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51.
In this work we consider a class of fourth-order nonlinear partial differential equation containing several un-specified coefficient functions of the dependent variable which encapsulates various mathematical models used, e.g. for describing the dynamics of thin liquid films. We determine the subclasses of these equations which are self-adjoint. By using a general theorem on conservation laws proved by one of the authors (NHI) we find conservation laws for some of these partial differential equations without classical Lagrangians.  相似文献   
52.

We propose a numerical method to obtain the transient and first passage time distributions of first- and second-order Multi-Regime Markov Fluid Queues (MRMFQ). The method relies on the observation that these transient measures can be computed via the stationary analysis of an auxiliary MRMFQ. This auxiliary MRMFQ is constructed from the original one, using sample path arguments, and has a larger cardinality stemming from the need to keep track of time. The conventional method to approximately model the deterministic time horizon is Erlangization. As an alternative, we propose the so-called ME-fication technique, in which a Concentrated Matrix Exponential (CME) distribution replaces the Erlang distribution for approximating deterministic time horizons. ME-fication results in much lower state-space dimensionalities for the auxiliary MRMFQ than would be with Erlangization. Numerical results are presented to validate the effectiveness of ME-fication along with the proposed numerical method.

  相似文献   
53.
The chain dynamics of short-chain perfluoropolyether melts confined in Vycor nanoporous media has been characterized by field cycling nuclear magnetic resonance relaxometry and the dipolar correlation effect. The slowdown of motions under confinement, leading to larger residual dipolar couplings, has been probed by looking at the quotient of stimulated and primary echoes. Using field cycling relaxometry, it has been shown that there is strong evidence of reptation-like motion, even for such short-chain polymers as shown by the frequency and molecular weight dependences of the spin-lattice relaxation time.  相似文献   
54.
Nonlinear dissipative systems display the full (3+1)D spatiotemporal dynamics of stable optical solitons. We review recent results that were obtained within the complex cubic-quintic Ginzburg-Landau equation model. Numerical simulations reveal the existence of stationary bell-shaped (3+1)D solitons for both anomalous and normal chromatic dispersion regimes, as well as the formation of double soliton complexes. We provide additional insight concerning the possible dynamics of these soliton complexes, consider collision cases between two solitons, and discuss the ways nonstationary evolution can lead to optical pattern formation.  相似文献   
55.
56.
    
The exact microscopic expression for the stress tensor in polymer liquids contains a tensor product of the the segment position vector with the total, intra- plus inter-chain, force acting on the segment. On the other hand, the widely accepted theory of viscoelasticity of polymer melts1) is based on the assumption, that contributions from interchain interactions to the viscosity of polymer melts is negligible relative to the effectively intrachain entropic interactions. Starting from the exact Green-Kubo formula for the viscosity, the Rouse dynamic correlation functions, and Newton's second law, we show that the intrachain assumption is inadequate. Rather, the intrachain and interchain forces acting on polymer segments cancel each other largely. The intrachain contribution therefore cannot be dominant as anticipated in the usual treatment1), or, in other words, the interchain contribution cannot be ignored. The main contribution to viscoelastic properties of polymer melts can only arise from a part of the total stress tensor as already suggested by M. Fixman based on a different argument2). It is concluded that the viscosity is of a purely interchain nature, and is determined by the tensor product of the vector connecting the centers-of-mass of neighboring macromolecules on the one hand, and the total force by which macromolecules interact, on the other, just in the case of simple liquids.  相似文献   
57.
    
Summary: The paper deals with the question whether the tube/reptation model of polymer chain dynamics is compatible with general laws of statistical physics. Based on a relation between the mean squared fluctuation of the number of segments in a given volume element and the isothermal compressibility of the polymer system, it follows straightforwardly that the tube/reptation model predicts fluctuations larger than permitted by thermodynamics on the time scale t ≳ τR, where τR is the Rouse relaxation time.  相似文献   
58.
    
We used 1H nuclear magnetic resonance pulsed‐field gradient to study the self‐diffusion of polyethylene glycol (PEG) and ions in a mixture of PEG and imidazolium bis(mandelato)borate ionic liquids (ILs) at IL concentrations from 0 to 10 wt% and temperatures from 295 to 370 K. PEG behaves as a solvent for these ILs, allowing observation of separate lines in 1H NMR spectra assigned to the cation and anion as well as to PEG. The diffusion coefficients of PEG, as well as the imidazolium cation and bis(mandelato)borate (BMB) anion, differ under all experimental conditions tested. This demonstrates that the IL in the mixture is present in at least a partially dissociated state, while the lifetimes of the associated states of the ions and ions with PEG are less than ~30 ms. Generally, increasing the concentration of the IL leads to a decrease in the diffusion coefficients of PEG and both ions. The diffusion coefficient of the anion is less than that of the cation; the molecular mass dependence of diffusion of ions can be described by the Stokes–Einstein model. NMR chemical shift alteration analysis showed that the presence of PEG changes mainly the chemical shifts of protons belonging to imidazole ring of the cation, while chemical shifts of protons of anions and PEG remain unchanged. This demonstrated that the imidazolium cation interacts mainly with PEG, which most probably occurs through the oxygen of PEG and the imidazole ring. The BMB anion does not strongly interact with PEG, but it may be indirectly affected by PEG through interaction with the cation, which directly interacts with PEG. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
59.
Conservation laws and exact solutions of nonlinear differential equations describing diffusion phenomena in anisotropic media with external sources are constructed. The construction is based on the method of nonlinear self-adjointness. Numerous exact solutions are obtained by using the recent method of conservation laws. These solutions are different from group invariant solutions and can be useful for investigating diffusion phenomena in complex media, e.g. in oil industry.  相似文献   
60.
We report the discovery of a quantization of the separation between phase-locked soliton pairs that is related to the radiation waves known as Kelly sidebands, in a passively mode-locked fiber ring laser. Our numerical simulations that predict this phenomenon have been confirmed by our experimental results.  相似文献   
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