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131.
132.
Padmanabhan Santhosh Nagarajan Senthil Kumar Murugesan Renukadevi Anantha Iyengar Gopalan Thiyagarajan Vasudevan Kwang-Pill Lee 《Analytical sciences》2007,23(4):475-478
A glassy carbon electrode modified with a coating of polypyrrole (Ppy) exhibited an attractive performance for the detection and determination of a non-steroidal and non-narcotic analgesic compound, ketorolac tromethamine (KT). Cyclic voltammetry, differential pulse and square wave voltammetry were used in a combined way to identify the electrochemical characteristics and to optimize the conditions for detection. For calibrating and estimating KT, square-wave voltammetry was mainly used. The drug shows a well-defined peak at -1.40 V vs. Ag/AgCl in the acetate buffer (pH 5.5). The existence of Ppy on the surface of the electrode gives higher electrochemical active sites at the electrode for the detection of KT and preconcentrate KT by adsorption. The square-wave stripping voltammetric response depends on the excitation signal and the accumulation time. The calibration curve is linear in the range 1 x 10(-11) to 1 x 10(-7) M with a detection limit of 1.0 x 10(-12) M. Applicability to serum samples was also demonstrated. A detection limit of 1.0 ng ml for serum was observed. Square-wave voltammetry shows superior performance over UV spectroscopy and other techniques. 相似文献
133.
Arjunan V Puviarasan N Mohan S Murugesan P 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,67(5):1290-1296
FTIR and FT-Raman spectra of 7-amino-4-trifluoromethylcoumarin (ATMC) have been recorded in the range 4000-400 and 3500-100 cm(-1), respectively, using Bruker IFS 66 V spectrometer. A detailed vibrational analysis has been carried out and assignments of the observed fundamental bands have been proposed on the basis of peak positions, relative intensities, fundamentals, overtones and combination bands. With hope of providing more and effective information on the fundamental vibrations, a normal co-ordinate analysis has been performed by assuming C(S) point group symmetry. The simple valance force field (SVFF) has been employed in normal co-ordinate analysis and to calculate the potential energy distribution (PED) for each fundamental vibration are reported. The PED contribution to each of the observed frequencies shows the reliability and precision of the spectral analysis. 相似文献
134.
Protease-triggered dispersion of nanoparticle assemblies 总被引:1,自引:0,他引:1
Laromaine A Koh L Murugesan M Ulijn RV Stevens MM 《Journal of the American Chemical Society》2007,129(14):4156-4157
135.
Sarma LS Chen CH Kumar SM Wang GR Yen SC Liu DG Sheu HS Yu KL Tang MT Lee JF Bock C Chen KH Hwang BJ 《Langmuir : the ACS journal of surfaces and colloids》2007,23(10):5802-5809
The chemical state and formation mechanism of Pt-Ru nanoparticles (NPs) synthesized by using ethylene glycol (EG) as a reducing agent and their stability have been examined by in situ X-ray absorption spectroscopy (XAS) at the Pt LIII and Ru K edges. It appears that the reduction of Pt(IV) and Ru(III) precursor salts by EG is not a straightforward reaction but involves different intermediate steps. The pH control of the reaction mixture containing Pt(IV) and Ru(III) precursor salts in EG to 11 led to the reduction of Pt(IV) to Pt(II) corresponding to [PtCl4](2-) whereas Ru(III)Cl3 is changed to the [Ru(OH)6](3-) species. Refluxing the mixture containing [PtCl4](2-) and [Ru(OH)6](3-) species at 160 degrees C for 0.5 h produces Pt-Ru NPs as indicated by the presence of Pt and Ru in the first coordination shell of the respective metals. No change in XAS structural parameters is found when the reaction time is further increased, indicating that the Pt-Ru NPs formed are extremely stable and less prone to aggregation. XAS structural parameters suggest a Pt-rich core and a Ru-rich shell structure for the final Pt-Ru NPs. Due to the inherent advantages of the EG reduction method, the atomic distribution and alloying extent of Pt and Ru in the Pt-Ru NPs synthesized by the EG method are higher than those of the Pt-Ru/C NPs synthesized by a modified Watanabe method. 相似文献
136.
