全文获取类型
收费全文 | 334篇 |
免费 | 2篇 |
专业分类
化学 | 112篇 |
晶体学 | 2篇 |
数学 | 11篇 |
物理学 | 211篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2015年 | 4篇 |
2014年 | 1篇 |
2013年 | 6篇 |
2012年 | 10篇 |
2011年 | 9篇 |
2010年 | 7篇 |
2009年 | 8篇 |
2008年 | 15篇 |
2007年 | 11篇 |
2006年 | 8篇 |
2005年 | 10篇 |
2004年 | 18篇 |
2003年 | 7篇 |
2002年 | 5篇 |
2001年 | 23篇 |
2000年 | 1篇 |
1999年 | 16篇 |
1997年 | 17篇 |
1996年 | 9篇 |
1995年 | 4篇 |
1994年 | 19篇 |
1993年 | 20篇 |
1992年 | 5篇 |
1991年 | 11篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1986年 | 12篇 |
1985年 | 6篇 |
1984年 | 14篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 7篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 8篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有336条查询结果,搜索用时 15 毫秒
21.
22.
Kuniaki Marui Yuuki Higashiura Shintaro Kodama Suguru Hashidate Akihiro Nomoto Shigenobu Yano Michio Ueshima Akiya Ogawa 《Tetrahedron》2014
The oxidation of alcohols using catalytic amounts of metal complexes is highly attractive from the viewpoint of green chemistry principles. However, examples of metal complex-catalyzed oxidations of alcohols with O2 using water as the solvent are still rare, and precious metals, high-pressure O2 or air, and a stoichiometric amount of base are often required. In this study, it was found that an oxovanadium-4,4′-t-Bubpy (4,4′-di-tert-butyl-2,2′-bipyridyl) complex exhibited high catalytic activity in the oxidation of benzhydrols under an atmosphere of O2 in water as the sole solvent. Interestingly, this catalytic oxidation method could be applied to the gram-scale aerobic oxidation of alcohols in water under the atmosphere. 相似文献
23.
24.
In vivo quantification of the metabolites in normal brain and brain tumors by proton MR spectroscopy using water as an internal standard 总被引:2,自引:0,他引:2
Metabolite concentrations in normal adult brains and in gliomas were quantitatively analyzed by in vivo proton magnetic resonance spectroscopy (MRS) using the fully relaxed water signal as an internal standard. Between January 1998 and October 2001, 28 healthy volunteers and 18 patients with gliomas were examined by in vivo proton MRS. Single-voxel spectra were acquired using the point-resolved spectroscopic (PRESS) pulse sequence with a 1.5 T scanner (TR/TE/Ave = 3000 ms/30 ms/64). The calculated concentrations of N-acetyl-aspartate (NAA), creatine (Cre), choline (Cho), and water(H(2)O) in the normal hemispheric white matter were 23.59 +/- 2.62 mM (mean +/- SD), 13.06 +/- 1.8 mM, 4.28 +/- 0.8 mM, and 47280.96 +/- 5414.85 mM, respectively. The metabolite concentrations were not necessarily uniform in different parts of the brain. The concentrations of NAA and Cre decreased in all gliomas (p < 0.001). The NAA/Cho and NAA/H(2)O ratios can distinguish the normal brain from gliomas and low-grade from high-grade astrocytoma (p < 0.001). The concentration of taurine (Tau) in medulloblastomas was 29.64 +/- 5.76 mM. This is the first quantitative analysis of Tau in medulloblastoma in vivo and confirms earlier in vitro findings. 相似文献
25.
In vivo quantification of the metabolites in normal brain and brain tumors by proton MR spectroscopy using water as an internal standard 总被引:13,自引:0,他引:13
Metabolite concentrations in normal adult brains and in gliomas were quantitatively analyzed by in vivo proton magnetic resonance spectroscopy (MRS) using the fully relaxed water signal as an internal standard. Between January 1998 and October 2001, 28 healthy volunteers and 18 patients with gliomas were examined by in vivo proton MRS. Single voxel spectra were acquired using the point-resolved spectroscopic pulse sequence with a 1.5-T scanner (TR/TE/Ave = 3000 ms/30 ms/64). The calculated concentrations of N-acetyl-aspartate (NAA), creatine (Cre), choline (Cho), and water (H2O) in the normal hemispheric white matter were 23.59 +/- 2.62 mM (mean +/- SD), 13.06 +/- 1.8 mM, 4.28 +/- 0.8 mM, and 47280.96 +/- 5414.85 mM, respectively. The metabolite concentrations were not necessarily uniform in different parts of the brain. The concentrations of NAA and Cre decreased in all gliomas (p < 0.001). The NAA/Cho and NAA/H2O ratios can distinguish the normal brain from gliomas, and low-grade astrocytoma from high-grade group (p < 0.001). The concentration of taurine (Tau) in medulloblastomas was 29.64 +/- 5.76 mM. This is the first quantitative analysis of Tau in medulloblastoma in vivo and confirms earlier in vitro findings. 相似文献
26.
