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991.
Neslihan Şahin Namık Özdemir Nevin Gürbüz İsmail Özdemir 《Molecular Crystals and Liquid Crystals》2018,664(1):109-123
A new benzimidazole based N-heterocyclic carbene (NHC) salt (1) was synthesized by the reaction of benzimidazole precursor with alkyl halide. The structure of 1 was determined by elemental analysis, FT-IR, 1H NMR and 13C NMR spectroscopy tecniques and X-ray crystallography. The compound crystallized in the triclinic space group P-1 with two molecules in the unit cell. The optimization of 1 was firstly performed at B3LYP/6-311G++(d,p) level, then the theoretical spectral studies performed and compared with the experimental values. Besides the frontier molecular orbital energies and chemical reactivity analysis of 1, together with the electrostatic potential and molecular electrostatic potential analyses were performed at the same level of theory. 相似文献
992.
Periodica Mathematica Hungarica - I give fully detailed proofs of two important theorems—the exact solution of the weak clique game and the compactness theorem—in the theory of... 相似文献
993.
Synthesis and characterization of a new phenanthrenequinoxaline‐based polymer for organic solar cells
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Eunsol Jo Jong Baek Park Woo‐Hyung Lee Ji‐Hoon Kim In Hwan Jung Do‐Hoon Hwang In‐Nam Kang 《Journal of polymer science. Part A, Polymer chemistry》2016,54(17):2804-2810
Two donor–acceptor (D‐A) conjugated polymers, PQx and PphQx, composed of alkylthienyl‐substituted benzo[1,2‐b:4,5‐b']dithiophene (BDTT) as the electron donor and the new electron acceptors quinoxaline (Qx) or phenanthrenequinoxaline (phQx), were synthesized with Stille cross‐coupling reactions. The number‐averaged molecular weights (Mn) of PQx and PphQx were found to be 25.1 and 23.2 kDa, respectively, with a dispersity of 2.6. The band‐gap energies of PQx and PphQx are 1.82 and 1.75 eV, respectively. These results indicate that, because phQx units have highly planar structures, their inclusion in D‐A polymers will be a very effective method for increasing the polymers' effective conjugation lengths. The hole mobilities of PQx and PphQx were determined to be 5.0 × 10?5 and 2.2 × 10?4 cm2 V?1 s?1, respectively. A polymer solar cell device prepared with PphQx as the active layer was found to exhibit a power conversion efficiency (PCE) of 5.03%; thus, the introduction of phQx units enhanced both the short circuit current density and PCE of the device. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2804–2810 相似文献
994.
Chi‐Ming Ho Dr. Sammi King‐Woon Yau Dr. Chun‐Nam Lok Dr. Man‐Ho So Chi‐Ming Che Prof. 《化学:亚洲杂志》2010,5(2):285-293
The oxidative dissolution of silver nanoparticles (AgNPs) plays an important role in the synthesis of well‐defined nanostructured materials, and may be responsible for their activities in biological systems. In this study, we use stopped‐flow spectrophotometry to investigate the kinetics and mechanism of the oxidative dissolution of AgNPs by H2O2 in quasi‐physiological conditions. Our results show that the reaction is first order with respect to both [Ag0] and [H2O2], and parallel pathways that involve the oxidation of H2O2 and HO2? are proposed. The order of the reaction is independent of the size of the AgNPs (≈5–20 nm). The rate of dissolution increases with increasing pH from 6.0 to 8.5. At 298 K and I=0.1 M , the value of kb is five orders of magnitude higher than that of ka (where ka and kb are the rate constants for the oxidative dissolution of AgNPs by H2O2 and HO2?, respectively). In addition, the effects of surface coating and the presence of halide ions on the dissolution rates are investigated. A possible mechanism for the oxidative dissolution of AgNPs by H2O2 is proposed. We further demonstrate that the toxicities of AgNPs in both bacteria and mammalian cells are enhanced in the presence of H2O2, thereby highlighting the biological relevance of investigating the oxidative dissolution of AgNPs. 相似文献
995.
E. V. Nam A. E. Zhirnov E. A. Litmanovich N. S. Melik-Nubarov I. D. Grozdova 《Polymer Science Series A》2010,52(9):907-913
Covalent modification of poly(alkylene oxides), block copolymers of ethylene oxide and propylene oxide with M ∼ 2000, with fluororescein isothiocyanate or 7-nitrobenzo-2-oxadiazole taken in a ratio of 0.6–1.0 mol of label/mole of polymer
leads to changes in the physical state of polymers and their solubility in water decreases, as well as the partition coefficient
in the hexane-water system and the critical concentration of aggregation and dimensions of the formed particles. 相似文献
996.
Sungho Cho Hyungwon Lee Chiwoong Moon Jaehyung Kim Jikoon Park Gyerok Jeon Rena Lee Sanghee Nam 《Journal of Sol-Gel Science and Technology》2010,53(2):171-175
Fine Eu3+-doped lutetium oxide (Lu2O3:Eu3+) nanophosphor were synthesized using a low-temperature solution-combustion method in a methyl-alcohol solution. The characteristics
of the nanophosphors synthesized at various sintering temperatures with different Eu3+ concentrations were analyzed to determine the optimum synthesis conditions. Thermogravimetry/differential thermal analysis
showed that Lu2O3:Eu3+ crystallizes completely when the dry powder is sintered at 500 °C. The Lu2O3:Eu3+ crystals had a cubic structure and monoclinic phase. The peak position of the luminescence spectrum did not differ with the
concentration of Eu or the sintering temperature or atmosphere, whereas the luminescence intensity was strongly dependent
on the concentration and sintering conditions. 相似文献
997.
