The dual reciprocity boundary elements method for the linear and nonlinear two‐dimensional time‐fractional partial differential equations

In this paper, we apply the dual reciprocity boundary elements method for the numerical solution of two‐dimensional linear and nonlinear time‐fractional modified anomalous subdiffusion equations and time‐fractional convection–diffusion equation. The fractional derivative of problems is described in the Riemann–Liouville and Caputo senses. We employ the linear radial basis function for interpolation of the nonlinear, inhomogeneous and time derivative terms. This method is improved by using a predictor–corrector scheme to overcome the nonlinearity which appears in the nonlinear problems under consideration. The accuracy and efficiency of the proposed schemes are checked by five test problems. The proposed method is employed for solving some examples in two dimensions on unit square and also in complex regions to demonstrate the efficiency of the new technique. Copyright © 2016 John Wiley & Sons, Ltd.     

Mixed Convection-Radiation in Power-Law Fluids Along a NOn-Isothermal Wedge in a Porous Medium with Variable Permeability

A boundary layer analysis has been presented for the interaction of mixed convection with thermal radiation in laminar boundary flow from a vertical wedge in a porous medium saturated with a power-law type non-Newtonian incorporating the variation of permeability and thermal conductivity. The transformed conservation laws are solved numerically for the case of variable surface temperature conditions. The combined convection non-similar parameter we note that =0 and 1 correspond to pure free and forced convection cases. The Rosseland approximation is used to describe the radiative heat flux in energy equation. Velocity and temperature profiles as well as the local Nusselt number are presented.     

Characterization of Mazuj galls of Quercus infectoria tree as green corrosion and scale inhibitor for effective treatment of cooling water systems

Research on Chemical Intermediates - The corrosion and scale inhibition efficiency of Mazuj gall extract in simulated cooling water has been evaluated. Potentiodynamic polarization, electrochemical...     

Organic contamination in clams,Venerupis aurea laeta and Cerastoderma edule glaucum,from Sicily (Italy)

Two species of edible clams Venerupis aurea laeta and Cerastoderma edule glaucum from Ganzirri Lake (Sicily, Italy) were investigated to determine OCP and PCB residues by GC-MS. Thirty-five samples were examined for two years in order to perform: a) their actual contamination; b) the daily dietary exposure of seafood consumers to the pollutants in question. In all the clams analysed in this study, PCB and OCP (4,4′-DDE) residues are always below the limits fixed by law. It seems that there is some seasonality of concentrations observed. In fact the more high concentrations of residues are detected in the hot months, for both species and years. Given the consumption of clams and the values obtained in this study for the two species analysed, it is possible estimate that the average daily dietary intake of NDL-PCB and of 4,4′-DDE for adults is really low.     

Facile preparation of 3-substituted 2-quinazolinones via electrogenerated base

A new series of 3,4-disubstituted quinazolin-2-ones, with potential T-type calcium channel antagonist activity, and new 4-methylene-quinazolin-2-ones, promising catalysts as N-heterocyclic olefins, have been prepared in good yield by a simple reaction between 2-aminobenzophenone, or 2-aminoacetophenone, and cyanomethyl anion electrogenerated by acetonitrile reduction at a graphite electrode, followed by the addition of different organic isocyanates and subsequent heterocyclization.     

A simple homemade spectrophotometer

A simple portable spectrophotometer was constructed and used to perform analytical experiments. The developed model uses available tools and materials such as light emitting diode lamps, compact discs, plastic and cardboard boxes and a cell phone camera to build a design that illustrates the major components of spectrophotometers. The spectra of serial concentrations of KMnO₄ (50?600 μM) were recorded and the values of absorbance were extracted at λ_max to build the calibration curve. A linear relationship between the concentration and absorbance was obtained with the coefficient of determination 0.994. The model was also utilized to study the spectra of KMnO₄, phenolphthalein and bromothymol blue in comparison with a Shimadzu UV-1800 spectrophotometer as a reference instrument. In spite of the differences in the observed spectra, the recorded λ_max were almost identical to those measured by the developed model. The model was successfully used to determine the concentration of sodium alendronate through ligand-exchange complexation with ferric salicylate.     

Microstructure characterization and magnetic behavior of NiAlxFe2−xO4 and Ni1−yMnyAl0.2Fe1.8O4 ferrites

NiAl_xFe_2−xO₄ and Ni_1−yMn_yAl_0.2Fe_1.8O₄ ferrites were prepared by the conventional ceramic method and were characterized by X-ray diffraction, scanning electron microscopy, and magnetic measurements. The single spinel phase was confirmed for all prepared samples. A proper explanation of data is possible if the Al³⁺ ions are assumed to replace Fe³⁺ ions in the A and B sites simultaneously for NiAl_xFe_2−xO₄ ferrites, and if the Mn²⁺ ions are assumed to replace Ni²⁺ ions in the B sites for Ni_1−yMn_yAl_0.2Fe_1.8O₄ ferrites. Microstructural factors play an important role in the magnetic behavior of Ni_1−yMn_yAl_0.2Fe_1.8O₄ ferrites with large Mn²⁺ content.