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51.
Saitô H Mikami J Yamaguchi S Tanio M Kira A Arakawa T Yamamoto K Tuzi S 《Magnetic resonance in chemistry : MRC》2004,42(2):218-230
We have so far demonstrated that well-resolved and site-specifically assigned (13)C peaks as recorded by site-directed NMR study on (13)C-labeled membrane proteins can serve as a convenient probe to reveal their local conformation and dynamics. We attempted here to clarify the extent to which (13)C NMR spectra of (13)C-labeled fully hydrated bacteriorhodopsin (bR) as a typical membrane protein are visible or well resolved in the presence of inherent fluctuation motions with frequency of 10(2)-10(8) Hz, especially at the membrane surfaces. Accordingly, we estimated the relative proportion of (13)C NMR signals from the surface areas with and without peak suppression by the accelerated transverse relaxation effect by surface-bound Mn(2+) ions, which could be effective for residues within 8.7 angstroms of the membrane surface. It turned out that the experimental findings are consistent with the predicted amount of amino acid residues under consideration located within 8.7 angstroms of the surface for [1-(13)C]Val- and Ile-labeled bR and also [3-(13)C]Ala-bR. In contrast, (13)C NMR peaks from such surfaces area are almost completely or partially suppressed for [1-(13)C]Gly-, Ala-, Leu-, Phe- and Trp-labeled bR, as a result of plausible interference of the fluctuation frequency with frequency of magic angle spinning (10(4) Hz). We further assigned several (13)C NMR signals of [1-(13)C] Val-, Trp- and Ile-labeled bR on the basis of a variety of site-directed mutants with reference to those of the wild type. Further, we recorded the (13)C NMR of bR in lipid bilayers to search for the optimal conditions to be able to obtain signals with the highest peak intensities and spectral resolution. Backbone dynamics turn out to be essential for recording (13)C NMR spectra so as to escape from motional frequencies of the order of 10(4)-10(5) Hz, either in the direction of accelerated fluctuation or slowed motions in the direction of forming the 2D array. 相似文献
52.
Katsuhiko Saido Takeshi Kuroki Tadashi Ikemura Makoto Kirisawa 《Journal of Analytical and Applied Pyrolysis》1985,9(1):29-34
In order to clarify the mechanism conferring heat resistance on phthalate esters, those with a substituent on the β-carbon atom, such as bis(2-aminobutyl) phthalate, bis(2-nitrobutyl) phthalate, bis(2,4-diphenylbutyl) phthalate and dineopentyl phthalate, were synthesized and their thermal stabilities were studied by thermogravimetry and differential thermal analysis. The analytical results for these phthalate esters were compared with those for dibutyl phthalate, with a straight alkyl chain. As the temperatures required for a 3% weight loss of phthalate esters with a substituent, an electron-donating group (amino group) or an electron-accepting group (nitro group) on the β-carbon atom move to the higher end of the range, the effect of the adjacent group was recognized. The presence of a phenyl group in phthalate esters considerably improved the heat resistance. It is considered that the high heat resistance of bis(2,4-diphenylbutyl) phthalate is due to the obstruction of the planar configuration for cis elimination by the phenyl group and hindrance by the phenyl group of the formation of the six-membered cyclic transition state owing to the interaction between non-bondable molecules. 相似文献
53.
Three newly prepared [Ni(mnt)2] complexes, (HMTTF)[Ni(mnt)2], (ChSTF)[Ni(mnt)2], and (DBTTF)2[Ni(mnt)2], are reported (DBTTF = dibenzotetrathiafulvalene, ChSTF = 2,3-cyclohexylenedithio-1,4-dithia-5,8-diselanafulvalene, HMTTF = bis(trimethylene)-tetrathiafulvalene, and mnt = maleonitrile dithiolate). The former two compounds have usual DA-type (D = donor, A = acceptor) mixed stacks, whereas the DBTTF complex has DDDDAA-type 6-fold columns. These compounds are electrical insulators, but the HMTTF and ChSTF complexes exhibit chiT minima at 16 and 55 K, respectively, followed by chiT peaks at 8 and 16 K. Below these temperatures the ESR signal disappears, indicating antiferromagnetic transitions. The origin of the ferromagnetic interaction is explained either from the difference of the g values between the donor and the anion or from the intrinsic ferromagnetic interaction of the [Ni(mnt)2] anions. 相似文献
54.
Chemical ionization (CI) and fast atom bombardment (FAB) mass spectra of simple bifunctional aromatic compounds were compared. Some significant differences were revealed with respect to the site of protonation and extent of fragmentations. Unlike conventional CI ionization, the protonated molecule formation by FAB could not be accounted for by ordinary proton transfer reactions in the gas phase. The observed ions under FAB conditions appear to be regulated by proton exchange reactions through frequent collisions in some particular region between the matrix and the gas phase. 相似文献
55.
A catalytic immuno-reactor for the determination of human serum albumin (HSA) was constructed by using immobilized antibody and an amperometric detector. A sandwich assay with hemin-labeled antibody to catalyze the decomposition of hydrogen peroxide was used, the catalytic activity of the hemin-antibody conjugate being determined by measuring the decrease in hydrogen peroxide concentration. The reaction of hemin-labeled antibody with antigen was complete within 30 min and the current decrease was correlated with the HSA concentration. The relative standard deviation was about 9% at an HSA concentration of 1 mg ml?1. 相似文献
56.
Asymmetric hydrogenation of dehydrodipeptides, α-acylaminocinnamoyl-(S)-amino esters, catalyzed by rhodium complexes with chiral diphosphines gave either (R)-N-acylphenylalanyl-(S)-amino esters or (S)-N-acylphenylalanyl-(S)-amino esters with high diastereomeric purity up to 98–99% on using proper chiral ligands. 相似文献
57.
58.
Tadashi Kon Tetsuro Kobayashi Shoichi Kitamura Keiichiro Nakamura Shunji Adachi 《Zeitschrift fur Physik C Particles and Fields》1994,61(2):239-246
In the framework of the minimal supersymmetric standard model (MSSM) and theR-parity breaking model (RBM), we investigate production processes of the scalar top (stop) at HERA energies. These models are characterized by the possible existence of the light stop whose mass is lighter than those of the top quark and the other squarks. It is shown that in the MSSM the stop pair production via boson-gluon fusion gives a sizeable cross section and the most serious background $ep \to ec\bar cX$ could be suppressed by appropriate kinematical cuts. We also show that in the RBM the stop is singly produced in the neutral current processes and we have a clear signal as a sharp peak in the Bjorken parameterx distribution of the scattered electron. 相似文献
59.
W. K. A. Kumuduni Y. Nakata T. Okada M. Maeda 《Applied physics. B, Lasers and optics》1994,58(4):289-294
One-dimensional imaging laser-induced fluorescence spectroscopy has been used for in-situ measurements of spatial distributions of YO molecules produced during the ArF-laser ablation of YBa2 Cu3 O
7–x
in vacuum and oxygen gas environment. The time-integrated angular distribution of particles ejected in vacuum has a cos
n
form, where 11 <n < 13. When oxygen gas was introduced, YO molecules were confined in a smaller volume, and temporal changes of their spatial distribution were interpreted in terms of blast-wave formation. 相似文献
60.