Seung‐Mann Paek Dr. Nam‐Jung Kim Dongyun Shin Dr. Jae‐Kyung Jung Prof. Jong‐Wha Jung Dr. Dong‐Jo Chang Dr. Hyunyoung Moon Young‐Ger Suh Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(15):4623-4628
Highly concise asymmetric total syntheses of (+)‐tetrabenazine ( 1 ), a drug for the treatment of chorea associated with Huntington’s disease, and of (+)‐α‐dihydrotetrabenazine ( 2 ), an active metabolite of 1 , have been accomplished. Our synthetic route features a trans‐selective enol etherification, followed by an unprecedented cation‐dependent aza‐Claisen rearrangement to establish the carbon framework and two stereogenic centers of tetrabenazine. The syntheses consist of seven steps (34 % overall yield) for (+)‐ 2 and eight steps (22 % overall yield) for (+)‐ 1 . 相似文献
998.
Lone S Kim SH Nam SW Park S Cheong IW 《Langmuir : the ACS journal of surfaces and colloids》2010,26(23):17975-17980
We present a simple fabrication of photo- and thermoresponsive microparticles with a narrow size distribution in the PDMS-based microfluidic device. The monodisperse water-in-oil (W/O) droplets of poly(N-isopropylacrylamide-co-spironaphthoxazine methacryloyl) (PNIPA-SPO) were formed at the T-junction channel of the device by adjusting the flow conditions of two immiscible solutions. Subsequently, the droplets were polymerized downstream of the channel under 365 nm UV irradiation in the presence of 2,2'-diethoxyacetophenone (DEAP, photoinitiator) and N,N'-methylenebisacrylamide (MBA, monomer and cross-linker). Being photosensitive, the polymerized microparticles progressively change their color when subjected to UV-vis irradiation. Above the LCST of the copolymer, the microparticles exhibited volume shrinkage accompanied by color deterioration. In addition, the UV light-driven clustering of the PNIPA-SPO copolymer was observed within the W/O droplet in the absence of photoinitiator, which contributed to variable microstructures from Janus to acorn-like and snowman-like morphologies. This work is the first attempt to unveil the photocontrolled asymmetric particle morphology by using the photoresponsive polymer. 相似文献
999.
Donghak Jang Ho Yong Lee Dr. Miae Park Seong Ryong Nam Dr. Jong‐In Hong Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(16):4836-4842
Two‐component amphiphiles based on hydrogen‐bonded complexes between terephthaloylbisalanine (H2TBA) and dodecylamine (DA) are able to self‐assemble into nano‐ and microsized superstructures in an aqueous solvent. It is possible to modulate the morphology of these self‐assembled superstructures by modifying the composition of the complexes, which can be achieved by changing the molar ratio of the two components or by changing the chirality of H2TBA. For example, right‐handed microhelical ribbon structures were formed with L ‐TBA1.0DA2.0, whereas in the case of rac‐TBA1.0DA2.0, flat ribbonlike structures were observed. Although L ‐TBA1.0DA1.0 exhibited entangled fibrous structures, rac‐TBA1.0DA1.0 exhibited wire structures. Different ratios of H2TBA and DA were self‐assembled into fiber‐, wire‐, and tubulelike superstructures, as well as monoclinic, columnar, and lamellar aggregation patterns. The self‐assembled superstructures of TBAxDAy were significantly changed by adding metal ions. Transition metal (CdII, CoII, and ZnII) complexes with L ‐TBAxDAy self‐assembled into rod‐, tubule‐, wire‐, and platelike superstructures. Metal‐ion complexes with rac‐TBAxDAy exhibited different superstructures. Our work suggests that it is possible to fabricate a wide variety of nano‐ and microsized superstructures by using two‐ and three‐component amphiphiles. 相似文献
1000.
Yuhong Oh Donggi Ahn Seunghoon Nam Byungwoo Park 《Journal of Solid State Electrochemistry》2010,14(7):1235-1240
The electrochemical properties of nanoscale Al2O3-coated LiCoO2 thin films were examined as a function of the coating coverage. Al2O3-coated LiCoO2 films showed enhanced cycle-life performance with increasing degree of coating coverage, which was attributed to the suppression
of Co dissolution and F− concentration in the electrolyte. Moreover, an Al2O3-coating layer with partial coverage clearly improved the electrochemical properties, even at 60 °C or with a water-contaminated
electrolyte. Even though metal-oxide coating on LiCoO2 has been actively investigated, the mechanisms of nanoscale coating have yet to be clearly identified. In this article, surface
analysis suggested that the Al2O3-coating layer had transformed to an AlF3
∙3H2O layer during cycling, which inhibited the generation of HF by scavenging H2O molecules present in the electrolyte. 相似文献