D.L. Young C.W. Chen C.M. Fan K. Murugesan C.C. Tsai 《European Journal of Mechanics - B/Fluids》2005,24(6):703-716
Numerical solutions based on the method of fundamental solutions are discussed for Stokes flow inside a rectangular cavity in the presence of circular cylinders. The Stokeslets are used as the fundamental solutions to obtain the solution for the flow field by a linear combination of fundamental solutions. Flow results on the cellular structure of flow field resulting from the dynamics of cylinders and the horizontal walls of the cavity are reported for (i) one rotating cylinder in a rectangular cavity with two parallel horizontal sides moving in the same directions as well as in the opposite directions, (ii) two rotating cylinders kept apart in a rectangular cavity with two parallel horizontal sides moving in the same directions as well as in the opposite directions. The effect of aspect ratio of the rectangular cavity, direction of movement of the two parallel horizontal sides of the cavity and the diameter of the rotating cylinder on the flow structure are studied. The flow results obtained for the single cylinder case are in accordance with the results available in the literature. From the computational point of view, the present numerical procedure based on the method of fundamental solutions is efficient and simple to implement as compared to the mesh-dependent schemes, which needs complex mesh generation procedure for the multiply connected geometrical domains considered in this article. 相似文献
137.
Separation of aromatic solvents from oil refinery reformates by a newly designed ionic liquid using gas chromatography with flame ionization detection 下载免费PDF全文
Indra Bahadur Mbongeni Mabaso Gan Redhi Prashant Singh Sudharsan Kumar Kandasamy Moodley 《Journal of separation science》2015,38(6):951-957
The aim of this study was to determine whether the new ionic liquid, N,N‐dimethyl‐2‐oxopyrrolidonium iodide, synthesized in our laboratory is a suitable solvent for the separation of aromatic components benzene, toluene, ethylbenzene, and xylenes from petroleum mixtures (reformates) in liquid–liquid extraction. In pursuance of the above aim, a method to extract all components of a mixture, containing four aromatic components simultaneously, was developed. A new ionic liquid and a previously used liquid were compared for their extraction abilities. These ionic liquids were, respectively, N,N‐dimethyl‐2‐oxopyrrolidinium iodide and 1‐ethyl‐3‐methyl imidazolium ethyl sulfate. The concentrations of each benzene, toluene, ethylbenzene, and xylenes component in the extract and raffinate phases were measured by gas chromatography with flame ionization detection as volume percent to determine the extraction ability of the ionic liquids. The results obtained for both the reformate samples and model mixtures indicated that the new ionic liquid was effective as an extracting solvent for the recovery of aromatic components from reformates. Also the analysis results, using gas chromatography with flame ionization detection, for the reformate samples were as good as the results obtained by a local oil refinery. The extraction results also show that the developed method is very suitable for the separation and analysis of aromatic components in reformates. 相似文献
138.
Murugesan Sasikumar Milind D. Nikalje Murugan Muthukrishnan 《Tetrahedron: Asymmetry》2009,20(24):2814-2817
Enantiopure (R)-mexiletine was prepared in a simple and practical way using hydrolytic kinetic resolution method of terminal epoxide by Jacobsen’s catalyst. High enantiomeric purity (98% ee) was achieved and the method is well amenable to industrial scale-up. 相似文献
139.
Milind D. Nikalje Murugesan Sasikumar Murugan Muthukrishnan 《Tetrahedron: Asymmetry》2010,21(23):2825-2829
A practical and highly efficient enantioselective synthesis of (R)-phenoxybenzamine hydrochloride has been described for the first time using Jacobsen’s hydrolytic kinetic resolution of a terminal epoxide as a key step and source of chirality. 相似文献
140.
This paper presents a study of the structure and dynamics of rigid fiber-laden deformable curved fluid membranes based on an viscoelastic model that integrates the statics of anisotropic membranes, the planar nematodynamics of fibers and the dynamics of isotropic membranes. Fiber-laden membranes arise frequently in biological systems, such as the plant cell wall and in protein–lipid bilayers. Based on the membrane's force and torque balance equations and the fiber's balance of molecular fields, a viscoelastic anisotropic model that provides the governing equations for the membrane's velocity and curvature and the fiber structure (fiber orientation and order) is found. A Helmholtz free energy that incorporates the tension/bending/and torsion membrane elasticity, the Landau–de Gennes fiber ordering, and fiber order-membrane curvature interactions is used to derive elastic moments, torques, and stresses. The corresponding viscous stresses and moments include the Boussinesq–Scriven contributions as well as bending, torsion, and rotational dissipation. A spectral decomposition leads to the main viscoelastic material functions for anisotropic fluid membranes. Applications of the rheological model to cylindrical growth and cylindrical axial stretching show that competing curvo-phobic, curvo-philic interactions under extensional flow predict transitions between axial and azimuthal fiber arrangements, of interest to cellulose fiber orientation in plant morphogenesis. 相似文献