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11.
Study of magnetoresistance and conductance of bicrystal grain boundary in La0.67Ba0.33MnO3 thin film
La0.67Ba0.33MnO3 (LBMO) thin film is deposited on a 36.7°C SrTiO3 bicrystal substrate using laser ablation technique. A microbridge is created across bicrystal grain boundary and its characteristics
are compared with a microbridge on the LBMO film having no grain boundary. Presence of grain boundary exhibits substantial
magnetoresistance ratio (MRR) in the low field and low temperature region. Bicrystal grain boundary contribution in MRR disappears
at temperature T>175 K. At low temperature, I-V characteristic of the microbridge across bicrystal grain boundary is nonlinear. Analysis of temperature dependence of dynamic
conductance-voltage characteristics of the bicrystal grain boundary indicates that at low temperatures (T<175 K) carrier transport across the grain boundary in LBMO film is dominated by inelastic tunneling via pairs of manganese
atoms and tunneling through disordered oxides. At higher temperatures (T>175 K), magnetic scattering process is dominating. Decrease of bicrystal grain boundary contribution in magnetoresistance
with the increase in temperature is due to enhanced spin-flip scattering process. 相似文献
12.
N. A. Burmistrova S. P. Mushtakova P. G. Nikonorov 《Journal of Analytical Chemistry》2005,60(2):125-129
The use of diphenyl reagents bearing electron-withdrawing substituents in catalymetric analysis was studied using sulfophenylanthranilic acid as an example. A selective catalytic effect of palladium(II) on the oxidation of sulfophenylanthranilic acid by cerium(IV) sulfate in a weakly acid solution was found. The reaction rate was studied as a function of component concentrations, solution acidity, and temperature. A procedure for determining palladium(II) was developed and tested using model mixtures and a KP-5 sample of complex composition.Translated from Zhurnal Analiticheskoi Khimii, Vol. 60, No. 2, 2005, pp. 144–148. Original Russian Text Copyright © 2005 by Burmistrova, Mushtakova, Nikonorov. 相似文献
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P. G. Nikonorov N. A. Burmistrova S. P. Mushtakova 《Journal of Analytical Chemistry》2008,63(4):395-399
The catalytic activity of Ir(IV), Rh(III), and Ru(IV) was studied in the reaction of the oxidation of triphenylamine-4-sulfonic acid by sodium periodate in a weakly acidic medium. The main analytical characteristics of triphenylamine-4-sulfonic acid were found out. The optimum conditions of the indicator reaction (concentrations of components, acidity, and temperature dependence) were selected. Procedures for determining Ir(IV), Rh(III), and Ru(IV) were proposed and tested with model mixtures. 相似文献
14.
Molar extinction coefficients of some carbohydrates viz. l-arabinose (C5H10O5), d-glucose (C6H12O6), d-mannose (C6H12O6), d-galactose (C6H12O6), d(-) fructose (C6H12O6) and maltose (C12H24O12) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by gamma ray transmission method in a
narrow beam good geometry set-up. These coefficients have been found to depend upon the photon energy following a 4-parameter
polynomial. These extinction coefficients for different sugars having the same molecular formula have same values varying
within experimental uncertainty. Within concentration ranges studied, Beer-Lambert law is obeyed very well. 相似文献
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We consider methods for the mathematical preprocessing of signals in the spectrometric analysis of multicomponent mixtures using chemometric algorithms aimed at adjusting the baseline, experimental noise, and random shift of spectral bands. Practical examples of using simple mathematical operations (scaling, centering, derivatization) are given. The effectiveness of algorithms is illustrated by a wide range of spectroscopic signals (electronic absorption, IR, and NMR spectra) combined with chemometric methods of principal component analysis and independent component analysis. 相似文献
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de Alwis SP 《Physical review D: Particles and fields》1992,46(12):5429-5438
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A. N. Pankratov S. P. Mushtakova L. A. Gribov 《Theoretical and Experimental Chemistry》1985,21(1):79-83
Using the CNDO/2 method, we have calculated the valence electron density distribution in molecules of diphenylamine and its 13 derivatives with the substituents COOH, NO2, OCH3 on the aromatic rings of ionized forms of some diaryl amines, and also 4-amino- and 4-amino-4-adnitro substituted compounds with bridge groups NH, O, S, CH2, CH=CH and analogous diphenyl derivatives. We have shown that independently of the nature of the bridge group, the principle of uncoupling of the aromatic rings is basically retained. Strong long-range effects of the substitutents along the chain of chemical bonds are not apparent. We have calculated the electrostatic molecular potential of the indicated compounds. We have established correlations between the electrostatic molecular potential and the protonization constants, the oxidation-reduction potentials of diarylamines; and also between the electrostatic molecular potential and the reaction rate constant for acylation of primary bridged amines at the amino group.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 21, No. 1, pp. 84–88, January–February, 1985. 相似文献