Mössbauer study of Martian regolith analogues

Terrestrial basalt rocks considered to be a good analogues of the Martian regolith were studied by using the Mössbauer spectroscopy and X-ray diffraction. The weathering of basalts was followed by the changes of the Fe²⁺/Fe³⁺ ratio. The basalt rock undergoes alteration from primary mineral composition (olivine+pyroxene+plagioclase) through smectite to kaolinite clay with oxides and hydroxides with the increase of the Fe²⁺/Fe³⁺ ratio.     

Inclusion of transverse quark momenta in the quark-gluon string model

The dependence of distribution functions of quarks, antiquarks, diquarks and their fragmentation into hadrons on the transverse momentumk _t is discussed in the frame of the quark-gluon string model. We then discuss the division ofk _t between 2n-quark-antiquark chains, orn-pomeron showers. Hadron and hadron-nuclear processesp?p,p?A,K ⁺?p,K ⁺?A are analysed. A strong dependence of the observed values on the numbern is derived by this method, which is of special importance for the analysis of hadron-nucleus collisions. Our method is compared with the regulark _t division method.     

Antiferromagnetic and superconducting states in the three-band two-dimensional repulsive Hubbard model

The three-band two-dimensional repulsive Hubbard model in the formalism of the temperature Green function is investigated. The applicability of the weak coupling approach at the values of the dimensionless coupling constant U/t≈10–11 is justified. The normal state, the antiferromagnetic state with Neel magnetic ordering on the “copper” sublattice, and the superconducting state with nontrivial Cooper pairing in channels with odd angular momenta are studied. The possibility of other magnetic states in the model is discussed. Bibliography: 20 titles. Translated fromZapiski Nauchnykh Seminarov POMI, Vol. 209, 1994, pp. 194–228. Translated by K. Malyshev.     

The signature theorem and some related questions

Some corollaries of the Hirzebruch-Thom signature theorem are discussed. The multiplicativity of the signature and the naturalness of the Pontryagin classes for coverings in the case of ℚ-homology manifolds is proved. A geometric proof of Hirzebruch’s well-known “functional equation” for the virtual signature is outlined. Bibliography: 25 titles. Translated fromZapiski Nauchnykh Seminarov POMI, Vol. 231, 1995, pp. 197–209. Translated by N. Yu. Netsvetaev.     

Synthesis of heterocyclic systems with a carbohydrate fragment

Levoglucosenone reacts with α-aminoazoles to yield azolo[1,5-a]pyrimidine systems fused with a carbohydrate fragment. The reaction oocurs much more smoothly than in the case of other α,β-unsaturated ketones. The reactions of levoglucosenone with β-dicarbonyl compounds (dimedone, barbituric acid) in the presence of a base results in the pyran ring closure, which has never been observed earlier in reactions of β-dicarbonyl compounds with α,β-unsaturated ketones under the conditions of basic catalysis. The structures of products were established by IR and NMR spectroscopy. For Part 3, see Ref. 1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 553–558, March, 1997.     

Synthesis, structure, and antimetastatic activity of thetrans-[Pt(NC5H4C(O)NHC2H4ONO2)2Cl2] complex

Thetrans-[Pt(NC₅H₄C(O)NHC₂H₄ONO₂)₂Cl₂] complex (2) was prepared by the reaction of nicorandyl (N-nitroethoxynicotinamide), which is widely used in cardiology, with K₂PtCl₄ in water. The structure of2 was established by X-ray structural analysis. It was found that complex2 exhibits high antitumor activity, in particular, antimetastatic activity, unlike the analogous Cu^II complex with bromine atoms. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1672–1675, September, 1997.