Synthesis and characterization of a novel terpolymer based on L‐lactide,glycolide, and trimethylene carbonate for specific medical applications

The bioresorbable new terpolymers of L ‐lactide, glycolide, and trimethylene carbonate were synthesized via ring‐opening polymerization reaction of the cyclic monomers using Stannous octoate as initiator. Glycolide and L ‐lactide were prepared from their parent acids and then purified by multiple re‐crystallization from ethyl acetate. The thermal and mechanical properties of this polymer were characterized by means of thermogravimetry, differential scanning calorimetry, stress–strain measurements, and dynamic mechanical analysis. The glass transition temperature of the terpolymers changed from 33 to 51°C with composition in a predictable manner. The rheological properties of copolymers and molecular weight of each copolymer were determined showing good processability for making fibers. Using a mini‐extruder, it was possible to produce some filaments. The filaments produced at 140°C had appropriate ductility. The in vitro measurements, specifying the biological properties were also carried out. The sample with monomer composition LLA:GA:TMC = 60:34:6 showed a slower degradation rate than the one with LLA:GA:TMC = 54:34:12. The low‐toxicity bioresorbable terpolymers with good rheological and in vitro properties are the promising new materials for biomedical applications specially a new suture formulation. Copyright © 2011 John Wiley & Sons, Ltd.     

Pure annihilation decay of strange beauty meson into two charm heavy mesons

In this study, the heavy to heavy decay of \begin{document}$ B^0_s\rightarrow D^{*+}D^- $\end{document} is evaluated through the factorization approach by using the final state interaction as an effective correction. Under the factorization approach, this decay mode occurs only through the annihilation process, so a small amount is produced. Feynman's rules state that six meson pairs can be assumed for the intermediate states before the final meson pairs are produced. By taking into account the effects of twelve final state interaction diagrams in the calculations, a significant correction is obtained. These effects correct the value of the branching ratio obtained by the pure factorization approach from \begin{document}$ (2.41\pm1.37)\times10^{-5} $\end{document} to \begin{document}$ (8.27\pm2.23)\times10^{-5} $\end{document}. The value obtained for the branching ratio of the \begin{document}$ B^0_s\rightarrow D^{*+}D^- $\end{document} decay is consistent with the experimental results.     

Evaluation of occupational noise pollution and attitudes of exposed workers in two metal industries

The purpose of the present study was to determined noise levels and to show the annoyance reaction, hearing loss, hearing impairment by the workers due to the occupational noise exposure according to Iran development of Environment （IDE） and also awareness about effects of noise and use of hearing protective devices （HPD） in the two manufacturing electronic equipment （metal） industries. The present study was carried out among industrial workers and included a sample of lao workers, site 1 （n = 52） and site 2 （n = 78） from two metal industries located in south eastern Iran province of Kerman. In order to attend the objectives of the current study, noise levels evaluation was determined throughout all different work stations in both industries. The results of the study revealed that noise levels in 75% of the stations are higher than limits used for assessment of noise for community response. The result of the study indicated that noise levels in the workplace are （66%） very high, （28%） high and only 6% low. Workers having higher education are much aware of the health impact due to occupational noise. Chi-square analysis indicated that the difference in educational background and not wearing HPD was significant and also a significant relationship was also observed between the impact of occupational noise on the health and education status. This research has clearly demonstrated that the workers in both the metal industries included in this study are at high risk of developing noise induced hearing loss and other associated ailments due to excessive occupational exposure to noise. There is a need to develop and apply a well-defined, comprehensive and enforceable training programs and noise regulation. The study revealed that the workers having higher education （9-12 grades） are much aware of the health impact due to occupational noise exposure. There is a need to establish a hearing conservation programs in both industries, the components of such program include noise assessment, use of hearing protection devices, audiometric and increasing awareness among the workers about the adverse effects of noise.     

FeNH4(SO4)2·12H2O (alum)-catalyzed preparation of 1,4-dihydropyridines: improved conditions for the Hantzsch reaction

Abstract  

FeNH₄(SO₄)₂·12H₂O (alum) efficiently catalyzes the one-pot three-component reaction of dimedone, aldehydes, and 3-aminocrotonate to afford 1,4-dihydropyridines. The work-up is easy, and the products are obtained in good to excellent yields and high purity.     

Monitoring the effects of homogeneity methanol/water/monomer on the mode of polymerization of styrene: dispersion polymerization versus emulsion polymerization

The polymerization of styrene (St) was carried out with varying amounts of methanol in aqueous medium. As methanol content decreased (to 50 %), the phase of polymerization mixture (methanol/water/monomer) changed to a heterogeneous state; the homogeneous state was obtained in samples that contain 75 and 100 % methanol. In order to verify the mechanism of polymerization in heterogeneous and homogeneous mixtures, the nucleus formation rate during polymerization, the stability equilibrium of the media and seeded particles, and the size of particles and their growth in polymerization were experimentally being monitored. With the homogeneous mixture in 75 wt% methanol, dumbbell, triangle, and peanut-like particles have been formed. On the other hand, the characteristics of the polymerization products were different from those typically obtained in the emulsion polymerization and in the sample with 100 wt% methanol dispersion polymerization. In the sample with 100 % methanol and in one with 50 % methanol, monodispersed spherical particles are formed in the final conversion. Thus, homogeneity in the aqueous methanol mixture can be a critical factor in determining the polymerization modes between dispersion and emulsion polymerization.     

One-pot,direct synthesis of acyl azides from carboxylic acids using Ph2PCl/I2/NaN3 reagent system

A mild,efficient and simple method for the preparation of acyl azides from carboxylic acids using chlorodiphenylphosphine in the presence of molecular iodine and sodium azide is described.     

Controlling morphology and structure of nanocrystalline cadmium sulfide (CdS) by tailoring solvothermal processing parameters

Cadmium sulfide (CdS) with different morphologies was successfully prepared by solvothermal process by controlling the processing parameters, including nature of precursor and solvent, reaction temperature and process time. X-ray diffraction patterns revealed that, in all cases highly pure and crystallized CdS with hexagonal structure were obtained. In addition, it was found that the processing parameters influence on preferable growth direction of CdS nanostructures. Field emission scanning electron microscope analysis showed that CdS nanowires with different aspect ratios were obtained (depending upon the reaction temperature and process time) in presence of sulfur powder and ethylenediamine, whereas CdS nanoparticles were produced by sulfur powder and ethanolamine. Moreover, CdS nanorods were prepared using thiourea and ethylenediamine. Transmission electron microscope image confirmed that CdS nanowire with one of the highest aspect ratio reported in the literature (i.e., 255) was achieved using sulfur powder and ethylenediamine at 200 °C reaction temperature for 72 h process time. UV–Vis absorption spectra of CdS nanostructures prepared under different conditions displayed a blue shift relative to that of bulk CdS due to the quantum size effect.     

Synthesis of Some Novel γ-Spirolactones

Summary. We report on the addition of dialkyl acetylenedicarboxylate to 1-alkylisatins or tryptanthrine in the presence of triphenylphosphine which leads to highly functionalised novel unsaturated -spirolactones.     

Shape invariance for the bent brane with two scalar fields

In this paper, we study the braneworld scenarios in the presence of two real scalar fields coupled by gravity. The first-order formalism for the bent brane (for both de Sitter and anti-de Sitter geometry), leads us to discuss the shape invariance method in the bent brane systems. So, by using the fluctuations of metric and fields we obtain the Schrödinger equation. Then we factorize the corresponding Hamiltonian in terms of multiplication of the first-order differential operators. These first-order operators lead us to obtain the energy spectrum with the help of shape invariance method.