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61.
62.
We predict the possibility of observing analogue of the Aharonov-Bohm effect due to long range interaction between spins originating
in the framework of spin gauge theory developed earlier. The effect is predicted for both electrons (fermions) and photons.
Appropriate experimental set-ups are suggested. 相似文献
63.
64.
Banerjee K Dasgupta S Jadhav MR Naik DG Ligon AP Oulkar DP Savant RH Adsule PG 《Journal of AOAC International》2010,93(6):1957-1964
An analytical method is reported for residue analysis of the fungicide meptyldinocap in different fruit matrixes that involves extraction with ethyl acetate, hydrolysis of the residues with ethanolamine, and determination by LC/MS/MS. The method involves extraction of 10 g sample with 10 mL ethyl acetate; evaporation of the ethyl acetate phase to dryness, and subsequent hydrolysis of the residues to 4,6-dinitro-2-(1-methylheptyl) phenol on reaction with 1% ethanolamine. The pH of this hydrolyzed product was neutralized with formic acid and analyzed by LC/MS/MS. The hydrolysis reaction followed pseudo-first-order kinetics, and the reaction product was spectroscopically confirmed as 2-(1-methylheptyl)-4,6-dinitrophenol. The method offered > 80% recoveries at an LOQ of 10 ng/g for grape and mango, 25 ng/g for pomegranate with intralaboratory Horwitz ratio < 0.5, and measurement uncertainties < 10% at LOQ levels. Considering first-order rate kinetics, activation energy, enthalpy of activation, and entropy of activation varied as solvent > mango > grape > pomegranate. Free energy of activation at 298 K was higher than at 280 K and was similar for solvent and three matrixes at both temperatures. 相似文献
65.
Haladhara Naik Guinyun Kim Ashok Goswami Sarbjit Singh Vijay Kumar Manchanda Devesh Raj Srinivasan Ganesan Young Do Oh Hee-Seock Lee Kyung Sook Kim Man-Woo Lee Moo-Hyun Cho In Soo Ko Won Namkung 《Journal of Radioanalytical and Nuclear Chemistry》2010,283(2):439-445
The mass–yield distributions of various fission products have been determined in the 50-, 60- and 70-MeV end point bremsstrahlung induced fission of natPb using off-line γ-ray spectrometric technique in the electron linac at Pohang Accelerator Laboratory, Korea. The mass–yield distributions are symmetric with average mass of 102.34, 102.25 and 102.03 and FWHM of 21, 22 and 23 mass unit, respectively. From the present data and literature data in the 50–85 MeV bremsstrahlung induced fission of 209Bi the following observations were obtained: (i) The average masses of the yield distributions in the 50–85 MeV bremsstrahlung induced fission of natPb and 209Bi are around 102.25 ± 0.25 and 103 ± 0.5, respectively. (ii) The FWHM of the mass–yield distributions increases from about 21 mass units at 50 MeV to 23 mass units at 70–85 MeV, which is explained from the point of increase in multi-chance fission probability with increasing excitation energy. (iii) Within the bremsstrahlung energy range of 50–85 MeV, the role of nuclear structure effect in the mass–yield distribution was observed in the photo-fission of 209Bi, whereas it was not seen in case of natPb. This may be due to the presence of so many isotopes in natPb unlike mono-isotopic 209Bi. 相似文献
66.
A.K. Sharma R.K. Patidar M. Raghuramaiah P.A. Naik P.D. Gupta 《Optics Communications》2011,284(19):4596-4600
A simple technique is presented to generate temporally flat-top shaped laser pulses using electro-optic modulator (Pockels cell). It involves splitting of input laser pulse into two halves of equal intensity and then stacking together with appropriate optical delay to get a temporally flat-top laser pulse. It also allows generation of other pulse shapes by varying the relative intensity, delay, and phase between two halves of the input laser pulse. Temporally flat-top laser pulses of duration ~ 9 ns have been generated using ~ 7 ns duration incident laser pulses from a flash lamp pumped Q-switched Nd:glass laser oscillator. The rise and fall-time of the shaped pulse is limited by speed of electro-optic switch (Pockels cell), which is ~ 2 ns in the present case. 相似文献
67.
