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91.
E. Yu. Osipova A. S. Ivanova A. N. Rodionov A. A. Korlyukov D. E. Arkhipov A. A. Simenel 《Russian Chemical Bulletin》2016,65(12):2868-2872
Regioselectivity of the HBF4-catalyzed ferrocenylalkylation of 2-mercaptobenzoxazole in two phase aqueous organic solvent mixture was studied. The reaction proceeds regioselectively at the heterocyclic nitrogen atom. Structures of the synthesized compounds were established by 2D NMR technique. Structure of 3-(1-ferrocenylbenzyl)benz[d]oxazol-2-thione was elucidated by X-ray diffraction. 相似文献
92.
E. Yu. Osipova A. N. Rodionov Yu. A. Belousov M. M. Il’in A. L. Nikolaev A. V. Gopin S. E. Mazina A. A. Simenel 《Russian Journal of Organic Chemistry》2016,52(1):127-130
The condensation of 1-(ferrocenylalkyl)pyrazole-3-carbaldehydes with 4′-aminotetraphenylporphyrin, followed by reduction with NaBH(OAc)3 in 1,2-dichloroethane, provides a convenient method for the synthesis of 5-{4-[({1-[1-(ferrocen-1-yl)alkyl]-5-methyl-1H-pyrazol-3-yl}methyl)amino]phenyl}-10,15,20-triphenylporphyrins which exhibit pronounced cytotoxicity against Staphylococcus aureus under ultrasonic irradiation. 相似文献
93.
A high-pressure turbulent flow reactor coupled with a chemical ionization mass-spectrometer was used to determine the branching ratio of the HO(2) + NO reaction: HO(2) + NO --> OH + NO(2) (1a), HO(2) + NO --> HNO(3) (1b). The branching ratio, beta = k(1b)/k(1a), was derived from the measurements of "chemically amplified" concentrations of the NO(2) and HNO(3) products in the presence of O(2) and CO. The pressure and temperature dependence of beta was determined in the pressure range of 72-600 Torr of N(2) carrier gas between 323 and 223 K. At each pressure, the branching ratio was found to increase with the decrease of temperature, the increase becoming less pronounced with the increase of pressure. In the 298-223 K range, the data could be fitted by the expression: beta(T,P) = (530 +/- 10)/T(K) + (6.4 +/- 1.3) x 10(-4)P(Torr) - (1.73 +/- 0.07), giving beta approximately 0.5% near the Earth's surface (298 K, 760 Torr) and 0.8% in the tropopause region (220 K, 200 Torr). The atmospheric implication of these results is briefly discussed. 相似文献
94.
Gushchin PV Bokach NA Luzyanin KV Nazarov AA Haukka M Kukushkin VY 《Inorganic chemistry》2007,46(5):1684-1693
The coupling between tetramethylguanidine, HN=C(NMe2)2, and coordinated organonitriles in the platinum(II) complexes cis/trans-[PtCl2(RCN)2] (R = Me, Et, Ph) proceeds rapidly under mild conditions to afford the diimino compounds containing two N-bound monodentate 1,3-diaza-1,3-diene ligands [PtCl2{NH=C(R)N=C(NMe2)2}2] (R = Et, trans-1; R = Ph, trans-2; R = Me, cis-3; R = Et, cis-4), and this reaction is the first observation of metal-mediated nucleophilic addition of a guanidine to ligated nitrile. Complexes 1-4 were characterized by elemental analyses (C, H, N), X-ray diffraction, FAB mass spectrometry, IR, and 1H and 13C{1H} NMR spectroscopies; assignment of signals from E/Z-forms of 1,3-diaza-1,3-diene ligands and verification of routes for their Z right harpoon over left harpoon E isomerization in solution were performed using 2D 1H,1H-COSY, 1H,13C-HETCOR, and 1D NOE NMR experiments. The newly formed and previously unknown 1,3-diaza-1,3-dienes NH=C(R)N=C(NMe2)2 were liberated from the platinum(II) complexes [PtCl2{NH=C(R)N=C(NMe2)2}2] (1-3) by substitution with 2 equiv of 1,2-bis-(diphenylphosphino)ethane (dppe) to give the uncomplexed HN=C(R)N=C(NMe2)2 species (5-7) in solution and the solid [Pt(dppe)2](Cl)2. The former were utilized in situ, after filtration of the latter, in the reaction with 1,3-di-p-tolylcarbodiimide, (p-tol)N=C=N(tol-p), in CDCl3 to generate (6E)-N,N-dimethyl-1-(4-methylphenyl)-6-[(4-methylphenyl)imino]-1,6-dihydro-1,3,5-triazin-2-amines) (8-10) due to the [4 + 2]-cycloaddition accompanying elimination of HNMe2. The formulation of 8-10 is based on ESI-MS, 1H, 13C{1H} NMR, and X-ray crystal structures determined for 9 and 10. The reaction of 1,3-diaza-1,3-dienes with 1,3-di-p-tolylcarbodiimide, described in this article, constitutes a novel synthetic approach to a useful class of heterocyclic species like 1,6-dihydro-1,3,5-triazines. 相似文献
95.
