全文获取类型
收费全文 | 123篇 |
免费 | 3篇 |
专业分类
化学 | 90篇 |
力学 | 7篇 |
数学 | 5篇 |
物理学 | 24篇 |
出版年
2022年 | 3篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 7篇 |
2015年 | 6篇 |
2014年 | 3篇 |
2013年 | 6篇 |
2012年 | 10篇 |
2011年 | 8篇 |
2010年 | 10篇 |
2009年 | 3篇 |
2008年 | 8篇 |
2007年 | 11篇 |
2006年 | 5篇 |
2005年 | 6篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 2篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1978年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有126条查询结果,搜索用时 15 毫秒
21.
P. Balasubramaniam P. Muthukumar 《Journal of Optimization Theory and Applications》2009,143(2):225-244
In this paper, sufficient conditions for the approximate controllability of the following stochastic semilinear abstract functional differential equations with infinite delay are established $$\begin{array}{@{}l@{}}d\bigl[x^{\prime}(t)-g(t,x_{t})\bigr]=\bigl[Ax(t)+f(t,x_{t})+Bu(t)\bigr]dt+G(t,x_{t})dW(t),\\\noalign{\vskip3pt}\quad \mbox{a.e on}\ t\in J:=[0,b],\\\noalign{\vskip3pt}x_{0}=\varphi\in {\mathfrak{B}},\\\noalign{\vskip3pt}x^{\prime}(0)=\psi \in H,\end{array}$$ where the state x(t)∈H,x t belongs to phase space ${\mathfrak{B}}$ and the control u(t)∈L 2 ? (J,U), in which H,U are separable Hilbert spaces and d is the stochastic differentiation. The results are worked out based on the comparison of the associated linear systems. An application to the stochastic nonlinear wave equation with infinite delay is given. 相似文献
22.
Water-soluble inhibitor on microbiologically influenced corrosion in diesel pipeline 总被引:1,自引:0,他引:1
Muthukumar N Maruthamuthu S Palaniswamy N 《Colloids and surfaces. B, Biointerfaces》2006,53(2):260-270
The effect of water-soluble corrosion inhibitor on the growth of bacteria and its corrosion inhibition efficiency were investigated. Corrosion inhibition efficiency was studied by rotating cage test and flow loop techniques. The nature of biodegradation of corrosion inhibitor was also analyzed by using Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR) and Gas chromatography and mass spectrometer (GC–MS). The bacterial isolates (Serratia marcescens ACE2, Bacillus cereus ACE4) have the capacity to degrade the aromatic and aliphatic hydrocarbon present in the corrosion inhibitor. The degraded products of corrosion inhibitor and bacterial activity determine the electrochemical behaviour of API 5LX steel. The influence of bacterial activity on degradation of corrosion inhibitor and its influence on corrosion of API 5LX have been evaluated by employing weight loss techniques and electrochemical studies. The main finding of this paper is that the water-soluble corrosion inhibitor is consumed by the microbial action, which contributes to the decrease in inhibitor efficiency. The present study also emphasis the importance of evaluation of water-soluble corrosion inhibitor in stagnant model (flow loop test) and discusses the demerits of the water-soluble corrosion inhibitors in petroleum product pipeline. 相似文献
23.
In this paper, the stability conditions and chaotic behaviors of new different fractional orders of reverse butterfly-shaped dynamical system are analytically and numerically investigated. Designing an appropriate feedback controller, the fractional order chaotic system is synchronized. Applying the synchronized fractional order systems in digital cryptography, a well secured key system is obtained. The numerical simulations are given to validate the correctness of the proposed synchronized fractional order chaotic systems and proposed key system. 相似文献
24.
Ng CC Magenau A Ngalim SH Ciampi S Chockalingham M Harper JB Gaus K Gooding JJ 《Angewandte Chemie (International ed. in English)》2012,51(31):7706-7710
Smart surfaces presenting both antifouling molecules with a charged functional group at their distal end, and molecules that are terminated by RGD peptides for cell adhesion, were fabricated and characterized (see picture). By applying potentials of +300 or -300?mV, the surfaces could be dynamically switched to make the peptide accessible or inaccessible to cells. 相似文献
25.
Winaki P. Sohtun Themmila Khamrang Arunachalam Kannan Gowdhami Balakrishnan Dhandayutham Saravanan Mohammad Abdulkader Akhbarsha Marappan Velusamy Mallayan Palaniandavar 《应用有机金属化学》2020,34(5):e5593
A series of iron(III) bis-complexes of the type [FeL2]X 1-4 , X = OH− ( 1 ), Cl¯ ( 3 ), and FeCl4¯ ( 2 , 4 ), where LH is a tridentate (N,N,S) ligands such as N′-(1-pyridin-2-ylethylidene)-hydrazinecarbodithioic acid methyl ester ( HL1 ), N′-(phenylpyridin-2-ylmethylene)-hydrazinecarbodithioic acid methyl ester ( HL2 ), N′-quinolin-2-ylmethylene-hydrazinecarbodithioic acid methyl ester ( HL3 ), or N′-(1-methyl-1H-imidazol-2-yl-methylene)hydrazinecarbodithioic acid methyl ester ( HL4 ) has been isolated in moderate to good yields and completely characterized by elemental analyses, conductivity studies, and infrared and UV-visible spectral measurements. The single crystal X-ray structures of 1 , 2 and 4 revealed that two deprotonated tridentate (NNS) ligands are meridionally coordinated to constitute a distorted octahedral coordination geometry around iron(III). In acetonitrile solution, all the complexes show quasi-reversible Fe(III)/Fe(II) redox behavior. The in vitro cytotoxicity of the ligands HL1–HL4 (IC50: HL1 , 64.5; HL2 , 51.0; HL3 , 124.0; HL4 , 45.0 μM at 24 h) and complexes 1–4 (IC50: 1 , 84.5; 2 , 40.0; 3 , 168.5; 4 , 50.5 μM at 24 h) towards A549 lung cancer cell lines are similar to cisplatin (69.0 μM), revealing that free ligands cause cancer cell death with potency higher than the corresponding iron(III) complexes. Also, both the ligands and the complexes cause cell death mainly through apoptotic mode, as revealed by the observation of a higher percentage of apoptotic cells in acridine orange (AO)/ ethidium bromide (EB), and Annexin V-Cy3 stained cancer cells. 相似文献
26.
