Cylindrical spike model for the formation of diamondlike thin films by ion deposition

T /n_S of n_T rearrangements and n_S atoms in the spike volume as the crucial parameter characterizing the ability of a given ion–target combination to achieve complete rearrangement of the spike volume. n_T/n_S>1 is the optimum condition for diamondlike film growth. For aC films the ion energy dependence of n_T/n_S agrees well with the measured sp³ bond fraction. For Ar⁺-ion-assisted deposition of aC we find n_T/n_S>1 above 50 eV with no pronounced ion energy dependence. Furthermore, our model predicts optimum conditions for the formation of cubic boron nitride between 50 eV and 3 keV. Accepted: 14 October 1997     

Recent trends and open issues in reverse engineering

This paper discusses recent trends in the field of reverse engineering, particularly those highlighted at the Second Working Conference on Reverse Engineering, held in July 1995. The trends observed include increased orientation toward tasks, grounding in complex real-world applications, guidance from empirical study, analysis of non-code sources, and increased formalization. The paper also summarizes open research issues and provides pointers to future events and sources of information in this area.     

Surface characterization of fluorinated polymers (PTFE, PVDF, PFA) for use in ultratrace analysis

Surface characterization of new unused PTFE, PFA and PVDF labware has been carried out by light microscopy, scanning electron microscopy, profilometry and atomic force microscopy. It has been found that in spite of higher micro-roughness, PFA exhibits the lowest nano-roughness and hence seems best suited as vessel material for relatively mild pressureless chemical operations for sample preparation of ultrapure substances, as container material for storage of ultrapure liquids, and for transport of such liquids, e.g., from the producer in the chemical to the end user in the microelectronics industry. This suitability refers only to the surface quality of the investigated materials. PTFE-surfaces, due to the sintering process of production, exhibit the most unfavourable surface quality of the investigated fluorinated polymers.     

Chlorokomplexe von Cu2+ und Ni2+ in Dimethylformamid

Zusammenfassung Durch spektrophotometrische Messungen in Dimethylformamid (DMF) werden die Koordinationsformen [CuCl]⁺ und [CuCl₃]^– sowie [NiCl]⁺, [NiCl₃]^– und [NiCl₄]^2– nachgewiesen. Bei Nickel(II)-chlorid und Kupfer(II)-chlorid wird Autokomplexbildung diskutiert. Die Solvate [Cu(DMF)₄] (ClO₄)₂ und [Ni(DMF)₆] (ClO₄)₂ werden isoliert.Im Zuge der Untersuchungen über Chlorokomplexe von Ionen der Übergangsmetalle^{1, 2} in nichtwäßrigen Lösungsmitteln wurden die Spektren der Lösungen von Kupfer(II)- und Nikkel(II)-perchlorat inDMF in Gegenwart verschiedener Mengen Tetraäthylammoniumchlorid aufgenommen.Mit 5 Abbildungen     

Crystal and molecular structure of crenatine carbonate

The crystal and molecular structure of 1-ethyl-4-methoxy-9H-pyrido[3,4b]indole (crenatine) carbonate C₁₄H₁₄N₂O·H₂CO₃, (MS, m/z 226)M _R 288.3, a-carboline alkaloid, has been determined from X-ray diffraction data. The compound crystallizes in the space group Pbca with cell parameters:a=11.616(4),b=18.450(8),c=12.992(5)Å,V=2784(2)ų,Z=8,D _calc=1.375 g cm^–3, (MoK)=0.71069Å,(Mo K)=0.94 cm^–1,F(000)=1216,R/R _w =8.2/10.3% for 1099 reflections. The ring system of the-carboline nucleus is planar. The title compound shows a two center hydrogen bond between the indole N-H group and the oxygen atom of a carbonate group. The structure does not display hydrogen bonding between-carboline groups but rather a bonding network involving the carbonate group.     

Ray Theory of the Diffraction of Sound by an Inhomogeneous Membrane

Present address: Department of Applied Mathematics and Theoretical Physics, University of Cambridge, Silver Street, Cambridge CB3 9EW, U.K. In this paper, a ray approach is developed for calculating theacoustic radiation into a fluid generated by a localized forcingon an elastic boundary. We consider here the case of fluid-loadedmembrane with a rigid line-mass distribution subject to infiniteplane-wave incidence from the fluid. It is demonstrated howray methods can be used to determine each of the constituentwaves of the scattered acoustic field, showing that non-uniformitiesarise whenever two such waves have tangential wavefronts. Transitionanalyses are presented to remove these non-uniformities, resultingin the prediction of beam-like structures in the scattered field.     

Optimal Estimation Rules for Functions of High Smoothness

Let I denote a linear functional defined on the space of 2-periodiccontinuous functions. It is an often used technique to approximateI[f] by I?intpol [f], where intpol [f] means a trigonometricinterpolation polynomial of f. The aim of this paper is tomakeclear that this technique is almost optimal for functions ofhigh smoothness. As a by-product we obtain a new proof of aresult of Schoenberg (1972) and v. Golitschek (1972) concerninglimits of interpolating spline functions.     

Analysis, synthesis, and perception of voice quality variations among female and male talkers

Voice quality variations include a set of voicing sound source modifications ranging from laryngealized to normal to breathy phonation. Analysis of reiterant imitations of two sentences by ten female and six male talkers has shown that the potential acoustic cues to this type of voice quality variation include: (1) increases to the relative amplitude of the fundamental frequency component as open quotient increases; (2) increases to the amount of aspiration noise that replaces higher frequency harmonics as the arytenoids become more separated; (3) increases to lower formant bandwidths; and (4) introduction of extra pole zeros in the vocal-tract transfer function associated with tracheal coupling. Perceptual validation of the relative importance of these cues for signaling a breathy voice quality has been accomplished using a new voicing source model for synthesis of more natural male and female voices. The new formant synthesizer, KLSYN88, is fully documented here. Results of the perception study indicate that, contrary to previous research which emphasizes the importance of increased amplitude of the fundamental component, aspiration noise is perceptually most important. Without its presence, increases to the fundamental component may induce the sensation of nasality in a high-pitched voice. Further results of the acoustic analysis include the observations that: (1) over the course of a sentence, the acoustic manifestations of breathiness vary considerably--tending to increase for unstressed syllables, in utterance-final syllables, and at the margins of voiceless consonants; (2) on average, females are more breathy than males, but there are very large differences between subjects within each gender; (3) many utterances appear to end in a "breathy-laryngealized" type of vibration; and (4) diplophonic irregularities in the timing of glottal periods occur frequently, especially at the end of an utterance. Diplophonia and other deviations from perfect periodicity may be important aspects of naturalness in synthesis.     

Deposition of copper oxide (Cu2O,CuO) thin films at high temperatures by plasma-enhanced CVD

Copper-oxide films are deposited by plasma-enhanced CVD using copper acetylacetonate as a precursor. The influence of various experimental parameters on deposition rate, film composition and resistivity have been studied. The substrate temperature and the bias are the parameters which affect these properties the most. An increase of the substrate temperature changes the phases of the deposit from Cu₂O-CuO over Cu₂O to Cu. At temperatures 500° C the deposition rates are high but the films consist mainly of metallic Cu. A negative bias enhances the deposition rate only slightly but has a strong effect on the film composition and can completely balance the oxygen deficiency. At a bias of –120 V the films consist of pure CuO even at temperatures 500° C.