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R. Nagarajan S. Ayyappan C. N. R. Rao 《Physica C: Superconductivity and its Applications》1994,220(3-4):373-376
While YSr2Cu3O7 cannot be prepared under ambient conditions, partial substitution of the phosphate group for copper, as in YSr2Cu2.8(PO4)0.2Oy, stabilizes this phase in the orthorhombic structure, but the material is not superconducting. Superconductivity in YSr2Cu2.8(PO4)0.2Oy is obtained by increasing the hole concentration through partial substitution of Y by Ca, as in Y0.7Ca0.3Sr2Cu2.8(PO4)0.2Oy (Tc≈40 K). By incorporating the phosphate group in orthorhombic YBaSrCu3O 7, a stable tetragonal derivative of the formula YBaSrCu2.8(PO4)0.2Oy (Tc≈ 47 K) has been prepared; the Tc increases to 70 K by partial substitution of Y by Ca as in Y0.7Ca0.3BaSrCu2.8(PO4)0.2Oy. 相似文献
14.
A. Subramanian T.-Y. Choi L.X. Dong J. Tharian U. Sennhauser D. Poulikakos B.J. Nelson 《Applied Physics A: Materials Science & Processing》2007,89(1):133-139
We report on a novel method for local control of shell engineering in multiwalled carbon nanotubes (MWNTs) using Joule-heating
induced electric breakdown. By modulating the heat dissipation along a nanotube, we can confine its thinning and shell breakdown
to occur within localized regions of peak temperatures, which are distributed over one-half of the NT length. The modulation
is achieved by using suitably designed nanomachined heat sinks with different degrees of thermal coupling at different parts
of a current-carrying nanotube. The location of electric breakdown occurs precisely at the regions of high temperatures predicted
by the classical finite-element model of Joule heating in the MWNT. The experiments herein provide new insight into the electric
breakdown mechanism and prove unambiguously that shell removal occurs due to thermal stress, underpinning the diffusive nature
of MWNTs. The method demonstrated here has the potential to be a powerful tool in realizing MWNT bearings with complex architectures
for use in integrated nanoelectromechanical systems (NEMS). In addition, the breakdown current and power in the nanotubes
are significantly higher than those observed in nanotubes without heat removal via additional heat sinks. This indicates future
avenues for enhancing the performance of MWNTs in electrical interconnect and nanoelectronic applications.
PACS 73.63.Fg; 65.80.+n 相似文献
15.
Recently, Chawla et al. described a second order finite difference method for the class of singular two-point boundary value problems: