Lithium garnet based free-standing solid polymer composite membrane for rechargeable lithium battery

Electrolytes with high lithium-ion conductivity, better mechanical strength and large electrochemical window are essential for the realization of high-energy density lithium batteries. Polymer electrolytes are gaining interest due to their inherent flexibility and nonflammability over conventional liquid electrolytes. In this work, lithium garnet composite polymer electrolyte membrane (GCPEM) consisting of large molecular weight (W_avg ~?5?×?10⁶) polyethylene oxide (PEO) complexed with lithium perchlorate (LiClO₄) and lithium garnet oxide Li_6.28Al_0.24La₃Zr₂O₁₂ (Al-LLZO) is prepared by solution-casting method. Significant improvement in Li⁺ conductivity for Al-LLZO containing GCPEM is observed compared with the Al-LLZO free polymer membrane. Maximized room temperature (30 °C) Li⁺ conductivity of 4.40?×?10^?4 S cm^?1 and wide electrochemical window (4.5 V) is observed for PEO₈/LiClO₄?+?20 wt% Al-LLZO (GCPEM-20) membrane. The fabricated cell with LiCoO₂ as cathode, metallic lithium as anode and GCPEM-20 as electrolyte membrane delivers an initial charge/discharge capacity of 146 mAh g^?1/142 mAh g^?1 at 25 °C with 0.06 C-rate.     

Investigations into conformational transitions and solvation structure of a 7-piperidino-5,9-methanobenzo[8] annulene in water

Solvation shell structure of a 7-piperidino-5,9-methanobenzo[8] annulene (PMA) in water has been investigated in ambient conditions using both molecular dynamics (MD) and Car-Parrinello molecular dynamics (CPMD) calculations. From the MD calculations, we find that this molecule exists in three major conformational states out of which two are in twist-boat forms and one in chair form. Due to the limited time scale accessible in CPMD simulations, we have studied all the three conformational states separately using CPMD. The molecular geometry, electronic charge distribution and solvation structure for all three forms are investigated. The stability order of the chair and twist-boat conformations in water solvent has been reversed when compared to the gaseous phase results and in the case of polar aprotic solvents (J. Org. Chem., 1999, 61, 5979). From the radial distribution function, we find that the solvent density around the chair form is significantly lower, which has to be directly related to the smaller solvent accessible area for this conformation and this is in complete agreement with earlier reports. Among the findings are that the solvation shell structure around the nitrogen atom in the chair form of PMA is considerably different from the open conformational forms or the twist-boat forms. The dipole moment for the closed form is found to be significantly larger when compared to the twist-boat forms.     

Simple methods to synthesize 2-pyridones: reactions of 2-aroyl-3,3-bis(alkylsulfanyl)acrylaldehydes and cyanoacetamide

5-Aroyl-6-(methylsulfanyl)-2-oxo-1,2-dihydro-3-pyridinecarbonitriles and 5-aroyl-4-(methylsulfanyl)-2-oxo-1,2-dihydro-3-pyridinecarbonitriles are synthesized effectively by the reaction of 2-aroyl-3,3-bis(alkylsulfanyl)acrylaldehydes and cyanoacetamide under two different conditions.     

CLAY CATALYZED SYNTHESIS OF BIO-DEGRADABLEPOLY(GLYCOLIC ACID)

Glycolic acid was polymerized under vacuum in the presence and absence of nano sized clay.The added clay catalyzed the condensation polymerization which can be confirmed by recording FTIR spectroscopy and intrinsic viscosity (Ⅳ)values.The relative intensity of C=O/CH is increased while increasing the amount of clay.DSC showed the appearance of multiple endotherms of poly(glycolic acid).TGA showed the percentage weight residue remain above 750℃for polymer-nano composite system was 21% and hence proved the...     

