Tb(III) Speciation in Human Blood Plasma by Computer Simulation

With the wide application of rare earth fertilizer and medicines1, more and more rare earths enter into environment, and also into human body via food chain. Now it is very urgent to study the biological effect of rare earths on human health and environment. After entering into human body by whatever route, lanthanide ions are transported to secondary deposition sites mainly via the plasma in the blood stream. So it is very important to study lanthanides speciation in human blood plasma. Becau…     

Jordan标准形定理的初等变换证明

本文对 Jordan标准形定理给出了一种使用初等变换的证明 ,直观意义明显、易于理解 ,可用于线性代数教学 .     

高功率毫米波圆波导TM01—TE11模式变换分析

 在数值研究高功率毫米波TM₀₁—TE₁₁光滑弯曲圆波导模式变换的基础上，对弯曲波导的几何结构进行了优化分析。在模式耦合理论的基础上，优化出了比较好的几何结构，并发现了圆波导半径、弯曲圆波导曲率和频率以及频带宽度之间的变化规律。以此数据设计的模式变换器的转换效率可达99%，带宽超过29.8%。     

具有渐近平均跟踪性质的系统

简记渐近平均跟踪性质为AASP.对于紧致度量空间上的连续映射f,证明了:(1)f有AASP当且仅当其逆极限空间上的移位映射有AASP;(2)若f有AASP且是等度连续的,则f是极小同胚.此外,讨论了AASP的拓扑共轭不变性.     

Synthesis, structural characterization and properties of a 3D infinitely extended structural rare earth coordination compound of K3{[Sm(H2O)7]2Na[α-SiW11O39Sm(H2O)4]2}·14 H2O

A 3D infinitely extended structural rare earth coordination compound with a formula of K3{[Sm(H2O)7]2Na[α-SiW11O39Sm(H2O)4]2}·14H2O has been synthesized by reaction of Sm2O3, HClO4, NaOH with α-K8SiW11O39·nH2O, and characterized by IR,UV spectra, ICP, TG-DTA, cyclic voltammetry, variable-temperature magnetic susceptibility and X-ray single-crystal diffraction.X-ray single-crystal diffraction indicates that the title compound crystallizes in a triclinic lattice, Pī space group, with a=1.2462(3) nm, b=1.2652(3) nm,c=1.8420(4) nm,α=87.45(3)°,β=79.91(3)°,γ=82.57(3)°,Z=1, R1=0.0778,wR2=0.1610.Structural analysis reveals that Sm3+(1) coordination cation has incorporated into the vacant site of [α-SiW11O39]8- entity,forming the [α-SiW11O39Sm(H2O)4]5- subunit.The two adjacent [α-SiW11O39Sm(H2O)4]5- subunits are combined with each other through two Sm(1)-O-W bridges accompanying the formation of dimmer structural unit [α-SiW11O39Sm(H2O)4]210- of the title compound.The neighboring dimmer structural units [α-SiW11O39Sm(H2O)4]210- are linked to form the 1D chainlike structure by means of two Sm3+(2) and a Na+(1) coordination cations.The K+(1) cations connect the 1D packing chains constructing the 2D netlike structure, and adjacent netlike layers are also grafted by K+(2) cations to build the novel 3D infinitely extended structure.The result of TG-DTA curves manifests that the decomposition temperature of the title polyanionic framework is 554℃.The cyclic voltammetry measurements show that the title polyanion has the two-step redox processes in aqueous solution with pH=3.1.Variable temperature magnetic susceptibility indicates the title compound obeys the Cruie-Weiss Law in the higher temperature range from 110 to 300 K, while in the lower temperature range from 2 to 110 K the comparatively strong antiferromagnetism interactions can be observed.     

Generalized Derivations with Skew Nilpotent Values on Lie Ideals

This article gives characterizations of generalized derivations with skew nilpotent values on noncommutative Lie ideals of a prime ring. The results simultaneously generalize the ones of Herstein, Lee and Carini et al.     

自抗扰控制技术在捷联惯导动基座初始对准中的应用研究

提出并设计了应用自抗扰控制技术(ADRC)的捷联惯性系统动基座初始对准方案。通过数字仿真，将卡尔曼滤波与自抗扰控制的性能进行了详细的比较，证明该方法具有对准时间快，精度高，抗干扰能力强等特点。     

神经网络算法及其在GPS导航中的应用

GPS导航解算中常采用最小二乘算法。由于导航解算中存在观测异常（粗差），采用的模型精度很难满足用户需求，而高动态用户需求的精度却不断提高，为此文中提出一种利用神经网络的非线性逼近能力，在顾及观测信息权阵的条件下，利用Hopfieid神经网络进行GPS导航解算的新算法。该算法具有很好的抗差性和自适应性，能较好地抑制观测粗差对导航解的影响。计算结果证明了该算法的有效性。     

N'-(2-羟基-5-甲氧基苯甲基)-4-二甲氨基苯甲酰肼及其氧钒(Ⅴ)配合物:合成、晶体结构和脲酶抑制活性

制备了一个苯甲酰腙化合物N'-(2-羟基-5-甲氧基苯甲基)-4-二甲氨基苯甲酰肼(H₂L)。利用H₂L、乙酰氧肟酸(HAHA)和VO(acac)₂在甲醇中反应得到了配合物[VOL(AHA)]。通过元素分析、红外和紫外光谱,以及单晶X-射线衍射对H₂L和其配合物进行了表征。苯甲酰腙配体作为二价阴离子,利用其酚羟基氧原子、亚胺基氮原子、以及烯醇氧原子与V原子进行配位。乙酰氧肟酸配体利用其羰基氧原子和去质子化的羟基氧原子进行配位。配合物中的V原子为八面体配位构型。测试了H₂L、HAHA和钒配合物的脲酶抑制活性。在浓度为100μmol·L^-1时,钒配合物对幽门螺旋杆菌脲酶的抑制率为63%,其IC₅₀值为45μmol·L^-1。还利用分子对接技术研究了配合物分子与脲酶的作用方式。