Preparation and Characterization of Reduced Graphene Oxide–Fe3O4 Nanocomposites in Polyacrylamide

Russian Journal of Physical Chemistry A - A hydrogel nanocomposite composed of reduced graphene oxide (RGO), iron oxide (Fe3O4) nanoparticles, and polyacrylamide (PAM) was prepared using radical...     

Ca掺杂的氧化铍纳米管吸附H2O和NH3的选择传感特

通过密度泛函计算, 借助NH₃和H₂O分子对未掺杂以及钙掺杂的BeO碳纳米管的结构和电传导性进行了研究. 结果发现,NH₃和H₂O分子可以吸附在纳米管侧壁的Be原子上,吸附能分别为约36.1和39.0 kcal/mol. 态密度分析显示BeO纳米管的电传导性在吸附后稍有变化. 对于NH₃和H₂O分子,纳米管表面的钙原子替换Be原子可使吸附能分别增加约7.4和14.7 kcal/mol. 与未掺杂纳米管不同的是,钙掺杂BeONT吸附NH₃和H₂O分子的电传导性更加敏感,且H₂O分子比NH₃分子更敏感.     

First results of movable limiter experiments and its effects on the tokamak plasma confinement

Limiters play a number of roles in the tokamak operation. It serves primarily to protect the wall from the plasma when there are disruptions, runaway electrons, or other instabilities and also the limiters localize the plasma–surface interaction. In this research, we presented the first results of movable limiter experiments and its effects on the tokamak plasma confinement. For this purpose, we designed, constructed, and installed a movable localized poloidal limiter, and then measured the effects of limiter position on the time intervals of plasma parameters such as plasma density, temperature, and energy confinement time. The results of effects of the movable limiter experiments on plasma confinement.     

Segmental Dynamics in net -poly(methyl methacrylate)- co -poly(n-butyl acrylate) Copolymer Networks

Dynamic mechanical spectroscopy and differential scanning calorimetry investigations of segmental dynamics are reported for net-poly(methyl methacrylate)-co-poly(n-butyl acrylate) copolymer networks. Three characteristic temperatures, namely, Vogel (T_∞), glass transition (T _g ), and crossover (T _c ), were used to define cooperativity range and a new reduced temperature parameter (Solidness, S). The results showed that broadness of the α -dispersion (glass transition) and cooperativity length scale at the glass transition temperature decreased with increasing butyl acrylate content and T _g -scaled temperature dependence of the relaxation time (fragility). However, the cooperativity range (T _c –T_∞), decreased with increasing fragility index. Furthermore, the solidness at T _g (S(T _g )) was nearly independent of chemical structure of the samples. Finally, a correlation was found between two measures of cooperativity length scale in the glass transition region, namely, average volume of cooperatively rearranging regions, V _CRR , and the number of basic units in an act of rearrangement in the glass transition region, Z(T _g ), determined from two completely independent experimental techniques.     

Injection/suction boundary conditions for fluid–structure interaction simulations in incompressible flow

This paper presents the analysis of injection/suction boundary conditions in the context of the fluid–structure interactions simulation of the incompressible turbulent flow. First, the equations used in the modelling of the fluid and the structure are presented, as well as the numerical methods used in the corresponding solvers. Injection/suction boundary conditions are then presented with details of different implementation alternatives. Arbitrary Lagrangian–Eulerian (ALE) approach was also implemented in order to test the injection/suction boundary conditions. Numerical tests are performed where injection/suction boundary conditions are compared to ALE simulations. These tests include forced movement of the structure and two‐degrees‐of‐freedom structure model simulations. Copyright © 2002 John Wiley & Sons, Ltd.     

Kinetic spectrophotometric determination of sulfide using whole kinetic curve and a fixed time method

The univariate and multivariate calibration method was applied for the determination of sulfide based on the addition reaction of sulfide with new fuchsin at pH 8 and 25°C. The decrease in absorbance of new fuchsin at 540 nm over a fixed time is proportional to the concentration of sulfide over the range of 0.05-2.5 μg ml⁻¹. The experimental calibration matrix for partial least squares calibration (PLS) method was designed with 20 samples. The cross-validation method was used for selecting the number of factors. The root mean square difference (RMSD) was 0.0843. The effects of various cations and anions on sulfide determination have been investigated.     

Novel Catalytic Acetylation of Alcohols with Preyssler's Anion, [NaP5Wa30O110]14– 1

Sodium 30-tungstopentaphosphate, the so-called Preyssler's anion with a formula of [NaP₅W₃₀O₁₁₀]^14– (I) catalyzes the acetylation of alcohols (C _n H_{2n + 1}OH, n = 2, 3, 4, 5) with acetic acid. High yield is obtained with I as pure acid or supported on silica. Both homogeneous and heterogeneous catalysts are discussed and compared. H₁₄[NaP₅W₃₀O₁₁₀], abbreviated as H₁₄-P₅, under homogeneous conditions, as well as supported on silica (heterogeneous conditions) is found to be an excellent catalyst. Our data indicate that, when the ammonium salt of I is employed as the catalyst, the yield increases as the alcohol carbon-chain is increased. This behavior is found to be quite general. The catalysts can be easily recovered and recycled with retention of their initial structure and activity.     

Kröhnke pyridines: an efficient solvent-free synthesis of 2,4,6-triarylpyridines

A simple and efficient synthesis of 2,4,6-triarylpyridines is described from a novel reaction between chalcones and ammonium acetate under solvent-free conditions in excellent yields.     

Synthesis of Novel 1H‐Imidazol[1,2‐a]Indeno[2,1‐e]Pyridine‐6(5H)‐Ones Derivatives via a One‐Pot Four‐Component Condensation Reaction

1H‐imidazol[1,2‐a]indeno[2,1‐e]pyridine‐6(5H)‐ones derivatives were synthesized in a one‐pot four‐component condensation of corresponding aldehydes, 1,3‐indandione, diamine, and nitro ketene dithioacetal using KAl(SO₄)₂·12H₂O (alum) as nontoxic, reusable, inexpensive and easily available catalyst in good to excellent yields. This green protocol provides a powerful entry into fused polycyclic structures related to bioactive heterocycles.