMC were comparatively accurate without significant damping and phase error. A similar tendency was seen also in the quasi‐steady solutions to the incompressible viscous flow problems: 2‐D driven cavity flow and natural convection in a square cavity. Copyright © 2002 John Wiley & Sons, Ltd.     

Asymptotic distributions of regression and autoregression coefficients with martingale difference disturbances

In this paper a form of the Lindeberg condition appropriate for martingale differences is used to obtain asymptotic normality of statistics for regression and autoregression. The regression model is y_t = Bz_t + v_t. The unobserved error sequence {v_t} is a sequence of martingale differences with conditional covariance matrices {Σ_t} and satisfying sup_{t=1,…, n} {v′_tv_tI(v′_tv_t>a) |z_t, v_t−1, z_t−1, …} 0 as a → ∞. The sample covariance of the independent variables z₁, …, z_n, is assumed to have a probability limit M, constant and nonsingular; max_t=1,…,nz′_tz_t/n 0. If (1/n)Σ_t=1ⁿΣ_t Σ, constant, then √nvec( _n−B) N(0,M⁻¹Σ) and _n Σ. The autoregression model is x_t = Bx_{t − 1} + v_t with the maximum absolute value of the characteristic roots of B less than one, the above conditions on {v_t}, and (1/n)Σ_t=max(r,s)+1(Σ_tv_t−1−rv′_t−1−s) δ_rs(ΣΣ), where δ_rs is the Kronecker delta. Then √nvec( _n−B) N(0,Γ⁻¹Σ), where Γ = Σ_{s = 0}^∞B^sΣ(B′)^s.     

A Small One-Fiber WDM Optical Ethernet PC Card for FTTD

A new generation of network interface card for fiber-to-the-desktop has been fabricated. The fabricated card is PC-card size and suitable for notebook PCs. It could become the key element in the coming optical Ethernet age.