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排序方式: 共有478条查询结果,搜索用时 31 毫秒
451.
Morgan Auffray Dae Hyeon Kim Jong Uk Kim Fatima Bencheikh David Kreher Qisheng Zhang Anthony D'Alo Jean‐Charles Ribierre Fabrice Mathevet Chihaya Adachi 《化学:亚洲杂志》2019,14(11):1921-1925
Thermally activated delayed fluorescence (TADF) based on through‐space donor and acceptor interactions constitute a recent and promising approach to develop efficient TADF emitters. Novel TADF isomers using a dithia[3.3]‐paracyclophane building block as a versatile 3D platform to promote through‐space interactions are presented. Such a 3D platform allows to bring together the D and A units into close proximity and to probe the effect of their orientation, contact site and distance on their TADF emission properties. This study provides evidence that the dithia[3.3]paracyclophane core is a promising platform to control intramolecular through‐space interactions and obtain an efficient TADF emission with short reverse‐intersystem crossing (RISC) lifetimes. In addition, this study demonstrates that this design can tune the energy levels of the triplet states and leads to an upconversion from 3CT to 3LE that promotes faster and more efficient RISC to the 1CT singlet state. 相似文献
452.
Yury N. Belokon Konstantin A. Kochetkov Fatima M. Plieva Nikolai S. Ikonnikov Viktor I. Maleev Virinder S. Parmar Rajesh Kumar Vladimir I. Lozinsky 《Applied biochemistry and biotechnology》2000,88(1-3):97-106
The application of immobilized α-chymotrypsin for the purpose of enantioselective hydrolysis of a Schiff's base of D,L-Phe-OEt
(D,L-SBPH) in the mixed water-acetonitrile media with the different content of water is described. The immobilized biocatalyst
was prepared by the chemical coupling of the enzyme to poly(vinyl alcohol) (PVA) cryogel—the macroporous hydrogel prepared
by means of the freezing-thawing techniques. SBPH is water insoluble, and, therefore, acetonitrile (MeCN) with minor water
additives was used as a solvent for the reaction of enantics elective hydrolysis of the racemic substrate. The process was
conducted for 96–200 h, and L-Phe with the purity up to 98% e.e. precipitated in both the reaction medium and gel-carrier
bulk. Theproduct wasrecovered by washing the organo-insoluble sediment with aqueous ammonia. D-Phe with the purity up to 85%
e.e. was recovered from the organic solution of D-ester after its acidic hydrolysis. The PVA-cryogel-attached enzyme was effective
in SBPH hydrolysis in MeCN/water mixtures. The immobilized biocatalyst was active for more than 1 mo of application and could
be successfully used after another 4 mo storage at +10°C. 相似文献
453.
A tandem technique for the detection of very low levels E. coli within about 2 h is demonstrated. The technique couples the widely employed microbial enzymatic detection methods with an immunoassay step. The bacterial marker enzyme, E. coli β-D-galactosidase, was used in conjunction with synthetic enzyme substrates to produce products that could be measured with a highly sensitive enzyme-labelled immunosorbent assay (ELISA). The commercially available 4-methylumbelliferyl-β-D-galactoside and a newly prepared substrate, 4-methylcoumarin-3-propionate-7-O-β-D-galactoside, were used with an ELISA for 7-hydroxy-4-methylcoumarin to demonstrate the detection of low levels of E. coli. The 2 h test indicates that a few viable bacteria cells could be detected by the tandem procedure. The end point of the test is an ELISA with colorimetric measurement step. The novel approach retains the essential features of the microbial enzymatic detection procedures and provides a highly sensitive detection system that can be used for rapid screening or quantification of viable microbial cells in water samples. The tandem test is generic for commonly employed glycosidases and other marker enzymes for which 4-methylumbillerone substrates are available. 相似文献
454.
Setifi F Golhen S Ouahab L Miyazaki A Okabe K Enoki T Toita T Yamada J 《Inorganic chemistry》2002,41(14):3786-3790
The preparation, X-ray crystal structures, and magnetic properties of two new isostructural charge transfer salts, (BDH-TTP)M(isoq)(2)(NCS)(4) (M = Cr(III) (1), Fe(III) (2), BDH-TTP = 2,5-bis(1,3-dithiolan-2-ylidene)-1,3,4,6-tetrathiapentalene, isoq = isoquinoline), are reported. Crystal data for 1: monoclinic, space group C2/c (#15), a = 16.1363(9) A, b = 19.0874(12) A, c = 12.5075(6) A, beta = 95.70(4) degrees, V = 3833.2(4) A(3), Z = 4, R = 0.0516 for 2844 reflections with I > 2 sigma(I); for 2: monoclinic, C2/c (#15), a = 16.1938(8) A, b = 19.1117(11) A, c = 12.5100(10) A, beta = 94.265(3) degrees, V = 3861.0(4) A(3), Z = 4, R = 0.0479 for 2969 reflections with I > 2 sigma(I). The crystal structure consists of zigzag mixed organic and inorganic layers, and each layer is formed by mixed columns of BDH-TTP radical cations and paramagnetic metal complex anions. Short intermolecular atomic contacts between donor and anion are observed within the column in the c-direction. The two compounds have weak room-temperature electrical conductivities. ESR measurements show a single signal without separating the donor and anion spins, suggesting a pi interaction between the d and pi electrons. For both compounds ferrimagnetic interactions are observed between the nonequivalent donor and anion spins. These materials exhibit bulk canted weak ferromagnetism below 7.6 K for both 1 and 2. 相似文献
455.
