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71.
Ken‐Ichi Seno Itsuko Tsujimoto Takunobu Kikuchi Shokyoku Kanaoka Sadahito Aoshima 《Journal of polymer science. Part A, Polymer chemistry》2008,46(18):6151-6164
Thermosensitive forced gradient copolymers with various sequence distributions were synthesized by living cationic polymerization in the presence of an added base. The synthesis was conducted using a semibatch reaction method, which is unfavorable for ionic polymerization, especially when a simple apparatus is employed. Polymerization of 2‐ethoxyethyl vinyl ether (EOVE) was initiated using a conventional syringe technique. Immediately after initiation, 2‐methoxyethyl vinyl ether (MOVE) was continuously added using a syringe pump at regulated feed rates, which allowed control of the sequence distribution. The resulting gradient copolymers of EOVE and MOVE underwent thermally induced association in water, forming micelles with a hydrophobic core derived from EOVE‐rich segments. Interestingly, the size of the micelles obtained from gradient copolymers decreased monotonously with increasing solution temperature, while the micelles of the corresponding block copolymers were unchanged in size. This self‐association behavior can be controlled by designing the gradient pattern of the instantaneous composition. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6151–6164, 2008 相似文献
72.
Takashi Murashima Satoshi Tsujimoto Toshifumi Miyazawa Noboru Ono 《Tetrahedron letters》2005,46(1):113-116
Water-soluble bicycloporphyrin and benzoporphyrin having octacarboxyl groups are synthesized from the corresponding octaester porphyrin by simple hydrolyzing and heating procedures. These compounds are characterized by UV-vis, NMR and mass spectroscopies. The benzoporphyrin octacarboxylic acid exhibits extremely high planarity in spite of its poly-substitution. 相似文献
73.
Masaki Tsujimoto Tomoki Yabutani Atsushi Sano Yuji Tani Hiroki Murotani Yuji Mishima Kenichi Maruyama Mikito Yasuzawa Junko Motonaka 《Analytical sciences》2007,23(1):59-63
A glucose sensor was developed by electrocopolymerization using pyrroles containing a tris-bipyridine (bpy) osmium complex (Os-py), pyrrole (py), pyrrole propanoic acid (PPA) and glucose oxidase (GOx) to improve the key performance characteristics, such as the sensitivity, selectivity, and long-term stability. Tris-bipyridine osmium pyrrole complexes with four different methylene moieties were utilized to correlate the methylene length with the glucose sensor performance. The electrocatalytic response of glucose was clearly observed at electrodes modified with Os-py, except for the electrode immobilized with the Os-py complex containing the shortest methylene moiety. The current response to glucose increased up to a concentration of 100 mmol dm(-3). The electrocatalytic response to glucose at the [Os(bpy)(2)(py(6)-bpy)](2+/3+)/py/PPA/GOx electrode was stable for more than 100 days. Dissolved oxygen and potential interference compounds (ascorbic acid, uric acid, and acetaminophen) minimally perturbed the current response to glucose at the [Os(DM-bpy)(2)(py(6)-bpy)](2+/3+)/py/PPA/GOx electrode. Based on these results, a longer methylene moiety appears to improve the performance characteristics of a glucose sensor fabricated via the electropolymerization of tris-bipyridine osmium pyrrole complexes. 相似文献
74.
75.
Indium silicate activated by terbium was found to be an efficient phosphor with CR excitation, the luminosity of which was comparable to the most luminous of other terbium-activated silicates. For the preparation of this phosphor, alkaline earth metal flourides proved to act as a good mineralizer. The best result was obtained when a mixture of 1 mol In2O3, 2.2 mol SiO2, 0.015 mol Tb4O7 and 0.05 mol BaF2 was fired at 1 400°C in air for 4 h. Other rare earth luminescent centers such as Ce, Pr, Eu, Dy, Er and Tm were examined but none showed noticeable emission. Some UV excitation properties are also described. 相似文献
76.
The mass spectra of N-iminopyridinium betaines, which have been generated within the ion source by pyrolysis of the corresponding hydrochlorides, have been compared with those of pyridine N-oxides. 相似文献
77.
Toshisada Takahashi Hiroaki Iwamoto Kazuyuki Inoue Ishio Tsujimoto 《Journal of Polymer Science.Polymer Physics》1979,17(1):115-122
Quiescent and strain-induced crystallization of poly(p-phenylene terephthalamide) (PPTA) from sulfuric acid solution has been studied. Negative spherulites (SA-PPTA spherulites) are formed from hot concentrated solutions by cooling. The spherulite consists of radiating fibrous lamellae several hundred angstroms wide. The electron diffraction pattern indicates that PPTA molecules are oriented perpendicular to the long axes of the fibrous lamellae and that the [010] or [110] direction of the modification I crystal and [010] direction of the modification II crystal are parallel to the long axes of the fibrous lamellae. The width of the lamellae is much smaller than the chain length of the starting PPTA. It appears that hydrolysis of PPTA during melting crystallization determines the chain length, i.e., the width of the fibrous lamella. Stacked, lamellar structures like “row structures” are formed under shear. The longer axes of the fibrous lamellae are oriented perpendicular to the shear direction. It is confirmed by electron diffraction studies that the PPTA molecules are oriented parallel to the shear direction. Well-developed fibrils with the PPTA molecules oriented to the fibril axis, are formed by adding the SA-PPTA spherulites to water with vigorous stirring. 相似文献
78.
Manickam Sivakumar Atsuya Towata Kyuichi Yasui Toru Tuziuti Teruyuki Kozuka Masahiko Tsujimoto Ziyi Zhong Yasuo Iida 《Ultrasonics sonochemistry》2010,17(1):213-218
Fine particles of rutile TiO2 supporting nanosized particles of Pt were prepared by a simultaneous in situ sonochemical reduction and deposition method using a standing wave sonochemical reactor (SWSR). The mean diameter of sonochemically obtained Pt particles are of 2 nm. Following this sonochemical technique, rutile TiO2 was also deposited with different weight percentages of Pt. Catalytic function of the prepared composite catalysts were tested by the oxidation of CO to CO2. From the catalytic activity results, it has been found out that the catalysts prepared by the sonochemical method exhibited higher catalytic activity for CO oxidation, probably attributed to the higher Pt particle distribution achieved under sonication. Transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), and diffuse reflectance spectroscopy (DRS) were employed to characterize the resulting material. 相似文献
79.
Taie S Takasu Y Sugawa S Yamazaki R Tsujimoto T Murakami R Takahashi Y 《Physical review letters》2010,105(19):190401
We report the realization of a novel degenerate Fermi mixture with an SU(2)×SU(6) symmetry in a cold atomic gas. We successfully cool the mixture of the two fermionic isotopes of ytterbium 171Yb with the nuclear spin I=1/2 and 173Yb with I=5/2 below the Fermi temperature T_{F} as 0.46TF for 171Yb and 0.54TF for 173Yb. The same scattering lengths for different spin components make this mixture featured with the novel SU(2)×SU(6) symmetry. The nuclear spin components are separately imaged by exploiting an optical Stern-Gerlach effect. In addition, the mixture is loaded into a 3D optical lattice to implement the SU(2)×SU(6) Hubbard model. This mixture will open the door to the study of novel quantum phases such as a spinor Bardeen-Cooper-Schrieffer-like fermionic superfluid. 相似文献
80.