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51.
Farida Benmouna Zohra Bouabdellah-Dembahri Mustapha Benmouna 《Journal of Macromolecular Science: Physics》2013,52(7):998-1008
The process of polymer synthesis based on polymerization-induced phase separation (PIPS) is revisited from the theoretical point of view. Cahn–Hilliard–Cook theories for spinodal decomposition are adapted to describe the kinetics of phase separation and deduce the time-resolved scattering function, while the double reaction model is used to describe the kinetics of polymerization. Coupling of these two kinetics is provided by the Carother's equation relating the fraction of reacted monomers to the degree of polymerization at time t, denoted N(t). It is argued that the approach to criticality is governed by a critical parameter, χc, that is different from the usual parameter for spinodal decomposition, χs, deduced from the second derivative of the free energy. While the latter parameter depends on the reciprocal degree of polymerization N?1(t), the former one depends on its time integral. This leads to significant consequences on the phase behavior developments during the PIPS process. Hydrodynamic interactions are found to speed up the emergence of instability modes. Although the qualitative trends remain similar to those of the Rouse dynamics, important quantitative changes are found due to the long-range viscous flow effects. 相似文献
52.
Mustapha El Jarroudi 《Applicable analysis》2013,92(5):693-715
We consider an elastic material in contact with a three-dimensional rigid plate of varying thickness. We suppose that a perfect adhesion occurs along thin zones disposed in a self-similar way on the interface between the two materials. We suppose that the elasticity coefficients in the plate depend on its thickness and tend to infinity as this thickness tends to zero. We derive the effective material properties using Γ-convergence methods. 相似文献
53.
Mustapha Dehmani Hamid Ez-Zahraouy Abdelilah Benyoussef 《Journal of Russian Laser Research》2013,34(1):71-76
We investigate the effect of an anisotropic depolarizing channel on the classical transmission of quantum entangled states. We calculate numerically mutual information between honest parts as a function of the degree of anisotropy of the depolarizing channel. In contrast to the case of isotropic channels, we found that the mutual information depends on both the degree of anisotropy and the degree of entanglement. It increases with increase in the degree of entanglement for a quantum channel with sufficiently large depolarizing anisotropy and decreases with increase in the entanglement. 相似文献
54.
Zerrouki Abdelkhalek Abrigach Farid Taleb Mustapha El Kadiri Sghir 《Research on Chemical Intermediates》2020,46(2):1453-1467
Research on Chemical Intermediates - A class of novel multi-tripodal ligands has been prepared via condensation reaction between pyrazole or triazole moieties and... 相似文献
55.
Alibe Ibrahim Mustapha Matori Khamirul Amin Sidek Hj Ab Aziz Yaakob Yazid Rashid Umer Alibe Ali Mustapha Zaid Mohd Hafiz Mohd Nasir Salisu Nasir Maharaz Mohammed 《Journal of Thermal Analysis and Calorimetry》2019,136(6):2249-2268
Journal of Thermal Analysis and Calorimetry - Willemite is an inorganic semiconductor material used for optoelectronic applications. The present study purposes a new polymer thermal treatment... 相似文献
56.
Ayoub Abdelkader Mekkaoui Abderrazak Aberkouks Lahcen Fkhar Mustapha Ait Ali Larbi El Firdoussi Soufiane El Houssame 《应用有机金属化学》2020,34(11):e5917
Various ratios of palladium nanoparticles supported on mesoporous natural phosphate (Pd@NP) were prepared using the wetness impregnation method. The prepared catalysts were characterized by IR, XRD, CV, SEM, EDX, XRF, TEM and BET analysis. The reduction and preparation of the palladium nanoparticles afford a crystallite size of 10.88 nm. The performance of the synthesized catalyst was investigated in the solvent-free dehydroaromatization of α-, β- and γ-himachalene mixture from Cedrus atlantica oil as a model substrate. In order to achieve an efficient and selective catalysis, the catalytic dehydroaromatization of various terpenes such as limonene, limonaketone, carvone, carveol and perillyl alcohol was studied. The Pd@NP catalyst performed a high catalytic activity, selectivity and recyclability in the terpenes dehydroaromatization reaction. 相似文献
57.
