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91.
Mary E. Neubert DAVID G. ABDALLAH Jr Sandra S. Keast Julie M. Kim Soonnam Lee Ryan M. Stayshich Margaret E. Walsh Rolfe G. Petschek Shin-Tson Wu 《Liquid crystals》2003,30(6):711-731
New diphenyldiacetylenes of the type with A, B = H and/or F; m = 0, 1; n = 1-4; and X = C n H 2n + 1 , F, CF 3 or CN were synthesized and their mesomorphic properties determined by hot stage polarizing microscopy and DSC. When m = 0, all of these compounds showed only a nematic phase except when X = CF 3 when both nematic and smectic A phases were seen. Both clearing and melting temperatures were higher than those reported for substitution with the corresponding alkyl chains but the much larger increase in clearing temperatures produced considerably wider nematic phases. Eutectic mixtures of a few of these olefins yielded nematic materials also having much wider temperature ranges and higher clearing temperatures than the eutectic mixtures of the alkyl compounds, while retaining their high birefringence and low viscosities. Such materials are of interest for beam-steering devices.
Four of the diacetylenes with m = 1 ( A, B = H) were also prepared ( X = C 6 H 13 , F, n = 2, 3). When X was C 6 H 13 ( n = 2), the nematic range was smaller in the 2- than in the 1-olefin but wider than in the alkyl series. When X = F, either no nematic phase or a monotropic one was observed, whereas the 1-olefins gave a much wider nematic phase. Both transition temperatures were lower than those for the corresponding 1-olefin and alkyl analogues. The compound with X = C 6 H 13 and n = 2 had a melting temperature below room temperature. 相似文献
Four of the diacetylenes with m = 1 ( A, B = H) were also prepared ( X = C 6 H 13 , F, n = 2, 3). When X was C 6 H 13 ( n = 2), the nematic range was smaller in the 2- than in the 1-olefin but wider than in the alkyl series. When X = F, either no nematic phase or a monotropic one was observed, whereas the 1-olefins gave a much wider nematic phase. Both transition temperatures were lower than those for the corresponding 1-olefin and alkyl analogues. The compound with X = C 6 H 13 and n = 2 had a melting temperature below room temperature. 相似文献
92.
N. M. Bogoliubov 《Journal of Mathematical Sciences》2007,143(1):2729-2737
We consider random walks of two essentially different classes of random walkers, namely, of vicious and friendly ones, on
one-dimensional lattices with periodic boundary conditions. The walkers are called vicious since, arriving at a lattice site,
they annihilate not only one another but all the remaining walkers as well. On the contrary, an arbitrary number of friendly
walkers can share the same lattice sites. It is shown that a natural model describing the behavior of friendly walkers is
an integrable model of the boson type. A representation of the generating function for the number of the lattice paths performed
by a fixed number of friendly walkers for a certain number of steps is obtained. Bibliography: 22 titles.
__________
Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 335, 2006, pp. 59–74. 相似文献
93.
94.
Raman scattering in glasses is investigated theoretically. The experimental Raman spectra of glasses exhibit a low-frequency peak (at ~10 cm?1) that, as a rule, is attributed to vibrational modes of nanometer-sized structural units (nanocrystallites). It is established that the elastic moduli of nanocrystallites must necessarily be dependent on their sizes due to the Laplace pressure effect. A theory of the low-frequency peak is constructed using a realistic size distribution function of nanocrystallites with allowance made for the Laplace pressure effect and the dissipation of vibrational energy. Within this theory, the shape of the low-frequency peak and its evolution with temperature can be analyzed quantitatively. The proposed approach offers a physical interpretation of the experimental data and provides insight into the relation of the characteristic nanocrystallite sizes to the elastic moduli and surface tension coefficients of materials. 相似文献
95.
96.
An experimental apparatus and related procedures for the determination of the effective thermal conductivity of sintered powder-metal
plates saturated with distilled water at temperatures in the range 20–150°C are discussed. The apparatus and procedures are
applied to two samples of sintered powder-metal plates, one made of nickel 200 and the other of stainless steel 316, with
porosities of 28.10 and 46.45%, respectively, and each of nominal dimensions 127 mm × 127 mm × 6.35 mm. The experimental
results are compared with corresponding predictions yielded by several correlations available in the literature. The correlations
based on experimental data for packed beds of spherical particles and also porous plates made of cold-pressed (but not sintered)
particles of angular shapes do not apply well to sintered powder-metal plates. A new correlation, which is based on extensions
of ideas contained in earlier works and provides improved predictions, is proposed. 相似文献
97.
98.
99.
A model of an expanding and rotating universe is constructed in the framework of general relativity. The parameters of the model are compared with the fundamental observables and shown to be in good agreement.Kaluzhsk Branch, N. É. Bauman Moscow State Technical University (MGTU). Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 71–77, June, 1993. 相似文献
100.
The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ± 0.3) × 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experimental data and calculations. Several possible reaction channels are discussed, and although products were not monitored, it seems probable, on the basis of other work and theoretical estimates, that the primary mechanism (?75%) for the removal of OH by CH3 at these conditions is their combination to form CH3OH. Rate coefficients of (5.3 ± 0.8) × 1012 and (9.0 ± 1.4) × 1012 cm3/mol-s were measured for the reactions of OH with acetone and ethane, respectively, at the same temperature and pressure. 相似文献