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排序方式: 共有323条查询结果,搜索用时 15 毫秒
81.
Tonka Vasileva Ilia Iliev Myriam Amari Veselin Bivolarski Marie-Sophie Bounaix Hervé Robert Sandrine Morel Philippe Rabier Iskra Ivanova Bruno Gabriel Catherine Fontagné-Faucher Valérie Gabriel 《Applied biochemistry and biotechnology》2012,168(3):718-730
Glycosyltransferase activity of 13 Leuconostoc mesenteroides strains isolated from Bulgarian fermented vegetables was investigated. All the strains displayed a mucoid phenotype on sucrose-containing agar media. Strains were characterized according to carbohydrate fermentation, species-specific multiple PCR using several primers, repetitive element-PCR fingerprinting using (GTG)5 primers and glycosyltransferase activity. Level of activity and cellular localization (soluble or cell-associated) were variable among strains. Precipitation of exopolysaccharides produced from sucrose by the soluble fractions from these strains allowed recovery of only glucans and further characterization by 1H and 13C NMR analysis and enzymatic digestion with dextranase revealed dextran production. However, levans could be detected in presence of raffinose as fructosyl donor. Both fructosyltransferase and glucosyltransferase encoding genes were detected by PCR and both active enzymes were detected after functional characterization by SDS-PAGE electrophoresis and in situ polymer production after incubation with sucrose. This work therefore showed that concomitant production of glucosyltransferase and fructosyltransferase is widespread in L. mesenteroides strains. 相似文献
82.
Rameshwar U. Kadam Myriam Bergmann Matthew Hurley Divita Garg Martina Cacciarini Magdalena A. Swiderska Cristina Nativi Michael Sattler Alan R. Smyth Paul Williams Miguel Cmara Achim Stocker Tamis Darbre Jean‐Louis Reymond 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2011,123(45):10819-10823
83.
Carlos Guido Bollini Mario Giambiagi Myriam Segre de Giambiagi Aloysio Paiva de Figueiredo 《Journal of mathematical chemistry》2000,28(1-3):71-81
The multicenter bond index proposed within the MO framework depends on the order of the centers for which it is calculated, outside from the 3-c case. For the 6-c case, the eventually different values are 60. A graphical approach links the MO values to VB structures. Benzene, chosen as our paradigm for the 6-c case, illustrates our proposition. 相似文献
84.
Myriam Eveno Adrian Duran Jacques Castaing 《Applied Physics A: Materials Science & Processing》2010,100(3):577-584
It is rare that the analyses of materials in paintings can be carried out by taking micro-samples. Valuable works of art are
best studied in situ by non-invasive techniques. For that purpose, a portable X-ray diffraction and fluorescence apparatus
has been designed and constructed at the C2RMF. This apparatus has been used for paintings of Rembrandt, Leonardo da Vinci,
Van Gogh, Mantegna, etc. Results are given to illustrate the performance of X-ray diffraction, especially when X-ray fluorescence
does not bring sufficient information to conclude. 相似文献
85.
Joachim Mohn Christina Biasi Samuel Bodé Pascal Boeckx Paul J. Brewer Sarah Eggleston Heike Geilmann Myriam Guillevic Jan Kaiser Kristýna Kantnerová Heiko Moossen Joanna Müller Mayuko Nakagawa Ruth Pearce Isabell von Rein David Steger Sakae Toyoda Wolfgang Wanek Sarah K. Wexler Naohiro Yoshida Longfei Yu 《Rapid communications in mass spectrometry : RCM》2022,36(13):e9296
86.
Myriam Díaz-Álvarez Antonio Martín-Esteban Esther Turiel 《Journal of separation science》2022,45(13):2356-2365
In this work, the preparation and evaluation of water-compatible molecularly imprinted polymers for triazines using 2-hydroxyethyl methacrylate and methacrylic acid as comonomers is described. Four sets of molecularly imprinted and non-imprinted polymers for propazine were prepared at varying monomer molar ratios (from 4:0 to 1:3), and evaluated for the recognition of several triazines directly in aqueous media. The evaluation was performed by loading 1 mL of an aqueous solution containing 500 ng of each selected triazine, washing with 500 μL of acetonitrile, and eluting with 500 μL of methanol followed by 2 × 500 μL of a solution of methanol containing 10% of acetic acid. Final determinations were performed by high-performance liquid chromatography-ultraviolet detection. Improvement in molecular recognition of triazines in water was obtained on those molecularly imprinted polymers incorporating 2-hydroxyethyl methacrylate in 3:1 or 2:2 molar ratios, being the former selected as optimum providing recoveries for propazine up to 80%. A molecularly imprinted solid-phase extraction protocol was developed to ensure that triazines-selective recognition takes place inside selective binding sites in pure water media. Finally, the developed method was successfully applied to the determination of the selected triazines in environmental waters providing limits of detection from 0.16 and the 0.5 μg/L concentration range. 相似文献
87.
Minerva Gamboa Myriam Campos Luis Alfonso Torres 《The Journal of chemical thermodynamics》2010,42(5):666-674
In this work, the stability of 5,10,15,20-tetraphenylporphine (TPP) and its metallic derivatives, NiTPP, CoTPP, CuTPP, and ZnTPP has been studied through differential scanning calorimetry and thermogravimetry. The decomposition temperatures are (712, 710, 708, 702, and 671) K for NiTPP, CoTPP, CuTPP, ZnTPP, and TPP, respectively. These values are in correspondence with the N–M bond length dM–N, of the metalloporphyrins. The corresponding molar enthalpies of melting ΔfusHm, were determined as (58, 57, 55, 52, and 44) kJ · mol?1 for the same series. These values are discussed in terms of the crystallographic features in the solid state. 相似文献
88.
We report on the investigation of thermal effects in high-repetition-rate pulsed optical parametric oscillators emitting in the mid-IR. We find that the thermal load induced by the nonresonant idler absorption plays a critical role in the emergence of thermally induced bistability. We then demonstrate a significant improvement of the conversion efficiency (more than 30%) when a proper axial temperature gradient is applied to the nonlinear crystal by use of a two-zone temperature-controlled oven. 相似文献
89.
Different models have been described in the literature to evaluate the total porosity of CEC columns: gravimetric, flow as well as conductivity-based methods. In this study, these models have been compared for two kinds of CEC columns: two mixed-mode silica particle stationary phases and different monolithic columns (acrylate or polystyrene divinylbenzene-based). The total porosities measured from the conductivity-based methods were lower than the total column porosities obtained by gravimetric or flow methods for all the investigated columns while the wide distribution of observed values shows that conductivity-based methods discriminate columns more efficiently with very different properties. We propose a conductivity-based method taking into account the actual length proposed by Horvath, to evaluate what we call an "actual electrokinetic" porosity (AEP). This parameter, based on electrokinetic theory only, affords the most consistent evaluation of porosity under experimental CEC conditions for the packed- and acrylate-based monolithic columns. To illustrate the potential of AEP and actual EOF for the estimation of the performances of a CEC system (stationary and mobile phases) we studied the influence of the mobile-phase composition on these parameters for CEC separations with an ammonium embedded packed stationary phase. The AEP and the actual electroosmotic mobility should allow a better understanding of the perfusive EOF and stationary-phase wettability. For neutral compounds (substituted phenols), AEP evaluation allowed us to predict the mobile-phase conditions able to enhance the efficiency while both AEP and actual EOF had to be considered in the case of peptide analysis. 相似文献
90.