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121.
Azizolla Beheshti William Clegg Nahid Ebrahimi Filoori Luca Russo 《Acta Crystallographica. Section C, Structural Chemistry》2011,67(5):m149-m153
Two polymorphs of the title compound, (C8H20N)[W2S4(S4)(C15H22BN6)], have been obtained unexpectedly by attempted recrystallization of a mixed‐metal–sulfur cluster complex from different solvents. The dinuclear complex anion contains WV in two different coordination environments, one of them distorted octahedral with a tris(pyrazolyl)borate anion, a terminal sulfide and two bridging sulfide ligands, the other distorted square‐pyramidal with a terminal sulfide, two bridging sulfide and a chelating tetrasulfide ligand. The three independent anions in the two polymorphs have essentially the same geometry. The central W2S2 ring is a slightly folded rhombus with acute angles at the S atoms, and the WS4 chelate ring is an envelope with one noncoordinating S atom as the flap. The second polymorph, with Z′ = 2 and pseudo‐inversion symmetry relating the anions of the asymmetric unit, also displays pseudo‐translation features in its layer structure, and all examined crystals were found to be twinned, possibly as a consequence of this structural feature. 相似文献
122.
Chalyavi N Troy TP Nakajima M Gibson BA Nauta K Sharp RG Kable SH Schmidt TW 《The journal of physical chemistry. A》2011,115(27):7959-7965
Gas phase excitation and emission spectra of three naphthylmethyl radical chromophores are presented. These resonance-stabilized species, 1-naphthylmethyl, 2-naphthylmethyl, and α-acenaphthenyl, each possessing an sp(2) carbon adjacent to a naphthalene moiety, are studied by resonant two-color two-photon ionization, laser induced fluorescence, and dispersed fluorescence spectroscopy. Identification of the radicals is made through a combination of dispersed fluorescence and density functional theory calculations. All three species possess spectra in the 580 nm region. The possible relevance to unidentified spectroscopic features such as the diffuse interstellar bands and emission from the Red Rectangle nebula is discussed. 相似文献
123.
In selecting sites for conservation purposes connectivity of habitat is important for allowing species to move freely within a protected area. The aim of the Reserve Network Design Problem is to choose a network of contiguous sites which maximises some conservation objective subject to various constraints. The problem has been solved using both heuristic and exact methods. Heuristic methods can handle much larger problems than exact methods but cannot guarantee an optimal solution. Improvements in both computer power and optimisation algorithms have increased the attractiveness of exact methods. The aim of this work is to formulate an improved algorithm for solving the Reserve Network Design Problem. 相似文献
124.
2-(3-Chloro-2-formyl-1H-indol-1-yl) acetic acid, as a bifunctional formyl-acid, is prepared in three steps. This compound undergoes a one-pot, four-center, three-component Ugi reaction with primary amines and alkyl isocyanides. A series of novel substituted indoloketopiperazine derivatives are obtained in moderate to high yields. 相似文献
125.
Nahid Talebi Burcu Ögüt Wilfried Sigle Ralf Vogelgesang Peter A. van Aken 《Applied Physics A: Materials Science & Processing》2014,116(3):947-954
Plasmonics is expected to play a key role in nanotechnology, leading to intriguing routes in many engineering and biological applications. Recently, it has been realized that toroidal resonances could be an alternative to electric and magnetic resonances, which have governed the innovation of plasmonic applications so far. In a previous contribution, we proved the existence of toroidal moments in an oligomeric void-plasmonic structure [1]. In this article, we investigate the role of topology and symmetry in decomposing the various dipolar, quadrupolar, and toroidal moments, using energy-filtering transmission electron microscopy supported by three-dimensional finite-difference time-domain method simulations. The consequences of changing the topology on the toroidal character are discussed by comparing results obtained from nanoholes forming heptamer and hexamer nanocavity systems that were drilled into a thin silver film. 相似文献
126.