Fatima Laytimi 《Archiv der Mathematik》1991,57(6):617-621
Sans résumé 相似文献
456.
Iqbal MP Mahmood S Mehboobali N Ishaq M Fatima T Parveen S Frossard P 《Experimental & molecular medicine》2004,36(2):110-115
The angiotensin converting enzyme (ACE) is a strong candidate gene for myocardial infarction (MI). Insertion-deletion dimorphism in intron 16 of this gene has been inconclusively found to be associated with it. Several new polymorphisms in the ACE gene have been identified and among these, a dimorphism in exon 17, ACE G2350A, has a significant effect on plasma ACE concentrations. To assess the value of genotyping the ACE G2350A dimorphism in a genetically homogeneous population, we carried out a case-control study of dimorphism G2350A for a putative association with MI among Pakistani nationals. We investigated a sample population of 370 Pakistanis, comprising 163 controls, and 207 patients with clinical diagnosis of acute MI (AMI). ACE G2350A alleles were visualized by assays based on polymerase chain reaction and restriction endonuclease analysis. Frequencies of G alleles were 0.68 among controls and 0.72 among AMI patients. The ACE G2350A dimorphism showed no significant association with MI (chi2 = 0.90, 2 df, P = 0.64), plasma levels of homocysteine (P = 0.52) or with serum levels of folate (P = 0.299). The results indicate that ACE G2350A polymorphism is not associated with risk of myocardial infarction in the Pakistani population investigated here. 相似文献
457.
Bouchama F Thathagar MB Rothenberg G Turkenburg DH Eiser E 《Langmuir : the ACS journal of surfaces and colloids》2004,20(2):477-483
Stable nanoclusters (approximately 2 nm in diameter) of copper, silver, gold, palladium, and ruthenium coated with hydrophobic coronas are easily trapped in self-assembled "soft crystal" hexagonal phase gels made of water and surfactants. The system's crystal structure and phase behavior are studied in detail. A partial phase diagram showing the hexagonal phase region for the water/SDS/toluene region is presented. High-energy X-ray scattering and cross-polarized optical microscopy experiments show that the clusters are tightly confined within the tubes. The thermal gel-fluid transitions of the hexagonal phase are investigated, and it is shown that the hexagonal phase can melt and recrystallize repeatedly. The melt/gel cycles enable easy trapping of various metal clusters in pre-prepared hexagonal phases. In contrast to spherical micelles, the hexagonal phase doped with metal clusters can grow without limit, basically up to the container walls (Ru-doped soft crystals grew to 0.5 mm over 2 months, forming wormlike tubes that are more than 50 microm long but only 7-10 nm in diameter). 相似文献
458.
A general and practical green chemistry route to the Biginelli cyclocondensation reaction using cerium(III) chloride as the catalyst (25% mol) is described under three different sets of reaction conditions. This method provides an efficient and much improved modification of original Biginelli reaction reported in 1893, in terms of high yields, short reaction times, and simple work-up procedure, and it has the ability to tolerate a wide variety of substitutions in all three components, which is lacking in existing procedures. 相似文献
459.
The international spot-market, risk-exposed, trading of a cotton merchant was studied. A price model for estimating a market price for cotton with varying characteristics was constructed. This formed the input for a trading decision model which predicted the outcome of the merchant taking risky positions. 相似文献
460.
Jamal Bennazha Fatima Erragh Ali Boukhari Elizabeth M. Holt 《Journal of chemical crystallography》2000,30(11):705-716
Syntheses and single-crystal X-ray structural results are reported for three new mixed diphosphates of the family AI
2BII
3(P2O7)2; Ag2Co3(P2O7)2 (I), Ag2Mn3(P2O7)2 (II), and Na2Cd3(P2O7)2 (III). All crystallize in the triclinic system, space group P1 bar: (I) a = 5.351(4), b = 6.375(4), c = 16.532(4) Å, = 80.83(6) = 81.45(4), = 72.87(5)°, V = 528.9(6) Å3, Z = 2, D
calc = 4.649 mg/m3, R/Rw = 0.0428/0.0548 for 3949 obs. reflns; (II) a = 5.432(7), b = 6.619(6), c = 16.51(3) Å, = 80.78(8) = 82.43(9), = 72.82(7)°, V = 557.7(13) Å3, Z = 2, D
calc = 4.338 mg/m3, R/Rw = 0.0679/0.1303 for 2100 obs. reflns and (III) a = 5.67(3), b = 7.08(4), c = 7.90(4) Å, = 77.0(2), = 82.5(2), = 67.8(2)°, V = 286(3) Å3, Z = 2, D
calc = 4.249 mg/m3, R/Rw = 0.0307/0.0342 for 1945 obs. reflns. (I) and (II) are isostructural but (III) is of a different type. All three structures are characterized by layers of P2O7 groups alternating with layers of mixed metal atoms. Differences are seen in the conglomerate bonding patterns of B atoms and in the irregular geometry of Ag in (I) and (II) compared to the octahedral bonding seen for Na in (III). The differences in structure may be understood in terms of the ratios of the ionic radii of A and B atoms. 相似文献