Mallayan Palaniandavar Marappan Velusamy Ramasamy Mayilmurugan 《Journal of Chemical Sciences》2006,118(6):601-610
Catechol 1,2-dioxygenase (CTD) and protocatechuate 3,4-dioxygenase (PCD) are bacterial non-heme iron enzymes, which catalyse
the oxidative cleavage of catechols tocis, cis-muconic acids with the incorporation of molecular oxygen via a mechanism involving a high-spin ferric centre. The iron(III)
complexes of tripodal phenolate ligands containing N3O and N2O2 donor sets represent the metal binding region of the iron proteins. In our laboratory iron(III) complexes of mono- and bisphenolate
ligands have been studied successfully as structural and functional models for the intradiol-cleaving catechol dioxygenase
enzymes. The single crystal X-ray crystal structures of four of the complexes have been determined. One of thebis-phenolato complexes contains a FeN2O2Cl chromophore with a novel trigonal bipyramidal coordination geometry. The Fe-O-C bond angle of 136.1‡ observed for one of
the iron(III) complex of a monophenolate ligand is very similar to that in the enzymes. The importance of the nearby sterically
demanding coordinated -NMe2 group has been established and implies similar stereochemical constraints from the other ligated amino acid moieties in the
3,4-PCD enzymes, the enzyme activity of which is traced to the difference in the equatorial and axial Fe-O(tyrosinate) bonds
(Fe-O-C, 133, 148‡). The nature of heterocyclic rings of the ligands and the methyl substituents on them regulate the electronic
spectral features, FeIII/FeII redox potentials and catechol cleavage activity of the complexes. Upon interacting with catecholate anions, two catecholate
to iron(III) charge transfer bands appear and the low energy band is similar to that of catechol dioxygenase-substrate complex.
Four of the complexes catalyze the oxidative cleavage of H2DBC by molecular oxygen to yield intradiol cleavage products. Remarkably, the more basic N-methylimidazole ring in one of
the complexes facilitates the rate-determining productreleasing phase of the catalytic reaction. The present study provides
support to the novel substrate activation mechanism proposed for the intradiol-cleavage enzymes. 相似文献
27.
28.
29.
Marappan Dharani Basudeb Sahu Chakrakodi S. Shastry 《Central European Journal of Physics》2014,12(10):755-766
We present a systematic study of the conditions for the generation of threshold energy eigen states and also the energy spectrum generated by two types of locally periodic delta potentials each having the same strength λV and separation distance parameter a: (a) sum of N attractive potentials and (b) sum of pairs of attractive and repulsive potentials. Using the dimensionless parameter g = λV a in case (a) the values of g = g n , n = 1, 2, …, N at which threshold energy bound state gets generated are shown to be the roots of Nth order polynomial D 1(N, g) in g. We present an algebraic recursive procedure to evaluate the polynomial D 1(N, g) for any given N. This method obviates the need for the tedious mathematical analysis described in our earlier work to generate D 1(N, g). A similar study is presented for case (b). Using the properties of D 1(N, g) we establish that in case (a) the critical minimum value of g which guarantees the generation of the maximum possible number of bound states is g = 4. The corresponding result for case (b) is g = 2. A typical set of numerical results showing the pattern of variation of g n as a function of n and several interesting features of the energy spectrum for different values of g and N are also described. 相似文献
30.
A new Schiff base (E)-4-((4-bromobenzylidene) amino) benzenesulfonamide (M2) was synthesized by the reaction between 4-bromobenzaldehyde and sulfanilamide followed by characterization using IR, Raman, UV–Visible, 1HNMR, and 13CNMR spectral techniques. This was followed by electronic structure studies using DFT and TD-DFT. We simulated the IR spectrum using B3LYP/6-31+G(d,p) level of theory, followed by a comparison with experimental spectra and detailed potential energy distribution and vibrational assignment analysis. The comparison of experimental UV and simulated UV spectrum using TD-DFT B3LYP/6-31+G(d,p) in DMSO solvent atmosphere gave good agreement. As Schiff bases are biologically active, we checked for the potential activity of the synthesized compound with the help of ADMET prediction and found it to be active. Wavefunctions related properties like ELF, LOL, and ELF are also reported. Prediction of biological activity spectrum study indicated possible antibacterial activity against bacteria, which is supported by molecular docking against Staphylococcus aureus (3U2D) protein with a docking score of ?7.1 kcal/mol. Experimental antibacterial study using the compound and standard drugs confirmed this prediction. 相似文献