含氟聚合物分子链的构象和柔顺性

通过对含氟聚合物分子链内旋转构象的分析,发现含氟聚合物与其它结构类型的聚合物一样,其玻璃化转变温度Tg与分子链横截面积A和分子链内旋转让阻因子σ之间的关系遵循同样的规律^[1,2]。建议用Tg=973(σ-1.44)来计算含氟聚合物的分子链内旋转位阻因子。内旋转位阻因子相同时,含氟聚合物的玻璃化转变温度较其它结构类型的聚合物为高(图2),可归结为含氟聚合物分子链的紧密堆积。     

General solutions of coupled thermoelastic problem

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长三角地区房地产市场是如何实现"去库存"的?

长三角地区在全国房地产"库存"的背景下,实现了房地产市场的不断向好.对长三角地区有关面板数据进行实证研究,实证结果表明房地产开发投资、医院床位数、工业生产总值与人均房地产成交面积呈正相关.城镇人口数,中、长期贷款利率与人均房地产成交面积呈负相关,高收入城市比低收入城市人均房地产成交面积低14.%,教育支出和城镇居民总的可支配收入对人均房地产成交面积影响不显著.     

A density-functional theory investigation on desorption of O2 on Sn（111） and its comparison with initial oxidation on the X（111） （X=Si,Ge, Sn,Pb） surfaces

<正>The first-principles calculations are performed to investigate the adsorption of O₂ molecules on an Sn（111） 2×2 surface.The chemisorbed adsorption precursor states for O₂ are identified to be along the parallel and vertical channels, and the surface reconstructions of Sn（lll） induced by oxygen adsorption are studied.Based on this,the adsorption behaviours of O₂ on X（111）（X=Si,Ge,Sn,Pb） surfaces are analysed,and the most stable adsorption channels of O₂ on X（111）（X=Si,Ge,Sn,Pb） are identified.The surface reconstructions and electron distributions along the most stable adsorption channels are discussed and compared.The results show that the O₂ adsorption ability declines gradually and the amount of charge transferred decreases with the enhancement of metallicity.     

Facile fabrication of oxygen-doped carbon nitride with enhanced visible-light photocatalytic degradation of methyl mercaptan

Research on Chemical Intermediates - Element doping has demonstrated an effective strategy for enhancing photocatalytic performance of carbon nitride (CN). Herein, we reported that oxygen-doped CN...     

In-situ self-templated preparation of porous core-shell Fe_(1-x)S@N,S co-doped carbon architecture for highly efficient oxygen reduction reaction

Transition metal compound(TMC)/carbon hybrids,as prospering electrocatalyst,have attracted great attention in the field of oxygen reduction reaction(ORR).Their morphology,structure and composition often play a crucial role in determining the ORR performance.In this work,we for the first time report the successful fabrication of porous core-shell Fe_1-xS@N,S co-doped carbon(Fe_1-xS@NSC-t,t represents etching time)by a novel in-situ self-template induced strategy using Fe3O4 nanospheres and pyrrole as sacrificial self-template.The post-polymerization of pyrrole can be accomplished by the Fe³⁺released through the etching of Fe₃O₄ by HCl acid.Thus,the etching time has a significant effect on the morphology,structure,composition a nd ORR performance of Fe_1-xS@NSC-t.Based on the cha racterizations,we find Fe_1-xS@NSC-24 can realize effective and balanced combination of Fe_1-xS and NSC,possessing porous core-shell architecture,optimized structure defect,specific surface area and doped heteroatoms configurations(especially for pyridinic N,graphitic N and Fe-N structure).These features thus lead to outstanding catalytic activity and cycling stability towards ORR.Our work provides a good guidance on the design of TMC/carbon-based electrodes with unique stable morphology and optimized structure and composition.     

Tempura-like carbon/carbon composite as advanced anode materials for K-ion batteries

Graphite as a promising anode candidate of K-ion batteries (KIBs) has been increasingly studied currently,but corresponding rate performance and cycling stabili...     

Lamb wave band gaps in locally resonant phononic crystal strip waveguides

Using finite element method, we have made a theoretically study of the band structure of Lamb wave in a locally resonant phononic crystal strip waveguide with periodic soft rubber attached on the two sides of epoxy main plate. The numerical results show that the Lamb wave band gap based on local resonant mechanism can be opened up in the stub strip waveguides, and the width of the local resonant band gap is narrower than that based on the Bragg scattering mechanism. The results also show that the stub shape and width have influence on the frequency and width of the Lamb wave band gap.     

双零色散光子晶体光纤结构参数的变化对其性能的影响

应用多极法,研究了正六边形结构光子晶体光纤的结构参数改变时,波长范围在0.8—1.8μm之间的双零色散光子晶体光纤的色散特性和非线系数随波长的变化规律.对具有相同结构参数的正六边形结构和正八边形结构进行比较,得到正六边形结构的双零色散光子晶体光纤的色散更加平坦,非线性系数有明显增大的结果.因此,正六边形结构更容易获得色散平坦的高非线性双零色散光子晶体光纤.最终设计了在800nm附近具有平坦色散和高非线性的正六边形双零色散光子晶体光纤.     

Additive Maps Preserving Nilpotent Operators or Spectral Radius

Let X be a （real or complex） Banach space with dimension greater than 2 and let B0（X） be the subspace of B（X） spanned by all nilpotent operators on X. We get a complete classification of surjective additive maps Ф on B0（X） which preserve nilpotent operators in both directions. In particular, if X is infinite-dimensional, we prove that Ф has the form either Ф（T） = cATA^-1 or Ф（T） = cAT＇A^-1, where A is an invertible bounded linear or conjugate linear operator, c is a scalar, T＇ denotes the adjoint of T. As an application of these results, we show that every additive surjective map on B（X） preserving spectral radius has a similar form to the above with ｜c｜ = 1.