Kawamura N Nagamine K Matsuzaki T Ishida K Nakamura SN Matsuda Y Tanase M Kato M Sugai H Kudo K Takeda N Eaton GH 《Physical review letters》2003,90(4):043401
A systematic experimental study on muon-catalyzed fusion was conducted using a series of solid deuterium and tritium mixtures. A variety of conditions were investigated, i.e., tritium concentrations from 20% to 70%, and temperatures from 5 to 16 K. With decreasing temperature, we observed an unexpected decrease in the muon cycling rate (lambda(c)) and an increase in the muon loss probability (W). The origins of these observed changes were interpreted by the temperature-dependence in the dt mu formation process for lambda(c) and that in the muon reactivation process after muon-to-alpha sticking for W. 相似文献
27.
T. Kondow A. Matsushita K. Kuchitsu K. Nishiyama Y. Morozumi K. Nagamine 《Hyperfine Interactions》1986,32(1-4):807-812
Surface muons produced in UT-MSL were introduced into argon gas of 4.0±0.2 atm with NO2 (0–30 ppm), and muonium signals were detected in the presence of a transverse (1.7–3.4 G) and a longitudinal magnetic field
(0–3.5 kG) at 295±1 K. The cross section for the transverse relaxation was (11.0±1.0)×10−16 cm2. The relaxation rates in different longitudinal magnetic fields show that the rate does not follow the conventional equation
which assumes that the relaxation occurs mainly by spin-exchange interaction. Similar measurements were performed for the
Mu+O2 system. These findings indicate that chemical reactions contribute to these relaxation rates. 相似文献
28.
P. Strasser K. Ishida S. Sakamoto M. Iwasaki E. Torikai K. Nagamine G. M. Marshall 《Hyperfine Interactions》1993,82(1-4):543-549
Slow – production via dd-CF using a two-layer arrangement is investigated. To determine its feasibility, experimental measurements are now in progress using the muonic X-ray detection method. The following experimental steps are being considered: (1) measurement of the number of – stopped inside a solid H2/D2 layer by detecting p K X-rays, (2) hot d emission detection by placing a secondary target at a distance of 10–30 mm from the layer and by detecting specific delayed X-rays, (3) measurement of the disappearance of d emission as the added D2 layer is increased, (4) dd-CF measurement by detecting fusion protons, and (5) slow – emission detection. Results of the initial test experiment are presented. 相似文献
29.
Kuniaki Tatsuta Tomohiro Fukuda Tatsuya Ishimori Rearu Yachi Shinpei Yoshida Hiroshi Hashimoto Seijiro Hosokawa 《Tetrahedron letters》2012,53(4):422-425
The first total synthesis of hibarimicinone has been achieved. The polyhydroxydecalin moieties (AB and GH rings) have been synthesized from sulfonylenone 4 derived from d-arabinose. The chiral biaryl 20 was coupled with two polyhydroxydecalins 11 by Michael–Dieckmann type condensation to give the eight rings system. Aromatization and oxidation with Ag+ gave quinone 24, and the subsequential transannular etheration gave the hibarimicinone skeleton. Deprotection and tautomerization were performed in one pot to give hibarimicinone (1). 相似文献
30.
N. Kawamura K. Nagamine T. Matsuzaki K. Ishida S. N. Nakamura Y. Matsuda M. Tanase M. Kato K. Kurosawa H. Sugai K. Kudo N. Takeda G. H. Eaton 《Hyperfine Interactions》2001,138(1-4):235-240
A systematic study on muon catalyzed fusion (μCF) was conducted in solid deuterium and tritium (D–T) mixture. A variety of
experimental conditions were investigated, i.e., tritium concentrations from 20 to 70%, temperatures from 5 to 16 K. A preliminary
analysis result suggests a steep decrease in the dtμ-molecule formation rate with decreasing temperature, and also an increase in the probability for a muon reactivation after
an α-sticking phenomenon.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献