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51.
用量子化学从头算方法(HF/6-31G)和密度泛函理论(DFT)的B3LYP方法,以6-31G标准基组加一个极化函数,对(ClAlNH)n(n=1-10)簇合物的几何构型,电子结构和红外光谱进行了优化,并讨论了聚合反应(ClAlNH)m→(ClAlNH)n的热力学效应,结果表明,(ClAlNH)n系列簇合物的基态稳定结构为Cs(n=1),D2h(n=2),D3h(n=3),Td(n=4),Cs(n=5),D3d(n=6),Cs(n=7),S4(n=8),D3h(n=9),C2h(n=10,n=2,4,6,8,10等偶数对应的(ClAlNH)n簇化合物的结构比n等于奇数量更稳定。 相似文献
52.
Jo‐Nan Chen Fang‐Ming Hsu Hui‐Chun Wang Chung‐Wen Wu Pao‐Swu Cheng Wen‐Liang Tsai 《中国化学会会志》2006,53(4):931-938
Four series of compounds 11?50 containing terminal alicyclic rings such as cyclohexylmethyl, cyclopentylmethyl, cyclobutylmethyl, and cyclopropylmethyl rings were synthesized and their liquid crystal behavior studied. The ring size and the length of flexible alkoxy chain influence the phase formation in different ways. While the smaller ring and the shorter alkoxy chain tend to favor the formation of the N phase, the larger ring and the longer alkoxy chain tend to favor the formation of the SmC phase. All the compounds except 11 and 21 exhibit SmA phases. The widest temperature range of the N, SmA, and SmC phases are found in the compounds 41 , 46 , and 20 , respectively, which are 75 °C for 41 , 115 °C for 46 , and 100 °C for 20 . 相似文献
53.
The interaction between gatifloxacin mesylate (GM) and salmon sperm DNA was studied by fluorescence spectrometry and ultra‐violet (UV) spectrometry. Additions of salmon sperm DNA to GM solution resulted in its strong fluorescence quenching and UV absorbance decrease due to the strong interaction between GM and salmon sperm DNA. Both the maximum fluorescence emission wavelength and the maximum UV absorbance wavelength of GM did not change with the increasing concentration of salmon sperm DNA, indicating no intercalative binding existed between them. The Stern‐Volmer plot indicated that the fluorescence‐quenching constant at different temperatures or different salmon sperm DNA concentration ranges was different. Effects of ionic strength and I? on the fluorescence quenching of GM by salmon sperm DNA indicated that electrostatic interaction and groove binding coexisted between them. 相似文献
54.
Direct electrochemical and electrocatalytic behavior of hemoglobin (Hb) immobilized on glass carbon electrode (GCE) containing gelatine (Gel) films was investigated. The characteristics of Hb/Gel film modified GC electrode were performed by using SEM microscopy, UV-vis spectroscopy and electrochemical methods. The immobilized Hb showed a couple of quasi-reversible redox peak with a formal potential of −0.38 V (versus SCE) in 0.1 M pH 7.0 PBS. The formal potential changed linearly from pH 4.03 to 8.41 with a slope value of −52.0 mV pH−1, which suggested that a proton transfer was accompanied with each electron transfer (ET) in the electrochemical reaction. The Hb/gelatine/GCE displayed a rapid amperometric response to the reduction of H2O2 and nitrite. 相似文献
55.
X射线荧光分析技术的研发动态 总被引:1,自引:0,他引:1
周南 《理化检验(化学分册)》2005,41(7):539-540
X射线荧光分析法(XRF)的正确命名,根据IUPAC命名委员会的建议,宜称作“X射线发射分析法”,因并不发生荧光,在保护环境的大前提下,它在分析化学中的地位日益受到重视。随着分析仪器向小型化发展的趋势,X射线荧光分析仪也向手提式轻便、小型携化发展,如手枪式或其他便于握持的式样。 相似文献
56.
The evaluation of matrix elements of two electron atoms is fundamental for the study of the electronic properties of those systems. We add to this knowledge by presenting an explicit expression for the matrix elements of the inverse of the interelectronic distance of two-electron atoms in any spatial dimension D. The basis functions used are the D-dependent hydrogenic wavefunctions {1s
2,2p
2,3d
2,4f
2,5g
2,...,21y
2,...}, extending and including, in this way, the results of the previous basis set {1s
2,2p
2,3d
2,4f
2}. The methodology used does not employ Fourier integral transforms as in previous works but hypergeometric transformation formulas. 相似文献
57.
A new method in which a series of substituted carbazoles is efficiently produced by the combination of an amide and an arene is described. The key feature of this method is the palladium-catalyzed tandem directed C-H functionalization and amide arylation. The method tolerates substitution on either ring of the biaryl amide substrates, and the products can be assembled in a simple two-step protocol from readily available reagents. The Pd(0) species generated are reoxidized to Pd(II) in the presence of Cu(OAc)2 and an atmosphere of oxygen. 相似文献
58.
Cu/TiO2-NiO上光促表面催化CO2和H2O合成CH3OH反应规律 总被引:8,自引:0,他引:8
采用溶胶-凝胶法制备了n(电子型)-p(空穴型) 复合半导体材料0.5%Cu/TiO2-2.0%NiO (w),利用X射线衍射(XRD)、透射电镜(TEM)、红外光谱(IR)、紫外-可见光漫反射(UV-Vis)、程序升温脱附(TPD)技术对材料结构、吸光性能、化学吸附性能进行了表征,研究了该材料对CO2和H2O合成CH3OH的光促表面催化反应(PSSR)规律.结果表明,所制备材料能够明显促进目的反应,室温条件下即有CH3OH生成.在200 ℃下,由于光-表面-热的协同效应,CO2转化率得以提高,且CH3OH的选择性达到87.5% .根据实验结果,得出CO2在材料表面的卧式吸附态为CH3OH的前驱物,并对PSSR机理进行了讨论. 相似文献
59.
A selective titrimetric determination of Pb after separation by a modified method of precipitation as its sulphate is proposed. Pb(II), present as the perchlorate, is precipitated by gentle boiling in 3.6M H(2)SO(4) presaturated with PbSO(4) and free from any extraneous anions. The customary time-consuming evaporation to fumes of sulphuric acid is dispensed with. The precipitate is collected, and dissolved in excess of HEDTA, the surplus of which is back-titrated with Zn(II) at pH 5.0-5.5. Use of Catechol Violet and Xylenol Orange as a mixed indicator gives a sharper end-point. The standard deviation of the proposed method for 60 mg of lead is 0.35 mg. The method has been successfully used to determine Pb in non-ferrous alloys. 相似文献
60.
A Novel Dimeric Coumarin from Clausena lenis 总被引:1,自引:0,他引:1
HongPingHE ShunTingCHEN YueMaoSHEN ChangXiangCHEN YiBinZHAO XiaoJiangHAO 《中国化学快报》2003,14(11):1150-1153
A novel dimeric coumarin (1), a dimeric of seselin named diseselin A, was isolated from the aerial part of Clausena lenis. The structure was elucidated based on the MS, 1D and 2D NMR data. 相似文献