Characterization of new-layered Cr(III)-doped chlorocadmiumphosphate, Cd(HPO4)Cl·[H3N(CH2)6NH3]0.5 crystal by EPR and optical studies

Cr(III)-doped Cd(HPO₄)Cl·[H₃N(CH₂)₆NH₃]_0.5, a new-layered cadmium phosphate, is synthesized in acidic condition at room temperature. EPR and optical studies are carried out at room temperature. Polycrystalline EPR spectrum reveals the presence of two sites of Cr(III) ions in this layered phosphate lattice with zero-field splitting values of 24.24 and 7.65 mT, indicating that Cr(III) ions are in distorted octahedral sites. The optical absorption spectrum of the sample indicates near octahedral symmetry for the dopant ions. Crystal field, inter-electronic and bonding parameters are evaluated by collaborating EPR and optical data. The evaluated parameters suggest the mode of entry of Cr(III) ion into the layered phosphate as interstitial site, and bonding between the metal and ligand is partially covalent.     

Polymer assisted assembling of the semiconductor particles: Structural and electrical studies

CdS and Si semiconductor nanopraticles were embedded in a polymer matrix and characterized using various techniques. The surface properties and size distribution of the nanoparticles were monitored by POM and SEM and found to be uniform but around the crystalline frameworks of the polymer. XRD and FTIR analysis have been used to ensure the composite nature and particle size of the semiconductor loaded films. The electrical conductivity of these films were evaluated and found to increase with semiconductor dispersion and attains a percolation threshold at optimum composition. This composition and the distribution of the clusters is shown to vary with the type of the semiconductor, i.e., CdS or Si.     

光孤子对的振幅比与相位差对传输的影响

利用分步傅里叶变换法分别求解含三阶色散效应和不考虑三阶色散情况下的光孤子非线性薛定谔（NLS）方程,通过数值求解发现三阶色散效应会使孤子对脉冲发生单边振荡,并在振荡侧逐级产生次脉冲。讨论孤子对的两束孤子脉冲之间的振幅比与相位差对传输的影响,发现在不考虑三阶色散的情况下,振幅比与相位差均对孤子对的传输有显著影响,在考虑三阶色散效应时,只有相位差对孤子对的传输产生影响,并可以导致脉冲能量转移。     

高效液相色谱法同时测定心可舒胶囊中齐墩果酸和熊果酸

建立高效液相色谱法同时测定心可舒胶囊中齐墩果酸和熊果酸的含量。采用HypersiL ODSC₁₈（4.6mm×250mm,5μm）色谱柱;流动相:甲醇-乙腈-水=79:5:16（V/V/V）;柱温:30℃;流速:1mL/min;检测波长:210nm。齐墩果酸在2.04—81.60μg/mL浓度范围内线性关系良好（r=0.9998）,熊果酸在5.00—80.00μg/mL浓度范围内线性关系良好（r=0.9998）,齐墩果酸的平均回收率为100.54%,RSD为1.56%,熊果酸的平均回收率为101.10%,RSD为1.13%。该法简单、准确、快捷,可用于心可舒胶囊中齐墩果酸和熊果酸的含量测定。     

基于多项式模型的混沌系统平方和算法脉冲控制

针对一大类混沌系统,提出一种新颖的基于多项式模型的脉冲控制方法.首先,建立系统的多项式模型.其状态方程由系统状态的多项式矩阵与其单项式组成列向量构成.与其他建模方法相比,该方法不必使用任何预制的假设.其次,提出基于平方和优化算法的脉冲控制方法,使得混沌系统的状态能够实现渐近稳定.基于该算法的脉冲控制与基于线性矩阵不等式凸优化算法的结果相比,能得到更大的脉冲间距,从而可以使用较少的控制能量实现同样的控制效果.最后,仿真实验结果验证了本方法的有效性.     

