Research on Chemical Intermediates - An efficient solid/slurry-state synthesis of arylidene and alkylidene malonates as versatile intermediates is developed in the presence of mesoporous... 相似文献
Research on Chemical Intermediates - A safe, green and convenient process was developed for the synthesis of a novel group of 4,8-dihydropyrano[3,2-b]-pyrans by dialkyl acetylenedicarboxylates and... 相似文献
Meccanica - The present work deals with temporal electro-aerodynamics instability properties of an inviscid confined planar jet in a zero gravity environment and the existence of electric field.... 相似文献
A practical and facile synthesis of various N-methyl imines, versatile scaffolds, was conducted at 85 °C using 4,4′-trimethylenedipiperidine as a safe and green catalyst. This reagent is a commercially available solid and can be handled easily. It has high thermal stability, low toxicity, and good solubility in green solvents such as water and ethanol. The regenerated catalyst demonstrated stable activity after several recycle runs, and any changes were detected in its chemical structure by 1H NMR monitoring. The novelty of the current work is that the 4,4′-trimethylenedipiperidine can act as a promising alternative for piperidine in organic reaction at higher temperatures due to its broad liquid range temperature, thermal stability, acceptor/donor hydrogen bond property, and other unique merits. Furthermore, the current protocol avoids waste generation in the workup process, which is a drawback in most previous reported procedures.
We designed and synthesized a novel catalyst consisting of ordered mesoporous silica (SBA-15) functionalized with bis(thiourea) (BTU) linker. The regular and unique pore channels of BTU-SBA-15 ensure proper control of the size and homogeneous distribution of palladium nanoparticles. The physiochemical properties of the hybrid Pd@BTU-SBA-15 pre-catalyst were investigated using various techniques. The proposed catalyst is found to be very active, reusable, stable and scalable, and has excellent reactivity and selectivity for Suzuki and Heck coupling reactions under very mild and sustainable reaction conditions. 相似文献
Publications mathématiques de l'IHÉS - In this paper, we prove that separation occurs for the stationary Prandtl equation, in the case of adverse pressure gradient, for a large class... 相似文献
Using the most recent differential cross section data for ep quasi-elastic scattering, the charged pion formation and its form factor Fπ is calculated in the energy range of 2.4 ~ 4 GeV at Q2 = 0.6 ~ 1.6 (GeV/c)2. The functional dependence of the charged pion form factor to the separated cross section σL is investigated and compared to the previously determined result. 相似文献