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11.
The complete force field for carbon suboxide has been evaluated. The optimum geometry, stretching and interaction force constants are obtained from a combination of the CNDO/force molecular orbital method and the compliance constant formalism. 相似文献
12.
Solutions of potassium permanganate in concentrated phosphoric acid (above 50%) are found to be unstable. The oxidation state of manganese is reduced from (VII) to (III) and oxygen is evolved during this process. The extent of decomposition of permanganate is found to be dependent on the concentration of the acid. 相似文献
13.
D. Indumathi M. V. N. Murthy V. Ravindran 《Zeitschrift fur Physik C Particles and Fields》1992,56(3):427-436
Following recent interest in the subject of polarisation phenomena, we discuss the cross-sections and polarisation asymmetry in 2-jet production in polarised proton-polarised proton (
) scattering. We set up a complete set of parametrisations for the proton spin-dependent parton densities and use them to demonstrate that this cross-section is dominated by gluonic terms. Hence, a measurement of the asymmetry in such processes will provide information on the gluon spin-dependent density. We further show that a factorisation of the hadronic cross-section a la Combridge and Maxwell's work in unpolarised 2-jet production also applies to the spin-dependent case. Hence, the cross-section can be written in terms of a genericpolarised parton density, which can then be measured in the process. 相似文献
14.
Lawan Ly Xiaoqian Cheng Saravana R. K. Murthy Olivia Z. Jones Taisen Zhuang Steven Gitelis Alan T. Blank Aviram Nissan Mohammad Adileh Matthew Colman Michael Keidar Giacomo Basadonna Jerome Canady 《Molecules (Basel, Switzerland)》2022,27(13)
Soft tissue sarcomas (STS) are a rare and highly heterogeneous group of solid tumors, originating from various types of connective tissue. Complete removal of STS by surgery is challenging due to the anatomical location of the tumor, which results in tumor recurrence. Additionally, current polychemotherapeutic regimens are highly toxic with no rational survival benefit. Cold atmospheric plasma (CAP) is a novel technology that has demonstrated immense cancer therapeutic potential. Canady Cold Helios Plasma (CHCP) is a device that sprays CAP along the surgical margins to eradicate residual cancer cells after tumor resection. This preliminary study was conducted in vitro prior to in vivo testing in a humanitarian compassionate use case study and an FDA-approved phase 1 clinical trial (IDE G190165). In this study, the authors evaluate the efficacy of CHCP across multiple STS cell lines. CHCP treatment reduced the viability of four different STS cell lines (i.e., fibrosarcoma, synovial sarcoma, rhabdomyosarcoma, and liposarcoma) in a dose-dependent manner by inhibiting proliferation, disrupting cell cycle, and inducing apoptosis-like cell death. 相似文献
15.
The basic principle for the production of polarised thermal neutrons is discussed and the choice of various crystal monochromators
surveyed. Brief mention of broad-spectrum polarisers is made. The application of polarised neutrons to the study of magnetisation
density distributions in magnetic crystals, the dynamic concept of polarisation, principle and use of polarisation analysis,
the neutron spin-echo technique are discussed. 相似文献
16.
Abstract Computer simulation studies of the energy distribution of transmitted ions such as alpha-particles, He-, and B-ions through crystalline silicon, using the enhanced binary-collision cascade simulator MARLOWE, will be reviewed. The enhancement includes an additional electronic-energy loss (EEL) model which takes into account explicitly both the target electron density variation via the structure factors and the electron density of the projectile. Investigations of the stopping power for He ions and protons in silicon, at intermediate- and high-energies, based on the adapted EEL model and a velocity-dependent effective charge will be presented. The overall agreement between the calculated and experimentally determined stopping power data and the simulated and measured transmission spectra will be demonstrated. Effects of energy-loss straggling, core-electron contribution to the energy loss at high-energies and charge-state effects at low energies on the transmission spectra will also be discussed. 相似文献
17.