Mechanically strengthened new Hagi porcelain developed by controlling the chemical environment of iron

In order to enhance the mechanical strength of Hagi Porcelain (Hagiyaki), one of the oldest and famous potteries in Japan, new preparation condition was examined. Tempered Hagi porcelain, denominated as ‘Hagi Porcelain B’, was prepared with the Porcelain clay originating from Daido district, Yamaguchi Prefecture, Japan. Structural change of ‘Hagi Porcelain B’ was investigated by means of ⁵⁷Fe-Mössbauer spectroscopy, X-ray diffractometry (XRD) and three-point bending test. Mechanical strength of the ‘original Hagi Porcelain B’ was estimated to be 43.1 MPa by means of the three-point bending test, while much larger value of 104.5 MPa could be achieved when tempered by a chemical modification. Mössbauer spectrum of the ‘original Hagi porcelain B’ was composed of a paramagnetic doublet and a magnetic sextet due to Fe(III) of γ-Fe₂O₃(maghemite), while only one paramagnetic doublet due to to octahedral Fe(II)O₆ was observed for the ‘tempered Hagi Porcelain B’ with isomer shift and quadrupole splitting values of 1.13 and 2.15 mm s^?1, respectively. It is considered that the absence of magnetic phase causes an increase of the mechanical strength because the maghemite phase has a defect spinel structure. These results indicate that mechanical strength of the ‘Hagi porcelain B’ could be enhanced by controlling the sintering condition.     

氟化锂和蓝宝石单晶冲击消光及其对辐射测温的影响

采用冲击波压缩原位光源技术结合时间分辨多波长高温计测量,研究了氟化锂和蓝宝石单晶样品的冲击消光现象,实验压力范围50～183了GPa,中心波长覆盖254～800 nm.结果表明,氟化锂单晶样品在实验压力下透过率变化不大,对界面温度的拟合值影响不明显,只是使表观发射率略有下降;当压力低于90GPa时,蓝宝石的消光情况同氟化锂接近,对界面温度的拟合影响也不明显;而当压力高于99 GPa时,蓝宝石呈现明显的消光衰减现象,实验测定的消光系数随压力增加而增加,与波长间呈反比关系,与文献报道250 0Pa高压消光特性一致.研究还发现,蓝宝石窗高压消光行为对界面温度的测量存在较大的影响,使得拟合温度明显偏低.本文研究对发展非透明材料冲击测温技术具有一定的参考价值.     

红外偏振成像对伪装目标的探测识别研究

针对目前普通光电成像系统对伪装目标的探测和识别概率较低的状况,提出伪装目标的探测识别新技术研究。介绍了红外偏振成像系统的原理、组成和特点,研制的中波/长波红外偏振成像装置,其波段范围为3 m ~5 m和8 m~12 m,线偏振度95%,消光比大于100∶1,给出了试验分析数据和偏振融合效果图。研究表明,采用红外偏振成像技术可以有效地实现对地面伪装目标的探测和识别。研究结果还可以扩展到对人工假目标、空中隐身目标等的探测和识别。     

大口径非球面主反射镜的装调方法研究

针对大口径非球面主反射镜（简称主镜）的装调要求,对比分析常用大口径非球面面形检测方法,提出该类主镜检测面形的最佳方案。在主镜的装调过程中,通过对主镜的固定方式和主镜变形补偿这2个关键环节的阐述,总结主镜固定的难点及主镜变形的原因,提出一套全新的装调方案,以旋转消重力法进行检测,并用专用工装实时定心调节,再用辅料焊接法固定主镜与中心轴,最后采用辅助支撑对主镜组件进行最终固定修正。装调结果表明:对于大口径非球面反射镜,装调完成后的主镜面形精度Rms0.03（＝632.8 nm）。     

含散射闪光照相系统的布局优化

为了提高现有照相系统的图像品质,对使用CCD探测器的法国客体(FTO)照相布局进行了优化,获得最佳图像品质因子下的照相布局。研究结果为:在模糊实验测量结果和高斯分布近似下,系统放大倍率为2.0;后保护器件距离客体50 cm;系统布局总长与探测系统的噪声相关,噪声越大,布局总长越短,最优布局总长的范围为3~5 m;实验验证了这一结果。