The reaction of 2‐aroyl‐3,3‐bis(alkylsulfanyl)acrylaldehydes and hydroxylamine hydrochloride: Facile synthesis of differently substituted isoxazoles

2‐Aroyl‐3,3‐bis(alkylsulfanyl)acrylaldehyde was utilized for the synthesis of three different isoxazoles by reacting with hydroxylaminehydrochloride. We synthesized differently substituted isoxazoles like (aryl)[5‐(methylsulfanyl)‐4‐isoxazolyl]methanones, 3‐(methylsulfanyl)‐5‐phenyl‐4‐isoxazolecarbonitriles and 5‐aryl‐3‐(methylsulfanyl)‐4‐isoxazolecarbaldehyde oximes in good yields by varying the substratereagent stoichiometry and temperature of the reaction medium.     

Stability and Hopf bifurcation of a diffusive predator‐prey model with hyperbolic mortality

The dynamics of a reaction‐diffusion predator‐prey model with hyperbolic mortality and Holling type II response effect is considered. The stability of the positive equilibrium and the existence of Hopf bifurcation are investigated by analyzing the distribution of eigenvalues without diffusion. We also study the spatially homogeneous and nonhomogeneous periodic solutions through all parameters of the system which are spatially homogeneous. To verify our theoretical results, some numerical simulations are also presented. © 2015 Wiley Periodicals, Inc. Complexity 21: 34–43, 2016     

Synthesis of acridinedione derivatives as laser dyes

Synthesis of 9-alkyl, 10-alkyl, 9,10-dialkyl, and 10-aryl-3,4,6,7,9,10-hexahydro-1,8(2H,5H)acridinedione (2a–r) are described as a new class of laser dyes. Reactions of diamines with methylene bis(cyclohexane-1,3-dione) yielded the respective bisacridinediones (3a–e). These dyes lase around 478–494 nm and are compared with the standard dye coumarin-102. © 1996 John Wiley & Sons, Inc.     

Design and optimization of photonic crystal based eight channel dense wavelength division multiplexing demultiplexer using conjugate radiant neural network

In this paper, two dimensional photonic crystal, based eight-channel demultiplexer is proposed and designed for DWDM applications. The performance parameters of the demultiplexer such as transmission efficiency, channel spacing, spectral line width, Q factor, and crosstalk have been evaluated. The proposed demultiplexer comprises of bus waveguide, drop waveguide and parellogram resonant cavity (PRC). The bus waveguide transmits light to the PRC and exits through respective drop waveguide. The PRC consists of a parellogram resonator with a nano ring cavity that is used for dropping eight specific wavelength for ITU-T G 694.1 standard with 50 GHz channel spacing. The circular ring resonator is placed above the PRC wherein a resonant air hole (Cr) is positioned for desired channel selection. The channel selection is done by altering the radius of the air hole. In addition, a conjugate radiant neural network is implemented for optimizing the radii of resonant air holes to select the required channel wavelength. The proposed device is very compact and it could be considered for implementing the photonic integrated circuits.     

SULPHONATED POLY ETHER ETHER KETONE/ POLYVINYL ALCOHOL/PHOSPHOTUNGSTIC ACID COMPOSITE MEMBRANES FOR PEM FUEL CELLS

Composite membranes with polyvinyl alcohol (PVA),sulphonated poly ether ether ketone (SPEEK) and phosphotungstic acid (PWA) were prepared using solvent casting method.The proton conductivities of such membranes were found to be in the order of 10~(-3) S/cm in the fully hydrated condition at room temperature as measured by impedance spectroscopy.The crystalline properties were studied by X-ray diffraction analysis.The thermal properties were determined by TGA and DSC techniques.The tensile strength and pe...     

Numerical simulation of shock tube generated vortex: effect of numerics

Vortices generated at the open end of a planar shock tube are numerically simulated using the AUSM+ scheme. This scheme is known to have low numerical dissipation and therefore is suitable for capturing unsteady vortex motion. However, this low numerical dissipation can also cause oscillations in the vorticity field. Numerical experiments presented here highlight the effect of numerical dissipation on the simulated vortex, as well as the role played by turbulence models. Two turbulence models – the shear-stress-transport (SST) and its modified version for unsteady flows (SST-SAS) – are employed to observe the effect of including turbulence models in such complex flows where the vortex has an embedded shock.