The effect of hydration on the molecular structure of amorphous poly (D, L-lactic acid) (PDLLA) with 50:50 L-to-D ratio has been studied by combining experiments with molecular simulations. X-ray diffraction measurements revealed significant changes upon hydration in the structure functions of the copolymer. Large changes in the structure functions at ~ 10 days of incubation coincided with the large increase in the water uptake from ~1 to ~40% and the formation of voids in the film. Computer modeling based on the recently developed TIGER2/TIGER3 mixed sampling scheme was used to interpret these changes by efficiently equilibrating both dry and hydrated models of PDLLA. Realistic models of bulk amorphous PDLLA structure were generated as demonstrated by close agreement between the calculated and the experimental structure functions. These molecular simulations were used to identify the interactions between water and the polymer at the atomic level including the change of positional order between atoms in the polymer due to hydration. Changes in the partial O-O structure functions, about 95% of which were due to water-polymer interactions, were apparent in the radial distribution functions. These changes, and somewhat smaller changes in the C-C and C-O partial structure functions, clearly demonstrated the ability of the model to capture the hydrogen bonding interactions between water and the polymer, with the probability of water forming hydrogen bonds with the carbonyl oxygen of the ester group being about four times higher than with its ether oxygen. 相似文献
18.
Konkala Karnakar Katla Ramesh Sabbavarapu Narayana Murthy Yadavalli Venkata Durga Nageswar 《Helvetica chimica acta》2013,96(12):2276-2281
The first example of the stereoselective synthesis of (Z)‐ and (E)‐allyl aryl sulfides and selenides from Baylis? Hillman acetates under neutral conditions in H2O by supramolecular catalysis involving β‐cyclodextrin is reported. β‐Cyclodextrin can be recovered and reused. The reaction is very efficient in providing allyl aryl sulfides and selenides in good‐to‐excellent yields with clean reaction profiles under mild reaction conditions. 相似文献
19.
Dr. Xinghai Ning Dr. Wonewoo Seo Dr. Seungjun Lee Dr. Kiyoko Takemiya Dr. Mohammad Rafi Dr. Xuli Feng Dr. Daiana Weiss Dr. Xiaojian Wang Larry Williams Vernon M. Camp Malveaux Eugene Prof. W. Robert Taylor Prof. Mark Goodman Prof. Niren Murthy 《Angewandte Chemie (International ed. in English)》2014,53(51):14096-14101
A positron emission tomography (PET) tracer composed of 18F‐labeled maltohexaose (MH18F) can image bacteria in vivo with a sensitivity and specificity that are orders of magnitude higher than those of fluorodeoxyglucose (18FDG). MH18F can detect early‐stage infections composed of as few as 105 E. coli colony‐forming units (CFUs), and can identify drug resistance in bacteria in vivo. MH18F has the potential to improve the diagnosis of bacterial infections given its unique combination of high specificity and sensitivity for bacteria. 相似文献
20.
T. V. Beatriceveena A. Sree Rama Murthy S. Murugesan E. Prabhu K. I. Gnanasekar 《Angewandte Chemie (International ed. in English)》2020,59(6):2241-2245
Owing to a wide range of industrial applications and fundamental importance, delafossite compounds have gathered tremendous interest in research community. In this study, the formation of hexagonal nanoplates of AgInO2 mainly dominated by (00l) facets with no metallic Ag impurity, reported using a facile hydrothermal route at 180 °C using KOH as mineralizer by adopting a factorial design approach. Rietveld analysis of the powder XRD pattern and SAED confirms the rhombohedral system of AgInO2. FE‐SEM image shows a uniform hexagonal plate‐like morphology with an average width of about 300 nm and thickness of 70 nm. XPS and EDX analysis confirm potassium ion free AgInO2. A specific surface area of about 48.5 m2 g?1 is arrived from N2 adsorption studies. Temperature‐dependent AC impedance measurements revealed an activation energy of 0.24 eV/f.u. Further, TG‐DTA studies found that the compound is stable in air up to 595 °C. 相似文献