Simulation of Z-Pinch Processes of Nested Tungsten Wire-Array on Angara-5-1 Facility

Based on the hydrodynamic shell-on-shell collision model, the Z-pinch processes of nested tungsten wire-array in Sino-Russian joint experiments on Angara-5-1 facility are simulated by means of our one-dimensional three-temperature radiation magneto-hydrodynamic code. The results show the evolutions of x-ray radiation burst, implosion trajectories of interfaces, current transfer in inner and outer wire-array plasmas, and the temporal and spatial changes of magnetic field and current density in the process. About 20% of the total driven current is transferred into the inner wire-array plasma by convection and diffusion of magnetic field when the two shells are pinched closest. Compared to the measured x-ray power, the simulated full width at half maximum and time at the strongest radiation agree approximately with the measured values. It is also demonstrated in our simulation that the radiation of nested wire-array Z-pinch is enhanced. The effects of fluctuations of driven current on yields of x-ray are also investigated.     

酸性条件下多苯基取代环戊二烯的氧化扩环反应

报道了空气(或氧气)存在的条件下,由高氯酸引发多苯基取代环戊二烯发生新颖的碳-碳键断裂扩环反应,在此反应中,氧原子插入到环戊二烯环中形成相应的六元环吡喃盐类化合物.分别用红外光谱、核磁共振氢谱、碳谱、质谱以及元素分析对所得化合物进行了表征.     

A～50区同位素的相对论平均场研究

利用轴向形变相对论平均场理论计算了A～50区的核基态性质,结果表明,在Fe同位素链中最稳定的核是⁵⁶Fe和⁵⁸Fe而不是通常的⁵⁴Fe;给出了⁴⁶Cr,⁵⁰Fe和⁵⁴N(N=Z－2),⁴⁵Cr,⁴⁹Fe和⁵³Ni(N=Z－3)核的质子和中子分离能,分析了它们的稳定性.     

乳酸链球菌素Z纯化脱色小试工艺研究

Nisin Z的工业生产中利用细胞菌体吸附Nisin Z,离心后的发酵上清液(Nisin Z效价1000IU/m L左右)则通常被当成废液处理。本文建立大孔吸附树脂富集浓缩,丙酮-盐双水相脱色及中压制备型高效液相色谱精制三步法,从低浓度的发酵液上清液中回收较高纯度Nisin Z的方法。经过HZM-3树脂吸附和解吸,乳链菌肽Z的纯度由0.28%提高了95倍至26.65%,双水相脱色后Nisin Z纯度进一步提高至55.43%,经过制备分离后Nisin Z纯度达到94.12%。总回收率为71.39%,脱色率为95.7%。     

素养导向的高中化学项目教学中教师有效行为研究——以“探秘神奇的医用胶”项目教学为例

以“探秘神奇的医用胶”为主题设计实施了素养导向的项目教学。从教师行为的角度,对本次项目教学的课堂录像编码分析,发现本次项目教学的3个关键过程、7种高频行为类型、7种高频和次高频问题类型。根据编码结果回顾课堂录像,分析讨论教师在项目教学中如何通过高频行为类型、高频和次高频问题类型帮助学生建立有机物和有机反应的认识角度和认识思路,促进学生化学学科核心素养的发展。     

MODELING OF A BLOCK TARIFF SYSTEM FOR GROUNDWATER REGULATION

The block tariff system is widely used by public utility companies and governments. Because the unit rate is determined at the same time as are choice variables, the resulting endogeneity has been the subject of studies on residential water demand and in labor economics. Without discussing any mechanism that helps people come to their final decisions, these studies rely on observed data and econometric tools to estimate parameters in demand or supply functions. Because their main concern is the amount of resources devoted to a prespecified activity, their methodologies cannot analyze problems in which resources could flow to more than one outlet. This study constructs a computable framework that can deal with the endogeneity issue and help allocate scarce resources to mutually exclusive activities. Using a block tariff system for regulating groundwater extraction by aquaculture farmers in Taiwan as an example, we will show how the government and farmers can rely on the proposed framework to meet their interests.     

基于低维相变薄膜的显示器件光学性质的研究

采用传输矩阵模型研究了基于低维相变薄膜的显示器件的光学特性与器件结构的关系。显示器件的类型有反射型和透射型,器件结构的关键参数包括Ge_2Sb_2Te_5(GST)层的厚度、ITO层的厚度、GST层的晶态与非晶态的变化。结果表明:对于反射型器件,ITO层的厚度对器件的反射光谱影响较大,可以通过改变ITO层的厚度达到改变器件颜色的效果;GST层的厚度为12 nm时,GST的晶态与非晶态的变化使器件有最好的颜色对比度且消耗较低的电功率。对于透射型器件,通过使用超薄的GST薄膜,器件的透明度可以保持很高,器件的透明度在GST的厚度超过几纳米后迅速下降。     

反相液相色谱法同时检测虾仁中合成色素的研究

建立了食品虾仁中合成色素(酸性大红GR、金黄粉、橙黄G、酸性红1号、酸性红26)的反相液相色谱同时检测方法。并且对提取剂、NH4Ac浓度和离子对种类等因素进行优化,使得5种色素完全分离,并且在色谱图上能与国标内的6种色素完全分离。金黄粉、酸性大红GR、橙黄G、酸性红1号、酸性红26的回收率均在80%以上,在0.05~10μg/mL范围内有良好的线性关系,相关系数大于0.9998。本法可用于食品虾仁中合成着色剂的快速检测。     

羟丙哌嗪分子印迹的固相萃取

以L-羟丙哌嗪为模板分子, α-甲基丙烯酸为功能单体, 三羟甲基丙烷三甲基丙烯酸酯为交联剂, 合成了羟丙哌嗪分子印迹聚合物, 利用该聚合物进行羟丙哌嗪固相萃取应用研究. 实验证明, 所合成的分子印迹聚合物具有良好的识别萃取模板分子羟丙哌嗪的能力, 能够用于羟丙哌嗪的富集浓缩, 而空白聚合物却不具备这样的特性. 考察了模板分子与其结构类似物苄基哌嗪、N-异丙基哌嗪和乙氧基羰基哌嗪的固相萃取分离情况, 研究表明, 虽然其中的苄基哌嗪在印迹材料上具有最强的保留, 但是通过先后使用不同的洗脱溶液实现了模板分子与苄基哌嗪的选择性分离.探讨了印迹识别机理,并用PM3 半经验计算机模拟方法进行了辅助分析验证.     

乙嘧酚磺酸酯中杂质的GC-MS分析

嘧啶类化合物因具有不同的生物活性,如杀虫、杀菌、除草、抗病毒等[1-2],引起人们的广泛兴趣.乙嘧酚磺酸酯(bupirimate)属于嘧啶类内吸性杀菌剂,具有用量少、高效、低毒、对白粉病有特效等优点,因此取代了乙嘧酚和二甲嘧酚等农药.目前乙嘧酚磺酸酯的合成与生物活性研究已成为当今绿色农药创制的热点[3].