全文获取类型
收费全文 | 657篇 |
免费 | 17篇 |
国内免费 | 5篇 |
专业分类
化学 | 513篇 |
晶体学 | 9篇 |
力学 | 20篇 |
数学 | 33篇 |
物理学 | 104篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 8篇 |
2019年 | 3篇 |
2018年 | 3篇 |
2017年 | 6篇 |
2016年 | 16篇 |
2015年 | 10篇 |
2014年 | 18篇 |
2013年 | 41篇 |
2012年 | 30篇 |
2011年 | 40篇 |
2010年 | 23篇 |
2009年 | 22篇 |
2008年 | 26篇 |
2007年 | 38篇 |
2006年 | 42篇 |
2005年 | 41篇 |
2004年 | 37篇 |
2003年 | 24篇 |
2002年 | 26篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 14篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 15篇 |
1990年 | 5篇 |
1989年 | 11篇 |
1988年 | 5篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 18篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1973年 | 7篇 |
排序方式: 共有679条查询结果,搜索用时 15 毫秒
51.
We investigated particularly the proactive nature of the visual-motor system by steady and transient experiments of a hand-tracking task, and confirmed that the hand motion precedes on the average the target motion in steady runs within a finite frequency range of the sinusoidal target motion. The question why and how much the hand motion should precede was answered by frequency-jump experiments. The results implied that the positive phase shift of the hand motion represents the proactive nature of the visual-motor control system which is adaptationally developed for each person to minimize the transient error of the hand motion when the target motion changes unexpectedly. 相似文献
52.
[reaction: see text] The Heck reaction is a more efficient and reliable method than previous ones for introducing a C3 unit at the benzyl position for the synthesis of Beraprost. Especially, trialkylated long-chain amines such as (n-C(8)H(17))(3)N and (n-C(12)H(25))(3)N resulted in good yields. This development will be used for the industrial synthesis of Beraprost. 相似文献
53.
Toshiki Yasokawa Ichirou Ishimaru Masahiro Kondo Shigeki Kuriyama Tsutomu Masaki Kaoru Takegawa Naotaka Tanaka 《Optical Review》2007,14(4):161-164
This paper describes a method for measuring the three-dimensional (3D) refractive-index distribution in a single cell. The
method can be used to observe the distribution of cell components without fluorescence staining. The two-dimensional optical
path length distributions from multiple directions are obtained by non-contact rotation of the cell. These optical path lengths
are converted into the line integrals of the refractive index, and the 3D refractive-index distribution is reconstructed by
means of computed tomography. The refractive-index distribution in a breast cancer cell can be measured using a phase-shifting
Mach—Zehnder interferometer in conjunction with proximal two-beam optical tweezers. 相似文献
54.
M.A. BramantyaT. Sawada 《Journal of magnetism and magnetic materials》2011,323(10):1330-1333
Structure of magnetorheological (MR) fluids depends on the strength of the magnetic field applied and on the mode of its application. The ultrasonic wave propagation velocity changes under the effect of an external magnetic field as a result of formation of clusters arranged along the direction of the field in the MR fluids. Therefore, we propose a qualitative analysis of these clustering structures by measuring properties of ultrasonic propagation. Since the MR fluids are opaque, the non-contact inspection using this ultrasonic technique can be very useful. In this study, we measured ultrasonic propagation velocity in MR fluid influenced by an external magnetic field for different swept rate precisely. With increasing magnetic field intensity, the changes of the ultrasonic wave velocity are more pronounced. Sedimentation effect takes place in certain time for different swept rate due to magnetic particle size and it follows linear relationship in log scale. Significant differences of the ultrasonic wave velocity are established between the case when the field is swept at a constant rate and the case when it is stepped up. 相似文献
55.
56.
57.
Mitsuhiro Wada Chieko Morinaka Toshihiko Ikenaga Naotaka Kuroda Kenichiro Nakashima 《Analytical sciences》2002,18(6):631-634
An HPLC method with fluorescence detection for the determination of nitric oxide (NO) in cultivated plant cells (Agave pacifica, Agavaceae) was developed. NO was derivatized in situ with 2,3-diaminonaphthalene (DAN) as a labeling reagent and converted to 1(H)-naphthotriazole. The maximum peak height of the derivative was observed by incubation for 3 h at 25 degrees C with 0.2 mM DAN. Excess reagent in cells was removed by washing 3 times with 5 ml of water. The calibration curve for authentic standard of DAN-NO spiked to cultivated plant cells showed a good linearity (r = 0.995) in the range of 5.0 to 50 pmol/g cell. The detection limit at a signal-to-noise ratio of 3 was 3.4 pmol/g cells. The proposed method was successfully applied to the monitoring of NO concentration with cell growth. The effect of thermal treatment on the concentration of NO in plant cells was also examined. The concentration of NO in cells treated at 5 degrees C for 1 h was significantly higher than that treated at 25 degrees C and 35 degrees C for 1 h (n = 3, p < 0.05). 相似文献
58.
59.
Novel fluoroalkyl end‐capped vinyltrimethoxysilane oligomer/hydroxyapatite (HAp) nanocomposites were prepared by the reaction of calcium nitrate tetrahydrate and phosphoric acid in the presence of the corresponding oligomer. These fluorinated oligomer/HAp composites thus obtained are nanometer size‐controlled fine particles (83–173 nm), and were found to exhibit good dispersibility in methanol, ethanol, and isopropyl alcohol. These fluorinated HAp nanocomposites were applied to the surface modification of glass and poly(methyl methacrylate) (PMMA) to exhibit good hydro‐ and oleophobic characteristics imparted by fluorine on their surface. In addition, the surface structural changes of the modified polyethylene terephtalate and PMMA films treated with these fluorinated nanocomposites before and after soaking in a simulated body fluid (SBF) were analyzed by using SEM, XRD, and EDX to observe the formation of spherical HAp deposits on the surface. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
60.
Evaluation of chemiluminescence reagents for selective detection of reactive oxygen species 总被引:2,自引:0,他引:2
Shinya Yamaguchi Kaname Ohyama Maiko Kohno Akira Takadate Naotaka Kuroda 《Analytica chimica acta》2010,665(1):74-27
In order to evaluate the chemiluminescence (CL) reagents for selective detection of reactive oxygen species (ROS), we comprehensively measured the CL responses of 20 CL reagents (three luminol derivatives, two imidazopyrazinone derivatives, eight lophine derivatives, six acridinium ester derivatives and lucigenin) against six types of ROS (superoxide anion: O2−, hydroxyl radical: OH, hydrogen peroxide: H2O2, hypochlorite anion: ClO−, singlet oxygen: 1O2, and nitric oxide: NO). As a result of the screening, it was found that nine CL reagents selectively detected O2− while one CL reagent selectively detected OH. However, no CL reagent had selectivity on the detection of H2O2, ClO−, 1O2 and NO. Our screening results could help to select the most suitable CL reagent for selective determination of different ROS.As an application study, 4-methoxyphenyl-10-methylacridinium-9-carboxylate (MMAC), one of the acridinium ester derivatives, showed high selectivity on the detection of O2−, and thus was applied to the assay of superoxide dismutase (SOD) activity. The dynamic range and detection limit of the developed CL assay were 0.1-10 and 0.06 U mL−1, respectively. Significant correlation (r = 0.997) was observed between the results by the CL assay using MMAC and the spectrophotometric assay using 2-(4-iodophenyl)-3-(4-nitrophenyl)-5-(2,4-disulfophenyl)-2H-tetrazolium monosodium salt. 相似文献