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31.
We have investigated the pressure-induced Raman spectral changes of 1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF4]). We found that [emim][BF4] did not crystallize up to 1.2 GPa. The Raman CH stretching spectra arising from the CH3 groups of the ethyl-chain and the CH3 group adjacent to the imidazolium-ring in [emim]+ cation largely changed against pressure. Moreover, the Raman intensity of the CH2 (N) bending band arising from the alkyl-chain drastically changes with increasing pressure, but that of the imidazolium-ring in-plane bending band arising from the imidazolium-ring is independent of pressure. Our results show that the environment around the alkyl-chain of [emim][BF4] is largely perturbed rather than that around the imidazolium-ring upon compression. 相似文献
32.
The stereoselective total synthesis of (+)-obtusenyne is described. The oxonene skeleton possessing trans-orientated alkyl substituents at the α,α′-positions was stereoselectively constructed via cyclization of the corresponding hydroxy epoxide promoted by Eu(fod)3. 相似文献
33.
Cationic liposomes enhanced firefly bioluminescent assay of bacterial ATP in the presence of an ATP extractant. 总被引:1,自引:0,他引:1
Naohiro Nakata Akihiko Ishida Hirofumi Tani Tamio Kamidate 《Analytical sciences》2003,19(8):1183-1185
Cationic liposomes composed of two components, diethylaminoethyl-carbamoyl cholesterol and phosphatidylcholine, were applied to an enhancer for a firefly bioluminescent (BL) assay of bacterial ATP in the presence of an ATP extractant. Trichloroacetic acid (TCA), which inhibits the activity of luciferase, was used as an ATP extractant. Cationic liposomes enhanced the BL intensity as long as luciferase was active. The detection limits for cell numbers of Escherichia coli extracts in the presence of cationic liposomes and in water alone were 199 and 897 colony forming units ml(-1), respectively. The sensitivity for bacterial ATP in the presence of cationic liposomes was improved by a factor of 2.5 times compared to that in the presence of diethylaminoethyl-dextran. 相似文献
34.
Naohiro Murayama Takao Oikawa Takayuki Katto Ken'ichi Nakamura 《Journal of Polymer Science.Polymer Physics》1975,13(5):1033-1047
The piezoelectricity of PVDF thermoelect rets formed with vacuum-coated aluminum electrodes has been investigated in detail. The piezoelectricity depends on the β-form crystal structure of PVDF homopolymer and copolymers. However, the piezoelectricity is not attributed to the stress dependence of the spontaneous polarization of β-form crystals, but rather to the persistent polarization arising from trapped charges. The trapping mechanism is discussed. 相似文献
35.
David W. Minaar Ralph A. Mudgett Michitoshi Soga 《International Journal of Theoretical Physics》1977,16(3):177-194
An elementary theory for a radiation field with any spinJ is presented. This is a natural extension of Maxwell's equations for the electromagnetic field. The idea is to use the generators for theU(2) group in a multidimensional representation. These generators are a linear combination of the ones for infinitesimal Lorentz transformations. The constants of the motion in this formalism are discussed. As an example, angular distributions of the Poynting vector are given.Supported in part by grants from the Research Corporation and the Mitsubishi Fund.Parts of this work were done in partial fulfilment of the requirements for the M.A. Degree at Western Michigan University. 相似文献
36.
Kazuo Soga Iwakazu Hattori Jiro Kinoshita Sakuji Ikeda 《Journal of polymer science. Part A, Polymer chemistry》1977,15(3):745-753
Copolymerization of ethylene oxide (EO) and sulfur dioxide (SO2) was conducted by using a variety of amines as catalyst. Aromatic tertiary amines such as quinoline and pyridine were found to show the best catalytic property of the various amines, and copolymerization was carried out in the temperature range between 0 and 80°C with the use of quinoline. The copolymerization rate was approximately first-order in quinoline, EO, and also SO2. The copolymer, was always composed of the two monomers: 1:1 ratio, independent of the initial concentration of the monomers. The copolymer obtained was a transparent viscous material which decomposed at 218°C to afford a considerable amount of ethylene sulfite. Spectroscopic analysis of the copolymer combined with the results of elemental analysis indicates the copolymer to have the structure The polymerizability of ethylene sulfite, which might be considered an intermediate compound in the copolymerization, was also examined at 60°C for 4 hr in the presence of quinoline, and it was found that ethylene sulfite could not be polymerized under these conditions. 相似文献
37.
Ohne Zusammenfassung 相似文献
38.
Red-shifts have been observed for Lyman-α lines of Z = 4–7 ions at an electron density of 1021 cm-3. The plasma was produced by a 0.1 TW 100 ps glass laser. The shift was measured relative to the line center of the spatially resolved unperturbed line. The results are compared with theory. 相似文献
39.
40.
A boron complex having plural proton donors (OH, amide NH) and proton acceptors (quinoline) acted as a selective chromo-ionophore toward phosphate anions in CH3CN. 相似文献