Sepahvandi A Moztarzadeh F Mozafari M Ghaffari M Raee N 《Colloids and surfaces. B, Biointerfaces》2011,86(2):390-396
Photoluminescence (PL) property is particularly important in the characterization of materials that contain significant proportions of noncrystalline components, multiple phases, or low concentrations of mineral phases. In this research, the ability of biomimetic bone-like apatite deposition on the surface of titanium alloy (Ti6Al4V) substrates in simulated body fluid (SBF) right after alkaline-treatment and subsequent heat-treatment was studied by the inherent luminescence properties of apatite. For this purpose, the metallic substrates were treated in 5 M NaOH solution at 60 °C. Subsequently, the substrates were heat-treated at 600 °C for 1 h for consolidation of the sodium titanate hydrogel layer. Then, they were soaked in SBF for different periods of time. Finally, the possibility to use of PL monitoring as an effective method and early detection tool is discussed. According to the obtained results, it was concluded that the PL emission peak did not have any significant shift to the shorter or higher wavelengths, and the PL intensity increased as the exposure time increased. This research proved that the observed inherent PL of the newly formed apatite coatings might be of specific interest for histological probing and bone remodelling monitoring. 相似文献
127.
A simple and novel speciation method for the determination of volatile organic compounds of selenium (dimethylselenide (DMSe) and dimethyldiselenide (DMDSe) has been developed using a headspace hollow fiber protected liquid-phase microextraction (HS-HF-LPME) combined with capillary gas chromatography-mass spectrometry (GC-MS). The organic solvent impregnated in the pores and filled inside the porous hollow fiber membrane was used as an extraction interface in the HS-HF-LPME of the compounds. The effect of different variables on the extraction efficiency was studied simultaneously using an experimental design. The variables of interest in the HS-HF-LPME were sample volume, extraction time, temperature of sample solution, ionic strength, stirring rate and dwelling time. A Plackett-Burman design was performed for screening in order to determine the significant variables affecting the extraction efficiency. Then, the significant factors were optimized by a Box-Behnken design (BBD) and the response surface equations were derived. Under optimum conditions, preconcentration factors up to 1250 and 1170 were achieved for DMSe and DMDSe respectively. The detection limit and relative standard deviation (RSD) (n=5, c=50 μg L(-1)) for DMSe were 65 ng L(-1) and 4.8%, respectively. They were also obtained for DMDSe as 57 ng L(-1) and 3.9%, respectively. The developed technique was found to be applicable to spiked environmental and biological samples. 相似文献
128.
Nahid Kamelipour Afshin Mohsenifar Meisam Tabatabaei Tavoos Rahmani-Cherati Kamyar Khoshnevisan Abdolamir Allameh Majid M. Milani Saeid Najavand Batool Etemadikia 《Mikrochimica acta》2014,181(1-2):239-248
A dimeric organophosphorus hydrolase (OPH; EC 3.1.8.1; 72 kDa) was isolated from wild-type bacteria, analyzed for its 16s rRNA sequence, purified, and immobilized on gold nanoparticles (AuNPs) to form the transducer part of a biosensor. The isolated strain was identified as Pseudomonas aeruginosa. The AuNPs were characterized by transmission electron microscopy and localized surface plasmon resonance. Covalent binding of OPH to the AuNPs was confirmed by spectrophotometry, enzymatic activity assays, and FTIR spectroscopy. Coumarin 1, a competitive inhibitor of OPH, was used as a fluorogenic probe. The bioconjugates quench the emission of coumarin 1 upon binding, but the addition of paraoxon results in an enhancement of fluorescence that is directly proportional to the concentration of paraoxon. The gold-OPH conjugates were then used to determine paraoxon in serum samples spiked with varying levels of paraoxon. The method works in the 50 to 1,050 nM concentration range, has a low standard deviation (with a CV of 5.7–11 %), and a detection limit as low as 5?×?10?11 M. Figure
Coumarin 1, a competitive inhibitor of organophosphorus hydrolase, was used as a fluorogenic probe in the bioconjugates. The gold nanoparticles contained in the bioconjugates quench the emission of coumarin 1 upon binding, but the addition of paraoxon results in an enhancement of fluorescence leading to its detection. 相似文献
129.
Shahabadi Nahid Razlansari Mahtab Khorshidi Aref Zhaleh Hossein 《Research on Chemical Intermediates》2020,46(9):4257-4278
Research on Chemical Intermediates - Epirubicin loaded on magnetite-coated calcium ferrite conjugated folic acid (Fe3O4@CaFe2O4-FA@EPI) was synthesized and characterized using various techniques... 相似文献
130.