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排序方式: 共有280条查询结果,搜索用时 31 毫秒
31.
Ramon M. Barnes Nada Kovačić Gerhard A. Meyer 《Spectrochimica Acta Part B: Atomic Spectroscopy》1985,40(7):907-918
A theoretical model for calculating radial and axial temperature profiles in a nitrogen ICP discharge was improved to include the normal distribution of magnetic flux density and a three-gas flow pattern commonly used in spectrochemical applications. Calculated radial temperature and particle velocity distributions for nitrogen ICP discharges compare well with experimentally obtained data. 相似文献
32.
de la Garza L Saponjic ZV Dimitrijevic NM Thurnauer MC Rajh T 《The journal of physical chemistry. B》2006,110(2):680-686
Control of surface states of titanium dioxide nanoparticles using 2-(3,4-dihydroxyphenyl)ethylamine (dopamine) and 3,4-dihydrophenylacetic acid, which act as ligands to the undercoordinated surface sites (carrier traps), is demonstrated by electrochemical techniques. The deepest traps were found to be most reactive and are selectively removed by the addition of the ligands which enhances the kinetics of electron accumulation in the film. Furthermore, a shift in the Fermi level to more positive potentials was detected for electrodes modified with the negatively charged ligand (3,4-dihydrophenylacetic acid) compared to that of electrodes modified with the positively charged ligand (dopamine). The presence of the negative charge on the ligand also contributed to the underpotential of hydrogen evolution on 3,4-dihydrophenylacetic acid-modified electrodes. 相似文献
33.
Nada Miljević Dusan Golobočanin Nives Ogrinc Ana Bondžić 《Isotopes in environmental and health studies》2013,49(2):137-148
Stable hydrogen and oxygen isotopes were analysed in water samples from the River Danube and its tributaries during a longitudinal survey performed in August 2005 on Serbian territory. Danube river water data ranged from?80‰ to?66‰ for δ2H, and from?11.2‰ to?9.3‰ for δ18O with δ values increasing downstream. The isotopic signatures of the adjacent tributaries (the Tisza, the Sava and the Velika Morava) sampled at the locations close to their confluence with the Danube (Titel, Ostru?nica and Ljubi?evski most, respectively) just about the time of the campaign were enriched (?67‰ and?63‰ for δ2H, and?9.3‰ and?8.9‰ for δ18O) with respect to the Danube water because of their catchment effects. Hydrogen and oxygen stable isotope values were used in combination with measured physico-chemical and biological parameters to trace hydrological and transport processes in these river systems. The mixing relationships between the Danube main stream and its tributaries were estimated using the mass balance for isotopic composition and electrical conductivity as conservative parameters. Evidence of an incomplete mixing process at the ?enta location, 8 km below the confluence of the Tisza river, with its participation of 88% was shown by its oxygen-18 content. The correlations between river water isotope composition and physico-chemical and biological parameters are discussed. 相似文献
34.
对一个度量空间(X,ρ),设↓C(X)是从X到I=[0,1]的连续函数下方图形全体之集赋予由度量空间X×I上的Hausdorff度量诱导出的拓扑.本文证明了下面的结果:如果(X,ρ)是一个非紧的、局部紧的、可分的、完全有界的度量空间,则↓C(X)同胚于c0当且仅当X上的孤立点全体之集在X中不稠密,这里c0={(xn)n∈N∈[-1,1]ω:sup|x+n|<1且limn→+∞xn=0}.特别地,对赋予通常度量的开区间(0,1),↓C((0,1))同胚于c0. 相似文献
35.