The mechanisms for the reactions of AlF with HCl have been characterized in detail using DFT as well as the ab initio method, including zero-point corrections. From the potential energy profile it can be predicted that the reaction process of forming the new Al(III) hydride HAlFCl compound for this reaction is spontaneous with a low activation energy barrier. The reaction yielding to AlFCl2 and molecular hydrogen was calculated to be highly exothermic. The present calculations also show that the possible routes to the trihalides species start more favorable with the primary insertion products. 相似文献
58.
Bourhim M Rajendran A Ramos Y Srikrishnan T Sulkowski E 《Journal of chromatographic science》2008,46(6):574-576
An investigation of the binding of native and recombinant human serum albumin and bovine serum albumin on three thiophilic gels, PyS, 2S, and 3S was performed. In addition to these proteins, we studied serum albumins from several species such as goat, rabbit, guinea pig, rat, hamster, baboon, and pig. Our results reveal that recombinant human serum albumin (rHSA) binds completely to PyS whereas native human serum albumin and bovine serum albumin bind only partially to PyS. The binding affinities of rHSA, human serum albumin and bovine serum albumin to 2S and 3S gels are less than their binding to PyS. Serum albumins from goat, rabbit, guinea pig, rat, hamster, baboon, and pig bind much stronger to 3S gel than human and bovine serum albumins. The binding of pig and hamster serum albumins is stronger than that of rat, goat, baboon, and rabbit. 相似文献
59.
Fikri M Makeich A Rollmann G Schulz C Entel P 《The journal of physical chemistry. A》2008,112(28):6330-6337
The thermal decomposition of Ga(CH3)3 has been studied both experimentally in shock-heated gases and theoretically within an ab-initio framework. Experiments for pressures ranging from 0.3 to 4 bar were performed in a shock tube equipped with atomic resonance absorption spectroscopy (ARAS) for Ga atoms at 403.3 nm. Time-resolved measurements of Ga atom concentrations were conducted behind incident waves as well as behind reflected shock waves at temperatures between 1210 and 1630 K. The temporal variation in Ga-atom concentration was described by a reaction mechanism involving the successive abstraction of methyl radicals from Ga(CH3)3 (R1), Ga(CH3)2 (R2), and GaCH3 (R3), respectively, where the last reaction is the rate-limiting step leading to Ga-atom formation. The rate constant of this reaction (R3) was deduced from a simulation of the measured Ga-atom concentration profiles using thermochemical data from ab-initio calculations for the reactions R1 and R2 as input. The Rice-Ramsperger-Kassel-Marcus (RRKM) method including variational transition state theory was applied for reaction R3 assuming a loose transition state. Structural parameters and vibrational frequencies of the reactant and transition state required for the RRKM calculations were obtained from first-principles simulations. The energy barrier E3(0) of reaction R3, which is the most sensitive parameter in the calculation, was adjusted until the RRKM rate constant matched the experimental one and was found to be E(0) = 288 kJ/mol. This value is in a good agreement with the corresponding ab-initio value of 266 kJ/mol. The rate constant of reaction R3 was found to be k 3/(cm(3) mol(-1)s(-1)) = 2.34 x 10(11) exp[-23330(K/ T)]. 相似文献
60.
Kassem Mustapha Maher Nour Bernardo Cockburn 《Advances in Computational Mathematics》2016,42(2):377-393
We study the hybridizable discontinuous Galerkin (HDG) method for the spatial discretization of time fractional diffusion models with Caputo derivative of order 0 < α < 1. For each time t ∈ [0, T], when the HDG approximations are taken to be piecewise polynomials of degree k ≥ 0 on the spatial domain Ω, the approximations to the exact solution u in the L ∞(0, T; L 2(Ω))-norm and to ?u in the \(L_{\infty }(0, \textit {T}; \mathbf {L}_{2}({\Omega }))\)-norm are proven to converge with the rate h k+1 provided that u is sufficiently regular, where h is the maximum diameter of the elements of the mesh. Moreover, for k ≥ 1, we obtain a superconvergence result which allows us to compute, in an elementwise manner, a new approximation for u converging with a rate h k+2 (ignoring the logarithmic factor), for quasi-uniform spatial meshes. Numerical experiments validating the theoretical results are displayed. 相似文献