全文获取类型
收费全文 | 1735篇 |
免费 | 87篇 |
国内免费 | 8篇 |
专业分类
化学 | 1458篇 |
晶体学 | 19篇 |
力学 | 20篇 |
数学 | 116篇 |
物理学 | 217篇 |
出版年
2023年 | 15篇 |
2022年 | 13篇 |
2021年 | 24篇 |
2020年 | 18篇 |
2019年 | 45篇 |
2018年 | 30篇 |
2017年 | 19篇 |
2016年 | 56篇 |
2015年 | 45篇 |
2014年 | 46篇 |
2013年 | 88篇 |
2012年 | 122篇 |
2011年 | 126篇 |
2010年 | 55篇 |
2009年 | 56篇 |
2008年 | 121篇 |
2007年 | 105篇 |
2006年 | 122篇 |
2005年 | 117篇 |
2004年 | 94篇 |
2003年 | 94篇 |
2002年 | 66篇 |
2001年 | 15篇 |
2000年 | 31篇 |
1999年 | 17篇 |
1998年 | 12篇 |
1997年 | 20篇 |
1996年 | 23篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1993年 | 11篇 |
1992年 | 15篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1985年 | 22篇 |
1984年 | 16篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1981年 | 17篇 |
1980年 | 12篇 |
1979年 | 7篇 |
1978年 | 12篇 |
1977年 | 10篇 |
1976年 | 20篇 |
1975年 | 14篇 |
1974年 | 3篇 |
1973年 | 7篇 |
1968年 | 3篇 |
排序方式: 共有1830条查询结果,搜索用时 31 毫秒
101.
Letters in Mathematical Physics - We construct explicitly strong generators of the affine $$\mathcal {W}$$-algebra $$\mathcal {W}^{K_0-N}(\mathfrak {sl}_N, f_{sub})$$ of subregular type A.... 相似文献
102.
Tairin Kawasaki Naoki Ishida Masahiro Murakami 《Angewandte Chemie (International ed. in English)》2020,59(41):18267-18271
A convenient method is reported to specifically acylate phenolic hydroxyl groups through a radical pathway. When a mixture of an aldehyde and a phenol in ethyl acetate is irradiated with blue light in the presence of iridium and nickel bromide catalysts at ambient temperature, phenoxyl and acyl radicals are transiently generated in situ and cross‐couple to furnish an ester. Aliphatic hydroxy groups remain untouched under the reaction conditions. 相似文献
103.
The title compounds, Ph2bNO and Ph3bNO, were designed as a biradical paramagnetic host, and their chelation ability was confirmed by inclusion of a size-matched alkaline-earth metal ion. The crystal structures of [Ca(hfac)2(Ph2bNO)] and [Ba(hfac)2(Ph3bNO)] were determined, where Hhfac stands for 1,1,1,5,5,5-hexafluoropentane-2,4-dione. The solution electron paramagnetic resonance spectra showed switching behavior. Five lines were found for Ph3bNO and charecterized as the hyperfine splitting due to the two nitrogen atoms. After addition of barium(II) ion, the spectrum turned to be three lines. Removal of the barium ion recovered the five line pattern. The present system can be regarded as a reversible magnetic-coupling switch by means of a supramolecular technique. 相似文献
104.
Naoki Kise Yosei Takenaga Yohei Ishikawa Yoichi Morikami Toshihiko Sakurai 《Tetrahedron letters》2012,53(15):1940-1945
The reductive coupling of N-methoxycarbonyl lactams with benzophenone by Zn-TiCl4 in THF gave cross-coupled products as cyclic α-diphenylidene-N-methoxycarbonylamines and ring-opening α,α-diphenyl-α-hydroxy-ω-(N-methoxycarbonyl)amino ketones selectively depending on the reduction conditions. The reductive coupling of N-methoxycarbonyl lactams with 9-fluorenone by Zn-TiCl4 gave cyclic α-(9H-fluoren-9-ylidene)-N-methoxycarbonylamines preferentially irrespective to the conditions. 相似文献
105.
106.
Sainer Siagian Khairul Basar Takashi Sakuma Haruyuki Takahashi Naoki Igawa Yoshinobu Ishii 《Solid State Ionics》2009,180(6-8):480-482
Diffuse neutron scattering from a powder AgCl was measured from 10 to 260 K. The correlation effects among thermal displacements of atoms were obtained from the diffraction data. The values of the correlation effects decrease rapidly with the increase of the inter-atomic distance. The values also decrease with the decrease of temperature. The similar tendency was also obtained in AgBr and CuI. The temperature dependence of the values of correlation effects agrees with the result by a simple Debye model of lattice vibrations. 相似文献
107.
Front Cover: Construction of a Triangle‐Shaped Trimer and a Tetrahedron Using an α‐Helix‐Inserted Circular Permutant of Cytochrome c555 (Chem. Asian J. 10/2018) 下载免费PDF全文
108.
Kota Tanaka Saki Okamura Ken Shibata Naoki Ikenaga Nobuyuki Tanaka Kazumi Hakamada Jun Miyake 《Research on Chemical Intermediates》2016,42(11):7723-7730
Renewable energy is regarded as a clean energy source but has some problems, one of which is intermittency. To reduce this, the time-delay of hydrogen production by photosynthetic bacteria can be effective. In this study, we qualitatively evaluated the time-delay of hydrogen production by photosynthetic bacteria under various irradiation conditions, and we also quantitatively evaluated it by fitting the experimental data and the hydrogen production model with a genetic algorithm. As a result of model fitting, we found that the relationship between the lengths of the optimized time-delay of hydrogen production by photosynthetic bacteria and the amount of light irradiation is linear. And we also found that the time-delay of hydrogen production by photosynthetic bacteria had an upper limit under low light intensity. We have suggested the existence of an energy store mechanism in photosynthetic bacteria. 相似文献
109.
110.
Matsumoto T Kominami T Ueda K Sugimoto T Tada T Noguchi S Yoshino H Murata K Shiro M Negishi E Toyota N Endo S Takahashi K 《Inorganic chemistry》2002,41(18):4763-4769
The 2:1 charge-transfer (CT) salts (1(2).FeBr(4) and 1(2).GaBr(4)) of ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide (1) with FeBr(4)(-) and GaBr(4)(-) counteranions were obtained as needle crystals, whose structures are almost the same as each other. The 1 molecules form a one dimensionally stacked column with alternation of their molecular axis direction, while the counteranions are aligned in parallel with the 1-stacked columns with the direction of their distorted-tetrahedral geometry maintained. The room-temperature electrical conductivities measured on the single crystals of 1(2).FeBr(4) and 1(2).GaBr(4) were 4.6 and 2.1 S cm(-1), respectively. From the temperature dependences of their electrical conductivities in both cases the electrical conducting properties were metallic between ca. 170 and 300 K, but below ca. 170 K converted to be semiconducting and continued till 5 K, although the activation energies are very small (4-10 meV). For 1(2).FeBr(4) very weak and antiferromagnetic interaction occurred between the d spins of FeBr(4)(-) ions in the temperature range of ca. 1-300 K. However, below ca. 15 K the ferromagnetic interaction was reversely preferential possibly by participation of the pi spin of 1. 相似文献