全文获取类型
收费全文 | 236837篇 |
免费 | 9272篇 |
国内免费 | 1811篇 |
专业分类
化学 | 143607篇 |
晶体学 | 3676篇 |
力学 | 10660篇 |
综合类 | 10篇 |
数学 | 23541篇 |
物理学 | 66426篇 |
出版年
2021年 | 2101篇 |
2020年 | 3196篇 |
2019年 | 5079篇 |
2018年 | 4615篇 |
2017年 | 4286篇 |
2016年 | 8059篇 |
2015年 | 5745篇 |
2014年 | 7574篇 |
2013年 | 12465篇 |
2012年 | 9565篇 |
2011年 | 9991篇 |
2010年 | 9146篇 |
2009年 | 9311篇 |
2008年 | 9817篇 |
2007年 | 9179篇 |
2006年 | 7997篇 |
2005年 | 7405篇 |
2004年 | 6950篇 |
2003年 | 6369篇 |
2002年 | 7036篇 |
2001年 | 6907篇 |
2000年 | 5366篇 |
1999年 | 3464篇 |
1998年 | 2724篇 |
1997年 | 2782篇 |
1996年 | 2543篇 |
1995年 | 2212篇 |
1994年 | 2326篇 |
1993年 | 2226篇 |
1992年 | 2525篇 |
1991年 | 2647篇 |
1990年 | 2554篇 |
1989年 | 2625篇 |
1988年 | 2532篇 |
1987年 | 2552篇 |
1986年 | 2413篇 |
1985年 | 3034篇 |
1984年 | 3101篇 |
1983年 | 2601篇 |
1982年 | 2568篇 |
1981年 | 2530篇 |
1980年 | 2335篇 |
1979年 | 2713篇 |
1978年 | 2673篇 |
1977年 | 2874篇 |
1976年 | 2873篇 |
1975年 | 2667篇 |
1974年 | 2602篇 |
1973年 | 2713篇 |
1972年 | 2088篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
Behavior of a poro-elastic material bonded onto a vibrating plate is investigated in the low-frequency range. From the analysis of dissipation mechanisms, a model accounting for damping added by the porous layer on the plate is derived. This analysis is based on a 3-D finite element formulation including poro-elastic elements based on Biot displacement theory. First, dissipated powers related to thermal, viscous and viscoelastic dissipation are explicited. Then a generic configuration (simply-supported aluminium plate with a bonded porous layer and mechanical excitation) is studied. Thermal dissipation is found negligible. Viscous dissipation can be optimized as a function of airflow resistivity. It can be the major phenomenon within soft materials, but for most foams viscoelastic dissipation is dominant. Consequently an equivalent plate model is proposed. It includes shear in the porous layer and only viscoelasticity of the skeleton. Excellent agreement is found with the full numerical model. 相似文献
122.
Yong‐Jin Kim Jin‐Woong Kim Jung‐Eun Lee Jee‐Hyun Ryu Junoh Kim Ih‐Seop Chang Kyung‐Do Suh 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5627-5635
Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004 相似文献
123.
Pedro lvarez‐Boo Jos Sergio Casas Alfonso Castieiras María Delfina Couce Eduardo Freijanes Eva Novoa Jos Sordo 《应用有机金属化学》2003,17(9):725-729
Reaction of dichloro‐ and dibromodimethyltin(IV) with 2‐(pyrazol‐1‐ylmethyl)pyridine (PMP) afforded [SnMe2Cl2(PMP)] and [SnMe2Br2(PMP)] respectively. The new complexes were characterized by elemental analysis and mass spectrometry and by IR, Raman and NMR (1H, 13C) spectroscopies. Structural studies by X‐ray diffraction techniques show that the compounds consist of discrete units with the tin atom octahedrally coordinated to the carbon atoms of the two methyl groups in a trans disposition (Sn? C = 2.097(5), 2.120(5) Å and 2.110(6), 2.121(6) Å in the chloro and in the bromo compounds respectively), two cis halogen atoms (Sn? Cl = 2.4908(16), 2.5447(17) Å; Sn? Br = 2.6875(11), 2.7464(9) Å) and the two donor atoms of the ligand (Sn? N = 2.407(4), 2.471(4) Å and 2.360(5), 2.455(5) Å). In both cases, the Sn? N(pyridine) bond length is markedly longer than the Sn? N(pyrazole) distance. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
124.
Studies in the field of radical copolymerization of N-vinylsuccinimide were summarized, theeffect of the reaction medium on the process kinetics was examined. Factors governing the relative activity ofthe monomers were revealed, and ways to control the reactivity of N-vinylsuccinimide in binary copolymerizations were suggested. 相似文献
125.
126.
In this work, the melting behaviors of nonisothermally and isothermally melt‐crystallized poly(L ‐lactic acid) (PLLA) from the melt were investigated with differential scanning calorimetry (DSC) and temperature‐modulated differential scanning calorimetry (TMDSC). The isothermal melt crystallizations of PLLA at a temperature in the range of 100–110 °C for 120 min or at 110 °C for a time in the range of 10–180 min appeared to exhibit double melting peaks in the DSC heating curves of 10 °C/min. TMDSC analysis revealed that the melting–recrystallization mechanism dominated the formation of the double melting peaks in PLLA samples following melt crystallizations at 110 °C for a shorter time (≤30 min) or at a lower temperature (100, 103, or 105 °C) for 120 min, whereas the double lamellar thickness model dominated the formation of the double melting peaks in those PLLA samples crystallized at a higher temperature (108 or 110 °C) for 120 min or at 110 °C for a longer time (≥45 min). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 466–474, 2007 相似文献
127.
The kinetics of hydrogen peroxide decomposition in a guaiacol solution, catalyzed by potassium hexacyanoferrate(II), were studied. The reaction mainly follows the pathway of guaiacol hydroxylation. The reaction order is 1 with respect to H2O2, 0.5 with respect to hexacyanoferrate, and from 0.4 to 0 with respect to guaiacol (the latter parameter decreases with increasing guaiacol concentration). The apparent activation energy is 105 kJ mol-
1. A kinetic scheme of the process was proposed. An expression consistent with the experiment was obtained for the rate of hydrogen peroxide decomposition in the presence of guaiacol, catalyzed by hexacyanoferrate(II). 相似文献
128.
Nikulin S. S. Akatova I. N. Kondrat'eva N. A. 《Russian Journal of Applied Chemistry》2003,76(4):652-655
The influence of the charge of a metal cation and the nature of a coagulant on the recovery of butadiene-styrene rubber and properties of rubber stocks and vulcanizates was examined. 相似文献
129.
N. Dolbilin 《Discrete and Computational Geometry》1995,13(1):405-414
If a given finite protoset, together with a given finite matching rule, gives rise to at most countably many different tilings
ofd-dimensional space, then at least one of them is periodic.
This research was supported in part by the SFB 343 “Diskrete Strukturen in der Mathematik” at Bielefeld University and the
Russian Foundation for Fundamental Research. 相似文献
130.
N. B. Voznesensky E. V. Gavrilov A. P. Zhevlakov V. K. Kirillovskiĭ P. V. Orlov 《Technical Physics》2007,52(2):271-275
Methods and schemes to inspect the EUV mirror shape are developed on the basis of a point diffraction interferometer with computer processing of interferograms. A measurement accuracy to within 0.001 of a wavelength in the visual range is achieved. 相似文献