Valeriy V. Bezrodnyi Sofia E. Mikhtaniuk Oleg V. Shavykin Igor M. Neelov Nadezhda N. Sheveleva Denis A. Markelov 《Molecules (Basel, Switzerland)》2021,26(21)
Novel peptide dendrimer with Lys-2His repeating units was recently synthesized, studied by NMR (Molecules, 2019, 24, 2481) and tested as a nanocontainer for siRNA delivery (Int. J. Mol. Sci., 2020, 21, 3138). Histidine amino acid residues were inserted in the spacers of this dendrimer. Increase of their charge with a pH decrease turns a surface-charged dendrimer into a volume-charged one and should change all properties. In this paper, the molecular dynamics simulation method was applied to compare the properties of the dendrimer in water with explicit counterions at two different pHs (at normal pH with neutral histidines and at low pH with fully protonated histidines) in a wide interval of temperatures. We obtained that the dendrimer at low pH has essentially larger size and size fluctuations. The electrostatic properties of the dendrimers are different but they are in good agreement with the theoretical soft sphere model and practically do not depend on temperature. We have shown that the effect of pairing of side imidazole groups is much stronger in the dendrimer with neutral histidines than in the dendrimer with protonated histidines. We also demonstrated that the capacity of a nanocontainer based on this dendrimer with protonated histidines is significantly larger than that of a nanocontainer with neutral histidines. 相似文献
96.
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99.
Electrochemical properties and radical anions of carbocycle‐fluorinated quinoxalines and their substituted derivatives
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Leonid A. Shundrin Irina G. Irtegova Nadezhda V. Vasilieva Pavel A. Avrorov Natalia Yu. Selikhova Arkady G. Makarov Alexander Yu. Makarov Yuri G. Slizhov Andrey V. Zibarev 《Journal of Physical Organic Chemistry》2017,30(8)
Electrochemical reduction (ECR) and oxidation (ECO) of 5,6,7,8‐tetrafluoroquinoxaline ( 1 ) and its derivatives bearing various substituents R (7‐H ( 2 ), 7,8‐H2 (3 ), 6‐CF3 ( 4 ), 6‐Cl ( 5 ), 5,7‐Cl2 ( 6 ), 5‐NH2 ( 7 ), 6‐OCH3 ( 8 ), 6,7‐(OCH3)2 ( 9 ), 6,7,8‐(OCH3)3 ( 10 ), 5,6,7,8‐(OCH3)4 ( 11 ), 6‐OCH3,7‐N(CH3)2 ( 12 ), 6‐N(CH3)2 ( 13 ), 6,7‐(N(CH3)2)2 ( 14 ), 5,6,7‐(N(CH3)2)3 ( 15 ), and 7,8‐cyclo‐(=CF‐CF = CF‐CF=) ( 16 )) in the carbocycle have been studied by cyclic voltammetry in MeCN. For 1 – 4 and 7 – 15 , the first reduction peaks have been found to be 1‐electron and reversible, thus corresponding to the formation of their radical anions (RAs), which are long lived at 295 K except those of 4 – 6 and 15 , 16 . Irreversible hydrodechlorination has been observed for 5 and 6 at the first step of their ECR confirmed by EPR detection of corresponding RAs of 2 and 5,7‐H2 derivative of 1 ( 17 ) at the next steps. Electrochemically generated RAs of 1 – 3 , 7 – 14 , and 17 have been characterized in MeCN by EPR spectroscopy together with DFT calculations at the (U)B3LYP/6‐31 + G(d) level of theory using PCM to describe the solvent. A noticeable alternation of spin density on the –NCCN– moiety of quinoxaline has been observed for all RAs possessing R‐substitution asymmetry. The comparative electron‐accepting ability of 1 – 15 has been analyzed in terms of their experimental reduction peak potentials and the (U)B3LYP/6‐31 + G(d)‐calculated gas‐phase first adiabatic electron affinities (EAs). The differences in electron transfer solvation energies for 1 – 15 have been evaluated on the basis of ECR peaks' potentials and calculated gas‐phase EAs. The ECO of 1 – 5 and 7 – 14 has been found to be irreversible. 相似文献
100.
V. M. Aynutdinov A. V. Avrorin V. A. Balkanov I. A. Belolaptikov D. Bogorodsky N. M. Budnev R. Wischnewski O. N. Gaponenko K. V. Golubkov O. A. Gress T. I. Gress O. G. Grishin I. A. Danilchenko Zh. -A. M. Dzhilkibaev G. V. Domogatsky A. A. Doroshenko A. Dyachok V. A. Zhukov A. M. Klabukov A. I. Klimov K. Konishchev A. Kochanov A. P. Koshechkin L. A. Kuzmichev V. F. Kulepov D. A. Kuleshov E. Middell M. B. Milenin R. R. Mirgazov S. P. Mikheyev E. A. Osipova A. I. Panfilov L. V. Pan’kov G. L. Pan’kov D. A. Petukhov E. N. Pliskovsky V. A. Poleshuk E. G. Popova P. G. Pokhil V. V. Prosin M. I. Rozanov V. Yu. Rubtsov O. V. Suvorova B. A. Tarashansky S. V. Fialkovsky B. A. Shaibonov A. A. Sheifler Ch. Spiering I. V. Yashin 《Bulletin of the Russian Academy of Sciences: Physics》2009,73(5):643-645
The status of the Baikal neutrino experiment is briefly reviewed and the results of the search for the natural flux of high-energy neutrinos are reported. 相似文献