全文获取类型
收费全文 | 3117篇 |
免费 | 520篇 |
国内免费 | 496篇 |
专业分类
化学 | 2416篇 |
晶体学 | 55篇 |
力学 | 231篇 |
综合类 | 64篇 |
数学 | 298篇 |
物理学 | 1069篇 |
出版年
2024年 | 14篇 |
2023年 | 64篇 |
2022年 | 152篇 |
2021年 | 154篇 |
2020年 | 149篇 |
2019年 | 155篇 |
2018年 | 124篇 |
2017年 | 147篇 |
2016年 | 165篇 |
2015年 | 207篇 |
2014年 | 209篇 |
2013年 | 256篇 |
2012年 | 300篇 |
2011年 | 276篇 |
2010年 | 217篇 |
2009年 | 222篇 |
2008年 | 216篇 |
2007年 | 190篇 |
2006年 | 160篇 |
2005年 | 138篇 |
2004年 | 77篇 |
2003年 | 70篇 |
2002年 | 75篇 |
2001年 | 59篇 |
2000年 | 64篇 |
1999年 | 39篇 |
1998年 | 34篇 |
1997年 | 27篇 |
1996年 | 23篇 |
1995年 | 27篇 |
1994年 | 19篇 |
1993年 | 17篇 |
1992年 | 18篇 |
1991年 | 15篇 |
1990年 | 20篇 |
1989年 | 8篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 8篇 |
1984年 | 1篇 |
1983年 | 6篇 |
1982年 | 1篇 |
1979年 | 3篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有4133条查询结果,搜索用时 15 毫秒
71.
The electronic conductivity of a particular metallic particles/semiconductor system, i.e. Ag particles in cesium-oxide thin film, has been studied. The experimental results show a transition from a polycrystalline semiconductor to metallic behavior as characterized by the conductivity-temperature curve (log bs 1/T), and a five order of magnitude increase in the room temperature value of the conductivity with surface Ag content increasing from an equivalent thickness of 2Å to 20Å. It was observed by TEM that the deposited Ag was mainly in the form of dispersed particles with the particle size varying from 20 to 200Å and their separations varying from hundreds to tens of angstroms over the Ag content range. These results can hardly be explained with the model of direct electron tunneling through the Schottky barrier at the Ag-particle/cesium-oxide interface. A microstructure model with two conduction layers is presented, and an analogy to the hopping conduction mechanism is proposed to explain the electronic conduction behavior. This model predicts that the attenuation length for electronic wavefunctions localized at Ag particles falls in the range 20–50Å. 相似文献
72.
报导用激光直接溅射的方法产生了大量的钽硫原子团簇离子Ta_nS_m~+(n≤9, m≤30),并用串级飞行时间质谱仪研究了所产生团簇离子的组成及紫外激光裂解规律。实验发现, 最稳定的团簇正离子往往具有Ta_nS_(2n+7)~+(n=1,2,…9)的组成, 相应的负离子具有, Ta_nS_(2n+3)~-(n=1,2,…9)的组成。各种团簇正离子的激光裂解的主要通道是连续的S_2消除过程, 且对于n=3,4,5的团簇, 主要光解产物还有Ta_3S_4~+或Ta_4S_6~+离子。据此推测出Ta_nS_m~+团簇离子的可能结构为在Ta原子周围有6个左右的S原子配位。Ta原子之间不存在直接的化学键,而较大团簇可能是以Ta_3S_4或Ta_4S_6为核心的结构。 相似文献
73.
Copper(II)-catalyzed aerobic oxidation of primary alcohols to aldehydes in ionic liquid [bmpy]PF6 总被引:1,自引:0,他引:1
A room-temperature aerobic oxidation of primary alcohols to aldehydes catalyzed by the three-component system acetamido-TEMPO/Cu(ClO(4))(2)/DMAP in the ionic liquid [bmpy]PF(6) has been developed, and the catalysts can be recycled and reused for five runs without any significant loss of catalytic activity. [reaction: see text] 相似文献
74.
Using the self-assembly β-cyclodextrin (β-CD) and cetyltrimethylammonium bromide (CTAB) as structure-directing agents, high-quality ordered MCM-41 silicas have been prepared. Small-angle X-ray diffraction (SXRD), N2 adsorption-desorption and scanning electron microscope (SEM) techniques were used to characterize the calcined samples. Results showed that the pore structure of the resulting mesoporous silica belonged to the two-dimensional hexagonal structure (space group p6mm). The high-quality hexagonal structure was formed as n?1 (n denotes molar ratio of β-CD to CTAB). N2 adsorption-desorption curves revealed type IV isotherms, H4 hysteresis loops, for all samples, and H1 hysteresis loops for samples at n=0, 0.1, 1 and 2, respectively. The pore size and the pore wall thickness of the samples increased with the increase in n values, respectively. 相似文献
75.
