首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   234535篇
  免费   4620篇
  国内免费   2888篇
化学   122525篇
晶体学   3905篇
力学   12433篇
综合类   171篇
数学   24981篇
物理学   78028篇
  2022年   2116篇
  2021年   2768篇
  2020年   2829篇
  2019年   3303篇
  2018年   4403篇
  2017年   4328篇
  2016年   5865篇
  2015年   3334篇
  2014年   5583篇
  2013年   10412篇
  2012年   9189篇
  2011年   10634篇
  2010年   8259篇
  2009年   8383篇
  2008年   9594篇
  2007年   9390篇
  2006年   8534篇
  2005年   7417篇
  2004年   6874篇
  2003年   6174篇
  2002年   6140篇
  2001年   6847篇
  2000年   5063篇
  1999年   4025篇
  1998年   3297篇
  1997年   3357篇
  1996年   3112篇
  1995年   2697篇
  1994年   2784篇
  1993年   2571篇
  1992年   2867篇
  1991年   2932篇
  1990年   2814篇
  1989年   2838篇
  1988年   2727篇
  1987年   2694篇
  1986年   2533篇
  1985年   3149篇
  1984年   3185篇
  1983年   2659篇
  1982年   2600篇
  1981年   2573篇
  1980年   2359篇
  1979年   2726篇
  1978年   2687篇
  1977年   2888篇
  1976年   2899篇
  1975年   2689篇
  1974年   2620篇
  1973年   2727篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
Journal of Nanoparticle Research - It was shown that the thermoelastic martensite transformation B2 ? B19 inside nanoparticles surrounded by amorphous matrix in Ni–Ti–Cu alloys as...  相似文献   
72.
The results of optical study and quantum-chemical simulation of a conjugated organic system, 2-cyclooctylamino-5-nitropyridine (COANP)-fullerene, performed to determine its potential for application as a limiter of visible and near-IR laser radiation and as a material for diffraction elements in systems for reversible recording of optical information, are presented. Complexation between a COANP molecule and fullerene is considered as one of the main mechanisms responsible for the corresponding properties of this system. For the first time, nonlinear optical characteristics of COANP-C60 and COANP-C70 systems are comparatively studied and the intermolecular interaction between a COANP molecule and fullerene is analyzed on the quantum-chemical level.  相似文献   
73.
We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na+), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed.  相似文献   
74.
Behavior of a poro-elastic material bonded onto a vibrating plate is investigated in the low-frequency range. From the analysis of dissipation mechanisms, a model accounting for damping added by the porous layer on the plate is derived. This analysis is based on a 3-D finite element formulation including poro-elastic elements based on Biot displacement theory. First, dissipated powers related to thermal, viscous and viscoelastic dissipation are explicited. Then a generic configuration (simply-supported aluminium plate with a bonded porous layer and mechanical excitation) is studied. Thermal dissipation is found negligible. Viscous dissipation can be optimized as a function of airflow resistivity. It can be the major phenomenon within soft materials, but for most foams viscoelastic dissipation is dominant. Consequently an equivalent plate model is proposed. It includes shear in the porous layer and only viscoelasticity of the skeleton. Excellent agreement is found with the full numerical model.  相似文献   
75.
The ring‐opening polymerization of ε‐caprolactone (ε‐CL), initiated by carboxylic acids such as benzoic acid and chlorinated acetic acids under microwave irradiation, was investigated; with this method, no metal catalyst was necessary. The product was characterized as poly(ε‐caprolactone) (PCL) by 1H NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet spectroscopy, and gel permeation chromatography. The polymerization was significantly improved under microwave irradiation. The weight‐average molecular weight (Mw) of PCL reached 44,800 g/mol, with a polydispersity index [weight‐average molecular weight/number‐average molecular weight (Mw/Mn)] of 1.6, when a mixture of ε‐CL and benzoic acid (25/1 molar ratio) was irradiated at 680 W for 240 min, whereas PCL with Mw = 12,100 and Mw/Mn = 4.2 was obtained from the same mixture by a conventional heating method at 210 °C for 240 min. A degradation of the resultant PCL was observed during microwave polymerization with chlorinated acetic acids as initiators, and this induced a decrease in Mw of PCL. However, the degradation was hindered by benzoic acid at low concentrations. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 13–21, 2003  相似文献   
76.
Studies in the field of radical copolymerization of N-vinylsuccinimide were summarized, theeffect of the reaction medium on the process kinetics was examined. Factors governing the relative activity ofthe monomers were revealed, and ways to control the reactivity of N-vinylsuccinimide in binary copolymerizations were suggested.  相似文献   
77.
78.
The kinetics of hydrogen peroxide decomposition in a guaiacol solution, catalyzed by potassium hexacyanoferrate(II), were studied. The reaction mainly follows the pathway of guaiacol hydroxylation. The reaction order is 1 with respect to H2O2, 0.5 with respect to hexacyanoferrate, and from 0.4 to 0 with respect to guaiacol (the latter parameter decreases with increasing guaiacol concentration). The apparent activation energy is 105 kJ mol- 1. A kinetic scheme of the process was proposed. An expression consistent with the experiment was obtained for the rate of hydrogen peroxide decomposition in the presence of guaiacol, catalyzed by hexacyanoferrate(II).  相似文献   
79.
The influence of the charge of a metal cation and the nature of a coagulant on the recovery of butadiene-styrene rubber and properties of rubber stocks and vulcanizates was examined.  相似文献   
80.
If a given finite protoset, together with a given finite matching rule, gives rise to at most countably many different tilings ofd-dimensional space, then at least one of them is periodic. This research was supported in part by the SFB 343 “Diskrete Strukturen in der Mathematik” at Bielefeld University and the Russian Foundation for Fundamental Research.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号