Reactions of ·OH/O .? radicals and H‐atoms as well as specific oxidants such as Cl2.? and N3· radicals have been studied with 2‐ and 3‐hydroxybenzyl alcohols (2‐ and 3‐HBA) at various pH using pulse radiolysis technique. At pH 6.8, ·OH radicals were found to react quite fast with both the HBAs (k = 7.8 × 109 dm3 mol?1 s?1 with 2‐HBA and 2 × 109 dm3 mol?1 s?1 with 3‐HBA) mainly by adduct formation and to a minor extent by H‐abstraction from ? CH2OH groups. ·OH‐(HBA) adduct were found to undergo decay to give phenoxyl type radicals in a pH dependent way and it was also very much dependent on buffer‐ion concentrations. It was seen that ·OH‐(2‐HBA) and ·OH‐(3‐HBA) adducts react with HPO42? ions (k = 2.1 × 107 and 2.8 × 107 dm3 mol?1 s?1 at pH 6.8, respectively) giving the phenoxyl type radicals of HBAs. At the same time, this reaction is very much hindered in the presence of H2PO ions indicating the role of phosphate ion concentration in determining the reaction pathway of ·OH adduct decay to final stable product. In the acidic region adducts were found to react with H+ ions. At pH 1, reaction of ·OH radicals with HBAs gave exclusively phenoxyl type radicals. Proportion of the reducing radicals formed by H‐abstraction pathway in ·OH/O .? reactions with HBAs was determined following electron transfer to methyl viologen. H‐atom abstraction is the major pathway in O .? reaction with HBAs compared to ·OH radical reaction. H‐atom reaction with 2‐ and 3‐HBA gave transient species which were found to transfer electron to methyl viologen quantitatively. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
68.
Sonochemical oxidation of benzyl alcohols into corresponding aldehydes by FeCl(3)/HNO(3) in acetone at room temperature has been reported. All substrates give good yield of the products within 10-25 min. The reaction of selected substrates were also studied under reflux and at the room temperature. Further, various Lewis acids were used to evaluate their catalytic efficacy. 相似文献
69.
H. Naik P. M. Prajapati S. V. Suryanarayana P. N. Pathak D. R. Prabhu V. Chavan D. Raj P. C. Kalsi A. Goswami S. Ganesan V. K. Manchanda 《The European Physical Journal A - Hadrons and Nuclei》2011,47(8):1-5
The νp process is a primary nucleosynthesis process which occurs in core-collapse supernovae. An essential role in this process is being played by electron antineutrinos. They generate, by absorption on protons, a supply of neutrons which, by (n, p) reactions, allow to overcome waiting point nuclei with rather long beta-decay and proton-capture lifetimes. The synthesis of heavy elements by the νp process depends sensitively on the $\bar \nu _e$ luminosity and spectrum. As has been shown recently, the latter are affected by collective neutrino flavor oscillations which can swap the $\bar \nu _e$ and $\bar \nu _{\mu ,\tau }$ spectra above a certain split energy. Assuming such a swap scenario, we have studied the impact of collective neutrino flavor oscillations on the νp-process nucleosynthesis. Our results show that the production of light p-nuclei up to mass number A = 108 is very sensitive to collective neutrino oscillations. 相似文献
70.
S. B. Hosur L. R. Naik N. M. Badiger 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2011,62(2):155-161
Low energy external bremsstrahlung (EB) photons were used to estimate the K shell photoelectric parameters; the K shell photoelectric
cross section at the K edge, the K shell binding energy, the K shell jump ratio, the K shell jump factors, the Davisson-Kirchner
ratio and the K shell oscillator strength for dysprosium (Dy), ytterbium (Yb) and tungsten (W) atoms. The EB photons are produced
in the nickel (Ni) target by using the beta particles from a weak beta source of 90Sr–90Y. These photons are made to fall on these elemental targets of our interest and the transmitted spectrum is measured using
GMX 10P HPGe detector coupled to an 8K multichannel analyzer. The sharp decrease at the K edge in the measured spectrum is
used to determine the K shell photoelectric parameters of these elements. The experimental results are in good agreement with
the theoretical values. 相似文献