Miljevic N Golobocanin D Ogrinc N Bondzic A 《Isotopes in environmental and health studies》2008,44(2):137-148
Stable hydrogen and oxygen isotopes were analysed in water samples from the River Danube and its tributaries during a longitudinal survey performed in August 2005 on Serbian territory. Danube river water data ranged from-80 per thousand to-66 per thousand for delta2H, and from-11.2 per thousand to-9.3 per thousand for delta18O with delta values increasing downstream. The isotopic signatures of the adjacent tributaries (the Tisza, the Sava and the Velika Morava) sampled at the locations close to their confluence with the Danube (Titel, Ostruznica and Ljubicevski most, respectively) just about the time of the campaign were enriched (-67 per thousand and-63 per thousand for delta2H, and-9.3 per thousand and-8.9 per thousand for delta18O) with respect to the Danube water because of their catchment effects. Hydrogen and oxygen stable isotope values were used in combination with measured physico-chemical and biological parameters to trace hydrological and transport processes in these river systems. The mixing relationships between the Danube main stream and its tributaries were estimated using the mass balance for isotopic composition and electrical conductivity as conservative parameters. Evidence of an incomplete mixing process at the Centa location, 8 km below the confluence of the Tisza river, with its participation of 88% was shown by its oxygen-18 content. The correlations between river water isotope composition and physico-chemical and biological parameters are discussed. 相似文献
36.
Maha M. Abdelrahman Neven M. Habib Aml A. Emam Hamada M. Mahmoud Nada S. Abdelwhab 《Biomedical chromatography : BMC》2020,34(4):e4804
Green TLC-densitometric and RP-HPLC methods were developed and validated for the determination of the active prodrug sulfasalazine (SZ), its active metabolite mesalazine (MZ) and the major active metabolite of mesalazine, N-acetyl-5-aminosalicylic acid (AS). In the developed TLC-densitometric method, chromatographic separation was carried out on TLC silica gel plates 60 F254 using a developing system consisting of ethyl acetate–methanol–ammonia solution 33% (8:2.5:0.3, by volume) and then scanning the separated bands at 215 nm using hydrochlorothiazide as an internal standard with linearity ranges of 0.4–3, 0.4–2.4 and 0.3–2 for SZ, MZ and AS, respectively. The developed RP-HPLC method depended on chromatographic separation using a C18 column with a solvent mixture of methanol–aqueous acetic acid solution (pH 5) as a mobile phase with gradient elution mode and UV scanning at 243 nm using pyrazinamide as internal standard with linearity ranges of 5–50, 5–40, and 3–20 for SZ, MZ and AS, respectively. US Food and Drug Administration guidelines were followed during validation of the methods. The greenness of the developed methods was estimated using the greenness profile and the Eco-Scale approach. Both methods passed the four quadrants of the greenness profile and had Eco-Scale score ˃75, thus they were considered to be green according to these approaches. 相似文献
37.
38.
Ana Đurović Zorica Stojanović Dušan Rakić Nada Grahovac 《International journal of environmental analytical chemistry》2018,98(4):369-385
In this paper, a chronopotentiometric method for the determination of herbicide metamitron (MTM) using a glassy carbon electrode (GCE) and a thin film mercury electrode (TFME) as working electrodes is presented. MTM provided a well-defined reductive peak in the Britton–Robinson buffer on both working electrodes. Instrumental and chemical factors such as pH of the buffer, initial potential and reduction current influencing MTM chronopotentiometric response were optimised with the Box–Behnken experimental design. Under the optimal combination of factors, the analytical signal was linear in the MTM concentration range of 0.8–30 mg/L, with a detection limit of 68.53 µg/L using a TFME, and in the concentration range of 1–30 mg/L, with a detection limit of 92.91 µg/L using a GCE. The precision of the method was estimated as a function of repeatability and reproducibility, with the value of relative standard deviation lower than 2.6%. The applicability of the method was verified by direct analysis of MTM in spiked water samples and commercial pesticide formulations. The obtained results were in good agreement with those obtained using liquid chromatography/tandem mass spectrometry (LC-MS/MS) method, or with those labelled by the manufacturer. By using chronopotentiometry, neither extraction nor preconcentration procedures are necessary, thus making this method simple, cost-effective and more feasible for analytical routine analysis. 相似文献
39.
40.
Nada M. Mostafa Mohamed L. Ashour Omayma A. Eldahshan 《Natural product research》2016,30(18):2093-2100
A novel biflavonoid [kaempferol (6→8″) apigenin] was isolated from the leaves of Jacaranda acutifolia. The structure was elucidated based on chemical evidence, 1D and 2D spectroscopic analyses as well as spectrometric techniques. The compound showed promising cytotoxic activity against breast cancer cell line MCF-7. The anticancer activity was explained via virtual docking of the isolated compound to the main sites in the human cyclin-dependent kinase2 (CDK2) crystal structure. 相似文献