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31.
Lie group analysis of nonlinear differential equations reveals existence of singularities provided by invariant solutions and invisible from the form of the equation in question. We call them internal singularities in contrast with external singularities manifested by the form of the equation. It is illustrated by way of examples that internal singularities are useful for analyzing a behaviour of solutions of nonlinear differential equations near external singularities.  相似文献   
32.
A new conservation theorem   总被引:2,自引:0,他引:2  
A general theorem on conservation laws for arbitrary differential equations is proved. The theorem is valid also for any system of differential equations where the number of equations is equal to the number of dependent variables. The new theorem does not require existence of a Lagrangian and is based on a concept of an adjoint equation for non-linear equations suggested recently by the author. It is proved that the adjoint equation inherits all symmetries of the original equation. Accordingly, one can associate a conservation law with any group of Lie, Lie-Bäcklund or non-local symmetries and find conservation laws for differential equations without classical Lagrangians.  相似文献   
33.

Purpose

To present proton magnetic resonance spectroscopy and diffusion-weighted imaging (DWI) findings of central neurocytoma (CN).

Methods and Materials

Imaging findings of seven patients with the histopathological diagnosis of CN (five male and two female; age range, 21–28 years of age) were evaluated retrospectively. In addition to conventional magnetic resonance imaging features, we also assessed the metabolite ratios and tumor normalized apparent diffusion coefficient (NADC), which was calculated by dividing the tumor apparent diffusion coefficient (ADC) values by normal ADC. Approval from our institutional review board was obtained for this review.

Results

The tumor choline/creatine ratios were 5.17±2.38, while N-acetyl aspartate/choline and N-acetyl aspartate/creatine ratios were 0.33±0.15 and 1.84±1.38, respectively. On DWI, tumors had heterogeneous hyperintense appearances when compared with the contralateral parietal lobe white matter and tumor NADC values were 0.63±0.05.

Conclusion

Significantly increased choline/creatine and decreased N-acetyl aspartate/choline ratios with lower NADC values in CN resemble high-grade gliomas and complicate the diagnosis. Familarity its physiologic features would help to presurgical diagnosis of ventricular and exraventricular CNs.  相似文献   
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35.
    
The need for fast approximate algorithms for Debye summation arises in computations performed in crystallography, small/wide‐angle X‐ray scattering and small‐angle neutron scattering. When integrated into structure refinement protocols these algorithms can provide significant speed up over direct all‐atom‐to‐all‐atom computation. However, these protocols often employ an iterative gradient‐based optimization procedure, which then requires derivatives of the profile with respect to atomic coordinates. This article presents an accurate, O(N) cost algorithm for the computation of scattering profile derivatives. The results reported here show orders of magnitude improvement in computational efficiency, while maintaining the prescribed accuracy. This opens the possibility to efficiently integrate small‐angle scattering data into the structure determination and refinement of macromolecular systems.  相似文献   
36.
    
A robust solid‐phase microextraction fiber was fabricated by electropolymerization of thiophene on a stainless steel wire. This fiber was applied for the determination of endocrine‐disruptor pesticides, namely, chlorpyrifos, penconazole, procymidone, bromopropylate, and λ‐cyhalothrin in well waters by a headspace solid‐phase microextraction procedure. Operational parameters, namely, pH, sample volume, adsorption temperature and time, desorption temperature, stirring rate, and salt amount were optimized as 7.0, 8 mL, 70°C and 20 min, 250°C, 600 rpm, and 0.3 g/mL, respectively. The separation power of GC was coupled with the excellent sensitivity of the developed fiber enabling us to determine pesticide mixtures simultaneously in a ng/mL range. The LOD was in the range of 0.02–0.64 ng/mL. The method was successfully applied for the selective and sensitive determination of target pesticides in well water samples with acceptable recovery values (92–110%). The polythiophene fiber gives satisfactory results compared with commercial fibers. Commonly used pesticides with different polarities were chosen as representative compounds to search the applicability of the fiber for well water analysis collected from vineyards.  相似文献   
37.
    
Structure and magnetic properties of N‐diisopropoxyphosphorylthiobenzamide PhC(S)‐N(H)‐P(O)(OiPr)2 ( HLI ) and N‐diisopropoxyphosphoryl‐N′‐phenylthiocarbamide PhN(H)‐C(S)‐N(H)‐P(O)(OiPr)2 ( HLII ) complexes with the CoII cation of formulas [Co{PhC(S)‐N‐P(O)(OiPr)2}2] ( 1 ), [Co{PhN(H)‐C(S)‐N‐P(O)(OiPr)2}2] ( 2 ), [Co{PhC(S)‐N(H)‐P(O)(OiPr)2}2{PhC(S)‐N‐P(O)(OiPr)2}2] ( 1a ) and [Co{PhC(S)‐N‐P(O)(OiPr)2}2}(2,2′‐bipy)] ( 3 ), [Co{PhC(S)‐N‐P(O)(OiPr)2}2(1,10‐phen)] ( 4 ), [Co{PhN(H)‐C(S)‐N‐P(O)(OiPr)2}2(2,2′‐bipy)] ( 5 ), [Co{PhN(H)‐C(S)‐N‐P(O)(OiPr)2}2(1,10‐phen)] ( 6 ) were investigated. Paramagnetic shifts in the 1H NMR spectrum were observed for high‐spin CoII complexes with HLI,II , incorporating the S‐C‐N‐P‐O chelate moiety and two aromatic chelate ligands. Investigation of the thermal dependence of the magnetic susceptibility has shown that the extended materials 1‐2 and 6 show ferromagnetic exchange between distorted tetrahedral ( 1 , 2 ) or octahedral ( 1a , 6 ) metal atoms whereas 3 and 5 show antiferromagnetic properties. Compound 4 behaves as a spin‐canted ferromagnet, an antiferromagnetic ordering taking place below a critical temperature, Tc = 115 K. Complexes 1 and 1a were investigated by single crystal X‐ray diffraction. The cobalt(II) atom in complex 1 resides a distorted tetrahedral O2S2 environment formed by the C=S sulfur atoms and the P=O oxygen atoms of two deprotonated ligands. Complex 1a has a tetragonal‐bipyramidal structure, Co(Oax)2(Oeq)2(Seq)2, and two neutral ligand molecules are coordinated in the axial positions through the oxygen atoms of the P=O groups. The base of the bipyramid is formed by two anionic ligands in the typical 1,5‐O,S coordination mode. The ligands are in a trans configuration.  相似文献   
38.
39.
A new grid adaptation strategy, which minimizes the truncation error of a pth-order finite difference approximation, is proposed. The main idea of the method is based on the observation that the global truncation error associated with discretization on nonuniform meshes can be minimized if the interior grid points are redistributed in an optimal sequence. The method does not explicitly require the truncation error estimate, and at the same time, it allows one to increase the design order of approximation globally by one, so that the same finite difference operator reveals superconvergence properties on the optimal grid. Another very important characteristic of the method is that if the differential operator and the metric coefficients are evaluated identically by some hybrid approximation, then the single optimal grid generator can be employed in the entire computational domain independently of points where the hybrid discretization switches from one approximation to another. Generalization of the present method to multiple dimensions is presented. Numerical calculations of several one-dimensional and one two-dimensional test examples demonstrate the performance of the method and corroborate the theoretical results.  相似文献   
40.
We consider the ground state energy of a massive scalar field in the space-time of a thick cosmic string in the 2+1 dimensional case for arbitrary angle deficit by using the zeta-function approach. Final numerical calculations were made in the massless case, only. We show that the zero point energy is negative, and for small angle deficit it is proportional to the fourth degree of the deficit.  相似文献   
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