全文获取类型
收费全文 | 556篇 |
免费 | 17篇 |
国内免费 | 5篇 |
专业分类
化学 | 425篇 |
晶体学 | 5篇 |
力学 | 3篇 |
数学 | 28篇 |
物理学 | 117篇 |
出版年
2021年 | 9篇 |
2020年 | 4篇 |
2019年 | 9篇 |
2018年 | 10篇 |
2017年 | 8篇 |
2016年 | 4篇 |
2015年 | 11篇 |
2014年 | 19篇 |
2013年 | 28篇 |
2012年 | 32篇 |
2011年 | 27篇 |
2010年 | 16篇 |
2009年 | 18篇 |
2008年 | 30篇 |
2007年 | 40篇 |
2006年 | 17篇 |
2005年 | 27篇 |
2004年 | 27篇 |
2003年 | 28篇 |
2002年 | 38篇 |
2001年 | 6篇 |
2000年 | 11篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1986年 | 3篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 9篇 |
1981年 | 4篇 |
1979年 | 6篇 |
1978年 | 9篇 |
1977年 | 2篇 |
1976年 | 5篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1970年 | 2篇 |
1968年 | 2篇 |
1967年 | 7篇 |
1965年 | 2篇 |
排序方式: 共有578条查询结果,搜索用时 375 毫秒
71.
A metal-support interaction between Pd and various kinds of zeolite and metal oxide supports was studied, which were active in the catalytic combustion and selective reduction of NO. The acid-base properties of supports affected the oxidation state, structure and catalytic activity of Pd. The acid sites of zeolite played the role to anchor the dispersed PdO as evidenced by the dynamic structural change of Pd. It was found that the metal-support interaction is an important factor, affecting the oxidation state, structure and catalytic performance of Pd. 相似文献
72.
Akinori Nishino Yasushi Komori Hideaki Ujino Miki Wadati 《Studies in Applied Mathematics》2002,108(4):399-425
We study the Macdonald polynomials that give eigenstates of some quantum many-body system with long-range interactions. Scalar products of the nonsymmetric Macdonald polynomials are algebraically evaluated through their Rodrigues-type formulas. We present a new proof of Macdonald's inner product identities without recourse to the shift operators; that is, we calculate square norms of the Macdonald polynomials through Weyl-symmetrization of those of the nonsymmetric Macdonald polynomials. 相似文献
73.
74.
Single‐Crystal‐to‐Single‐Crystal Transition in an Enantiopure [7]Helquat Salt: The First Observation of a Reversible Phase Transition in a Helicene‐Like Compound
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Naba K. Nath Lukáš Severa Dr. Roman A. Kunetskiy Prof. Ivana Císařová Prof. Michal Fulem Prof. Květoslav Růžička Dr. Dušan Koval Dr. Václav Kašička Dr. Filip Teplý Prof. Panče Naumov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(39):13508-13512
Here it is reported that crystals of an enantiopure [7]helquat salt undergo reversible thermal solid–solid phase transition at 404 K. Differential scanning calorimetry (DSC), capillary electrophoresis (CE), and X‐ray diffraction analysis were used to unravel the mechanistic details of this process. The single‐crystal‐to‐single‐crystal course enabled direct monitoring of the structural changes by in situ variable‐temperature X‐ray diffraction, thus providing the first direct evidence of a solid phase transition in a helicene‐like compound. 相似文献
75.
Miki ItoFujiko Konno Takuya KumamotoNoriyuki Suzuki Masatoshi KawahataKentaro Yamaguchi Tsutomu Ishikawa 《Tetrahedron》2011,67(41):8041-8049
Both enantiomers of chelidonine, a B/C-cis-11-hydroxyhexahydrobenzo[c]phenanthridine alkaloid, were synthesized by manipulation of the B/C-dehydro ring juncture of benzo[c]phenanthridine skeleton using Sharpless asymmetric dihydroxylation and stereospecific catalytic hydrogenation after introduction of oxygen functions on the C ring as key reaction steps for the construction of stereogenic centers. 相似文献
76.
We propose a conformational search method to find a global minimum energy structure for protein systems. The simulated annealing is a powerful method for local conformational search. On the other hand, the genetic crossover can search the global conformational space. Our method incorporates these attractive features of the simulated annealing and genetic crossover. In the previous works, we have been using the Monte Carlo algorithm for simulated annealing. In the present work, we use the molecular dynamics algorithm instead. To examine the effectiveness of our method, we compared our results with those of the normal simulated annealing molecular dynamics simulations by using an α-helical miniprotein. We used genetic two-point crossover here. The conformations, which have lower energy than those obtained from the conventional simulated annealing, were obtained. 相似文献
77.
78.
79.
Miki Yumoto Takahiro Tamura Taketomo Sato Hideki Hasegawa 《Superlattices and Microstructures》2003,34(3-6):485
In view of applications to hexagonal binary decision diagram (BDD) LSIs, a first attempt is made to form quantum BDD node switches on selectively grown (SG) embedded quantum wires (QWRs) by molecular beam epitaxy (MBE). SG branch switches controlled by a Schottky wrap gate (WPG) were successfully fabricated by MBE growth and subsequent device processing. Gate control characteristics were studied by gate-dependent Shubnikov–de-Haas measurements, and the behavior was found to be similar to that of devices fabricated on wires by etching. The switch exhibited clear conductance quantization at low temperature, and temperature dependence of the voltage slope of conductance jump was clarified. A Y-branch BDD node device using two SG branch switches was successfully fabricated, and realized clear path switching characteristics. 相似文献
80.