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91.
An ‘on-water’, efficient, high yielding, expeditious method has been developed for the synthesis of 1,4-dihydropyridine (1,4-DHP) derivatives via an one-pot multi-component condensation of dimedone or 4-hydroxycoumarine, aldehydes, and ammonium acetate using Fe3O4@SiO2 nanoparticles as a recyclable heterogeneous catalyst. This method takes advantage of the fact that water, a green solvent is used in combination with Fe3O4@SiO2 nanoparticles as catalyst which can be easily recovered magnetically and reused for further runs. 相似文献
92.
Mousumi Singha Sangita Pal K. N. Hareendran S. B. Roy 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(2):961-966
A novel hydrophilic, three dimensionally cross-linked, aliphatic backbones with pendant hydroxamic acid (HA) group as functional moiety has been synthesized and utilized targeting removal of gadolinium [Gd(III)] from laboratory waste aqueous effluent. To understand the nature of sorption, gadolinium solution of various concentrations viz., 20, 10, 5.0, 1.0, 0.5 and 0.1 ppm has been contacted with a dose rate of 1 g/100 mL for 2 h. In this study, ICP-AES has been used for determination of concentration (ppm) of gadolinium in feed, filtrate and elute. EDXRF study also ensures the presence of gadolinium in the respective medium. Loaded gadolinium matrix was eluted with 1 N HCl for determining the elution factor (0.98). 相似文献
93.
Sanjoy Pal Trinath Chowdhury Kishalay Paria Sounik Manna Sana Parveen Manjeet Singh Pralay Sharma Sk Saruk Islam Sk Md Abu Imam Saadi Santi M. Mandal 《印度化学会志》2022,99(1):100244
BackgroundThe recent pandemic by COVID-19 is a global threat to human health. The disease is caused by SARS-CoV-2 and the infection rate is increased more quickly than MERS and SARS as their rapid adaptation to varied climatic conditions through rapid mutations. It becomes more severe due to the lack of proper therapeutic drugs, insufficient diagnostic tool, scarcity of appropriate drug, life supporting medical facility and mostly lack of awareness. Therefore, preventive measure is one of the important strategies to control. In this context, herbal medicinal plants received a noticeable attention to treat COVID-19 in Indian subcontinent. Here, 44 Indian traditional plants have been discussed with their novel phytochemicals that prevent the novel corona virus. The basic of SARS-CoV-2, their common way of transmission including their effect on immune and nervous system have been discussed. We have analysed their mechanism of action against COVID-19 following in-silico analysis. Their probable mechanism and therapeutic approaches behind the activity of phytochemicals to stimulate immune response as well as inhibition of viral multiplication discussed rationally. Thus, mixtures of active secondary metabolites/phytochemicals are the only choice to prevent the disease in countries where vaccination will take long time due to overcrowded population density. 相似文献
94.
Lakshminarayanan Gowtham Das Ujjalkumar Laxmi Moksha Tapas Kumar Roy Nabanita Halder Thirumurthy Velpandian 《Journal of separation science》2022,45(6):1210-1221
4-Hydroxy isoleucine is one of the potent hypoglycemic active constituents of fenugreek seeds. A method capable of reducing biological interferences is required for bioavailability studies. An isocratic separation of 4-hydroxy isoleucine from endogenous interferences was achieved in ZIC-cHILIC column using 0.1% formic acid in water and acetonitrile (20:80, % v/v) pumped at 0.5 ml/min. Quantification was performed in multiple reaction monitoring mode using the transitions of m/z 148.1→102.1 and m/z 276.1→142.2 for 4-hydroxy isoleucine and homatropine (as internal standard), respectively. After full method validation, 4-hydroxy isoleucine levels in human plasma and commercial fenugreek formulations were determined. This method showed good linearity in the range of 50–2000 ng/mL. Intra- and interday accuracies were in the range of 90.64–109.0% and precision was <4.82% CV. The mean (SD) plasma concentration of 4-hydroxy isoleucine in healthy individuals at 2 h after oral administration of fenugreek tablet was found to be 1590 (260) ng/mL. Half of marketed formulations were found to contain <0.05% of 4-hydroxy isoleucine content. We developed a rapid hydrophilic interaction liquid chromatography–tandem mass spectrometry method for analysis of 4-hydroxy isoleucine in human plasma. This method can be applied directly to conduct the clinical pharmacokinetics studies of 4-hydroxy isoleucine in human population. 相似文献
95.
96.
A. V. Filippov A. G. Zagorodny A. I. Momot A. F. Pal A. N. Starostin 《Journal of Experimental and Theoretical Physics》2007,104(1):147-161
An asymptotic theory for the screening of the electric field of a dust particle or a spherical probe in a plasma with an external steady and/or internal (proportional to the electron density) gas ionization source has been developed for the first time. It has been established that the screening of the charge of a spherical body adsorbing the charge of the incident plasma particles is described by a superposition of two exponentials with different screening constants. The two exponentials are retained even in the absence of nonequilibrium fluxes on the macroparticle and only in the special case of an isothermal plasma does the screening become Debye one. The screening length is determined by the ratio of the electron-ion, βei, and Langevin, βL = 4πeμi (where μi is the ion mobility), recombination coefficients. If βL ? βei, then it is much larger than the electron Debye length. The ions in an isothermal plasma have been found to give the same contribution to the screening as the electrons if the electron-ion recombination coefficient exceeds the Langevin ion recombination coefficient by a factor of 2 or more, βei ≥ 2βL. The Vlasov equation is used to analyze the asymptotic behavior of the macroparticle potential in a collisionless plasma. 相似文献
97.
Gabriella Kervefors Kumar Bhaskar Pal Gergely L. Tolnai Mukul Mahanti Hakon Leffler Ulf J. Nilsson Berit Olofsson 《Helvetica chimica acta》2021,104(2):e2000220
β-Galactose derivatives have recently been reported to selectively inhibit galectin-3, and a library of O3-arylated galactosides with varying substitution patterns was designed to study such inhibitions further. The O3-arylated galactosides were synthesized using diaryliodonium salts under mild and transition metal free conditions, providing the target products in moderate to good yields. An O3-trifluoroethylated galactoside was also synthesized using iodonium salt chemistry. Azido-substituted products were subsequently transformed into the corresponding triazoles. After deprotection, a selection of galactoside derivatives were evaluated for inhibitory potencies against galectins-1, 3, 4 N (N-terminal domain), 4 C (C-terminal domain), 7, 8 N, 8 C, 9 N, and 9 C and one compound with promising affinity and selectivity for both the N- and C-terminal domain of galectin-9 was discovered. 相似文献
98.
99.
100.
G. G. Midyana R. G. Makitra E. Ya. Pal’chikova 《Russian Journal of General Chemistry》2014,84(1):22-24
Rate constant of chloroacetic acid alkaline hydrolysis in the mixed aqueous-organic solvents depends on the organic co-solvent nucleophilic solvation; however, the effect of the medium polarity on the rate constant is not clear. The rate constant can be reasonably estimated with a multi-parameter equation accounting for the organic co-solvent basicity as well as its density of cohesion energy and molar volume. 相似文献