A vanadium oxide-modified glassy carbon electrode was simply and conveniently fabricated by casting vanadium tri(isoproxide) oxide (VO(OC3H7)3) and poly(propylene carbonate) (PPC) onto the glassy carbon electrode surface. The electrochemical properties of iodide at the VO(OC3H7)3-PPC film-modified glassy carbon electrode were investigated by cyclic voltammetry, and an anodic peak was observed at approximately +0.71 V (vs. SCE). Based on this, a sensitive and convenient electrochemical method was proposed for the determination of iodide. Flow injection amperometry (FIA) exhibited a good linear relationship with the concentration of iodide in the range of 5 × 10−7 mol L−1 and 1 × 10−3 mol L−1, and the detection limit was 1 × 10−7 mol L−1. Quantitative recovery of iodide in synthetic samples has been obtained and the interferences from different cations and anions have been studied. The method has been successfully applied to the determination of iodide in dry edible seaweed. The concentrations of iodide measured by this method are in good agreement with those obtained by spectrophotometric method. 相似文献
76.
77.
78.
Qian Ming Chen Nan Liu Min Cheng Liang Li Jing Wang Min 《Journal of Solid State Electrochemistry》2017,21(11):3121-3127
Journal of Solid State Electrochemistry - In this report, we present a novel platform to study the formation of delicate ordered vertically aligned copolymer nanowires array with EDOT and Py as the... 相似文献
79.
Xiaoji Cao Jingfang Qiao Liping Wang Xuemin Ye Lebin Zheng Nan Jiang Weimin Mo 《Rapid communications in mass spectrometry : RCM》2012,26(7):740-748
A powerful ionic liquid‐based ultrasonic‐assisted extraction (ILUAE) method combined with ultra‐performance liquid chromatography coupled to electrospray ionization quadrupole time‐of‐flight tandem mass spectrometry (UPLC/ESI‐QTOFMSn) was employed in the rapid simultaneous screening of iridoid glycosides, phenylethanoid glycosides, and cucurbitacin glycosides from P. scrophulariiflora. The ILUAE procedure was optimized over several ultrasonic parameters, including the ultrasonic power, concentration of the ionic liquid, and solid–liquid ratio. A comparison with conventional heat‐reflux extraction and regular UAE demonstrated that the optimized approach yielded a high extraction efficiency (Picroside I, 2.84%; Picroside II, 3.57%; 6‐O‐E‐feruloyl catalpol, 2.20%) within a short extraction time of 30 min. Negative ion mode ESI‐QTOFMS2 analysis of the fragmentation reactions of the [M–H]– ions was conducted to characterize the diagnostic ions related to the glycosyl moieties, aglycone units, and the type and substituted position of the ester groups. Interestingly, the positional isomers of the iridoid glycosides could be easily discriminated based on the characteristic ions. A total of 15 glycosides, including three groups of iridoid glycoside isomers and two groups of phenylethanoid glycoside isomers, were conveniently identified within 13.5 min. Moreover, 6'‐O‐vanilloyl catalpol was identified in P. scrophulariiflora for the first time. The method developed here was further validated by measuring the recovery, correlation coefficient (R2), and reproducibility (RSD, n = 5) of three iridoid glycosides: 89.60%–109.02%, 0.9991–0.9998, and 0.93%–1.44%, respectively. This study demonstrated the capabilities of ILUAE combined with UPLC/ESI‐QTOFMSn for the rapid screening of glycosides in P. scrophulariiflora. This method offers an approach to similar studies on other natural plants. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
80.
Yong-Dong Li Hao Zhao Nan Zhang 《International Journal of Solids and Structures》2013,50(22-23):3610-3617
The purpose of the present work is to study the mixed mode fracture of a piezoelectric–piezomagnetic composite with two un-coaxial cracks parallel to the interface and each in a layer. Methods of generalized dislocation simulation, Green’s function, Cauchy singular integral equation and Lobatto–Chebyshev collocation are combined together to get the numerical results of mechanical strain energy release rate (MSERR). Three kinds of effects are revealed by parametric studies, i.e., the free-surface effect, the shielding effect and the interference effect, and they are used to interpret the characteristics of COD and MSERR curves. In addition, the effects of shear loading, magnetic loading and electric loading on MSERR are also disclosed, respectively, by varying the corresponding loading factor. 相似文献