Synthesis and binding properties of calix[4]arene telomers

Two calix[4]arene derivatives (5 and 8) and their telomers are synthesized to estimate selective extraction of alkali and transition metal cations from the aqueous to the organic phase (chloroform). Compound 5 shows selectivity toward Hg²⁺. Compound 8 and telomers 6 and 9 are not selective but are good extractants for all used transition metal ions. The observations suggest that ethylene glycol bridges are efficient for carrying transition metal cations in a two-phase solvent system. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 4351–4355, 1999     

Double-Layer Micro Porous Media Burner from Lean to Rich Fuel Mixture: Analysis of Entropy Generation and Exergy Efficiency

Porous media burner (PMB) is widely used in a variety of practical systems, including heat exchangers, gas propulsion, reactors, and radiant burner combustion. However, thorough evaluations of the performance of the PMB based on the usefulness of entropy generation, thermal and exergy efficiency aspects are still lacking. In this work, the concept of a double-layer micro PMB with a 23 mm cylindrical shape burner was experimentally demonstrated. The PMB was constructed based on the utilization of premixed butane-air combustion which consists of an alumina and porcelain foam. The tests were designed to cover lean to rich combustion with equivalence ratios ranging from ϕ = 0.6 to ϕ = 1.2. It was found that the maximum thermal and exergy efficiency was obtained at ϕ = 1.2 while the lowest thermal and exergy efficiency was found at ϕ = 0.8. Furthermore, the findings also indicated that the total entropy generation, energy loss, and exergy destroyed yield the lowest values at ϕ = 1.0 with 0.0048 W/K, 98.084 W, and 1.456 W, respectively. These values can be stated to be the suitable operating conditions of the PMB. The findings provided useful information on the design and operation in a double-layer PMB.     

Nonrelativistic Shifted-1 Expansion Technique for Three- and Two-Dimensional Schrodinger Equation

The shifted-1 expansion techniques (SLET) has been developed to get eigenvalues of Schrödinger equation in three (30) and two dimensions (2D). SLET simply consists of 1/l as a perturbation parameter, where l= 1 -β.β is a suitable shift, l is the angular-momentum quantum number for the 3D-case, l = |m| for the 2D-case, and m is the magnetic quantum number. Unlike the shifted large-N expansion theory (SLNT), SLET seems to be applicable to a wider number of problems of significant interest in physics.     

2,4,5‐Substituted furan‐3(2H)‐ones: Synthesis,reactions with amino acid and hydrazine derivatives

Furan‐3(2H)‐ones ( 3 ) were obtained from some 2,3‐dihydro‐furan‐2,3‐diones with a few Wittig reagents ( 2 ). The compounds of 3 with glycin and hydrazines ( 4a,b ) produced 2,3‐dihydro‐1H‐pyrrol‐3‐ones ( 5a–d ). All the reaction mechanisms were discussed by utilizing the similar reaction pathways. Structures of these compounds were determined by the IR, NMR, elemental analysis, and X‐ray diffraction method. © 2005 Wiley Periodicals, Inc. Heteroatom Chem 16:235–241, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20115     

Modeling and Sensitivity Analysis of Particle Size Distribution and Chain Length Distribution in a Semibatch Emulsion Copolymerization Reactor

Summary: A comprehensive model is developed to predict the relationship between the particle size distribution and molecular weights of particles in an emulsion copolymerization reactor. A full population balance equation is used for the particle size distribution and extended to the model for the molecular properties using a continuous reactor approach. The numerical prediction clearly distinguishes the characteristics of molecular properties of particles by homogeneous nucleation from those by micellar nucleation with the dependence on the particle size. Sensitivity analysis of the proposed model under a variety of conditions shows that the compartmentalized feature of the emulsion system should be considered for better prediction of molecular properties, and provides information on the manipulated variables and lumped parameters which effectively decompose the correlation of both properties. Finally, a control strategy utilizing a lumped parameters tracking method is suggested for the regulation of both the particle size distribution and molecular properties.

Time evolution of number‐averaged molecular weights in the element under base conditions.     

Heat removal from oscillating flow in a vertical annular channel

In this study, heat removal from a surface, which is located into the reciprocating flow in a vertical annular liquid column, is investigated experimentally. The experiments are carried out for four different oscillation frequencies and three heat fluxes while the amplitude remains constant for all cases. Instantaneous and time-averaged surface and bulk temperature variations are presented. The cycle-averaged values are considered in the calculation of heat transfer using the experimental measurements. Heat removal from the cold surface due to the oscillating liquid column is determined in terms of Nusselt number. Based on the experimental data, an empirical equation is obtained for the cycle averaged Nusselt number as a function of kinetic Reynolds number.     

MHD natural convection in porous media-filled enclosures

In this work, the magnetohydrodynamics （MHD） natural convection heat transfer problem inside a porous medium filled with inclined rectangular enclosures is investigated numerically. The boundary conditions selected on the enclosure are two adiabatic and two isothermal walls. The governing equations, continuity, and Forchheimer extension of the Darcy law and energy are transformed into dimensionless forms by using a set of suitable variables, and then solved by using a finite difference scheme. The governing parameters are the magnetic influence number, the Darcy Rayleigh number, the inclination angle, and the aspect ratio of the enclosure. It is found that the magnetic influence number and the inclination angle have pronounced effects on the fluid flow and heat transfer in porous media-filled enclosures.     

Modification of Crosslinked Poly(styrene) Based Polymers for Boron-Specific Extraction

A new polymeric resin with glucose sulfonamide functions has been prepared for the extraction of boric acid. This poly (styryl sulfonamide) based resin has been demonstrated to be an efficient sorbent for the removal of boron. The resin had a boron loading capacity of 2.365 mmol.g⁻¹ and showed reasonably rapid sorption ability. Splitting of sorbed boron can be achieved by simple acid leaching (2M H₂SO₄).