Fundamental aspects of initiated oxidation of tridecane and polyethylene in solutions

Specific features of the initiated oxidation of polyethylene and its low-molecular-weight analogue tridecane, associated with the occurrence of the process in the short-chain mode, were studied.     

Thermal and dielectric behaviors of poly(vinylidene fluoride-trifluoroethylene) copolymers at the curie transition

The thermal and dielectric behaviors of poly(vinylidene fluoride-trifluoroethylene) copolymers near the ferroelectric-to-paraelectric phase transition are investigated for samples with 20, 25, 30, and 40 mol% trifluoroethylene (TrFE). The data suggest that the transition becomes continuous for a particular composition near 50 mol% TrFE. Experimental data are sensitive to thermal history (kinetics of crystallization, and kinetics and cycling over the structural transition). It is found that several anomalies are present at the structural change, and in particular the 30 mol% TrFE sample shows the most marked anomalies. These phenomena can be attributed to defects, but another possibility would be the existence of an intemediate supplementary phase. Both hypotheses are discussed.     

1,1,3-Trimethyl-3-phenylindan as a Luminescent Additive to a Plastic Scintillator Based on Poly(methyl Methacrylate)

The luminescence and scintillation properties of poly(methyl methacrylate) containing 1,1,3-trimethyl-3-phenylindan were studied.     

Depth profile analysis of polyimide film treated by potassium hydroxide

The structural change in the depth direction of a polyimide (UPILEX‐S) film treated in alkaline solution, which was a representative surface treatment used to form a seed layer for plating and to improve the adhesive strength, was analyzed by means of micro Fourier transform infrared attenuated total reflection (FTIR‐ATR) line analysis with gradient shaving preparation. The polyimide film was treated with KOH. The imide ring opened through the alkaline treatment, and the amide structure and carboxylic acid salt were formed. The attainment depth of this structural change was almost proportional to the treatment time, and it reached about 8 μm after a 30‐min treatment. The degree of structural change through the alkaline treatment was almost constant after it reached a considerably degraded stage, and the chemically changed region penetrated into the inner part of the film from the surface. An intermediate layer before the final degraded stage appeared in the treated layer, and its thickness increased with the treatment time. The region that was changed chemically by the alkaline treatment progressed to the inner part simultaneously and continuously as the treatment time increased. The combined use of gradient shaving preparation and micro FTIR‐ATR line analysis was found to be extremely effective for the depth profiling of organic materials. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2071–2078, 2003     

Generalized Artin–Hasse and Iwasawa Formulas for the Hilbert Symbol in a High-Dimensional Local Field

The generalized Hilbert symbol in a cyclotomic extension of an absolutely unramified higher local field of characteristic 0 with a perfect last residue field of characteristic p > 2 is considered. Generalized Artin–Hasse and Iwasawa formulas are derived from an explicit Kummer Type Vostokov formula. Bibliography: 13 titles.     

Decrease in the group velocity of a light pulse in the Bose-Einstein condensate of a dilute gas

A semiclassical theory of electromagnetically induced transparency in a Bose-Einstein condensate is considered. A nonlinear Schrödinger equation that describes the interaction of the Bose-Einstein condensate with an electromagnetic field is derived. An analysis of the obtained solutions to this equation demonstrates a decrease in the group velocity of the light pulse.     

Martensite Transformation in Nanoparticles and Nanomaterials

Journal of Nanoparticle Research - It was shown that the thermoelastic martensite transformation B2 ? B19 inside nanoparticles surrounded by amorphous matrix in Ni–Ti–Cu alloys as...     

Optical limiters and diffraction elements based on a COANP-fullerene system: Nonlinear optical properties and quantum-chemical simulation

The results of optical study and quantum-chemical simulation of a conjugated organic system, 2-cyclooctylamino-5-nitropyridine (COANP)-fullerene, performed to determine its potential for application as a limiter of visible and near-IR laser radiation and as a material for diffraction elements in systems for reversible recording of optical information, are presented. Complexation between a COANP molecule and fullerene is considered as one of the main mechanisms responsible for the corresponding properties of this system. For the first time, nonlinear optical characteristics of COANP-C₆₀ and COANP-C₇₀ systems are comparatively studied and the intermolecular interaction between a COANP molecule and fullerene is analyzed on the quantum-chemical level.     

Effect of maltodextrins on the surface activity of small-molecule surfactants

We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na⁺), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed.     

Investigation and modelling of damping in a plate with a bonded porous layer

Behavior of a poro-elastic material bonded onto a vibrating plate is investigated in the low-frequency range. From the analysis of dissipation mechanisms, a model accounting for damping added by the porous layer on the plate is derived. This analysis is based on a 3-D finite element formulation including poro-elastic elements based on Biot displacement theory. First, dissipated powers related to thermal, viscous and viscoelastic dissipation are explicited. Then a generic configuration (simply-supported aluminium plate with a bonded porous layer and mechanical excitation) is studied. Thermal dissipation is found negligible. Viscous dissipation can be optimized as a function of airflow resistivity. It can be the major phenomenon within soft materials, but for most foams viscoelastic dissipation is dominant. Consequently an equivalent plate model is proposed. It includes shear in the porous layer and only viscoelasticity of the skeleton. Excellent agreement is found with the full numerical model.