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121.
Mohammad A Hossain Sereyrath Ngeth Teddy Chan Michael N Oda Gordon A Francis 《BMC biochemistry》2012,13(1):1
Background
ATP-binding cassette transporter A1 (ABCA1) mediates the lipidation of exchangeable apolipoproteins, the rate-limiting step in the formation of high density lipoproteins (HDL). We previously demonstrated that HDL oxidized ex vivo by peroxidase-generated tyrosyl radical (tyrosylated HDL, tyrHDL) increases the availability of cellular cholesterol for efflux and reduces the development of atherosclerosis when administered to apolipoprotein E-deficient mice as compared to treatment with control HDL. 相似文献122.
The structural parameters with stability upon Si incorporation and elastic, electronic, thermodynamic and optical properties of Ti3Al1−xSixC2 (0≤x≤1) are investigated systematically by the plane wave pseudopotential method based on the density functional theory (DFT). The increase of some elastic parameters with increasing Si-content renders the alloys to possess higher compressive and tensile strength. The Vickers hardness value obtained with the help of Mulliken population analysis increases as x is increased from 0 to 1. The solid solutions considered are all metallic with valence and conduction bands, which have a mainly Ti 3d character, crossing the Fermi level. The temperature and pressure dependences of bulk modulus, normalized volume, specific heats, thermal expansion coefficient, and Debye temperature are all obtained through the quasi-harmonic Debye model with phononic effects for T=0−1000 K and P=0−50 GPa. The obtained results are compared with other results available. Further an analysis of optical functions for two polarization vectors reveals that the reflectivity is high in the visible–ultraviolet region up to ∼10.5 eV region showing promise as a good coating material. 相似文献
123.
Ningsih Z Hossain MA Wade JD Clayton AH Gee ML 《Langmuir : the ACS journal of surfaces and colloids》2012,28(4):2217-2224
The mechanism of interaction between a model antimicrobial peptide and phospholipid unilamellar vesicle membranes was studied using fluorescence spectroscopy, fluorescence lifetime measurements, and light scattering. The peptide, a mellitin mutant, was labeled at position K14 with the polarity-sensitive probe AlexaFluor 430. The kinetics of the interaction of this derivative with various concentrations of 1,2-dipalmitoyl-sn-glycero-3-phosphatidylcholine (DPPC) vesicles was examined. Our work unveiled two novel aspects of peptide-lipid interactions. First, the AB plot or phasor analysis of the fluorescence lifetime studies revealed at least three different peptide states, the population of which depended on the lipid to peptide (L:P) concentration ratio. Second, complex fluorescence kinetics were observed over extended time-scales from 30 s to 2 h. The extended kinetics was only observed at particular lipid concentrations (L:P ratios 20:1 and 10:1) and not at others (30, 40, 50 and 100:1 L:P ratio). Analysis of the complex kinetics revealed several intermediates. We assign these to distinct states of the peptide formed during helix insertion into the vesicle membrane that are intermediate to lytic pore formation. 相似文献
124.
Yoshinori Namihira Md. Anwar Hossain Taito Koga Md. Ashraful Islam S. M. Abdur Razzak Shubi F. Kaijage Yuki Hirako Hiroki Higa 《Optical Review》2012,19(2):78-81
In this paper, we propose a highly nonlinear dispersion flattened hexagonal photonic crystal fiber (HNDF-HPCF) with nonlinear
coefficients as large as 57.5W−1 km−1 at 1.31 μm wavelength for dental optical coherence tomography (OCT) applications. This HNDF-HPCF offers not only large nonlinear
coefficient but also very flat dispersion slope and very low confinement losses. Using these characteristics of our proposed
PCF, it is shown through simulations by using finite difference method with an anisotropic perfectly matched boundary layer
that this PCF offers the efficient supercontinuum (SC) generation for dental OCT applications at 1.31 μm wavelength using
a picosecond pulse easily produced by commercially available less expensive laser sources. Coherent length of light source
using SC is found 10 μm and the spatial resolutions in the depth direction for dental applications of OCT are found about
6.1 μm for enamel and 6.5 μm for dentin. 相似文献
125.
126.
We present a highly nonlinear non-circular core photonic crystal fiber (HNL-NCPCF) with all normal group velocity dispersion (GVD) to design a supercontinuum (SC) light source for optical coherence tomography (OCT) system. Nonlinear coefficient is increased as large as 66 W?1 km?1 at by reducing the effective mode area and core is made non-circular to increase birefringence by putting the square lattice of air-holes inside the silica host. About 85 nm 10 dB spectral bandwidths for 2.5 ps input optical pulse and 140 nm 10 dB spectral bandwidths for 1.0 ps input optical pulse have been observed using the same fiber length of 200 m and input optical power of 15 W. Coherent lengths of the generated supercontinuum light sources are found for 2.5 ps input optical pulse and for 1.0 ps input optical pulse. Therefore, the highest longitudinal resolution for dental OCT at is found about for tooth enamel. 相似文献
127.
Siddiquee S Cheong BE Taslima K Kausar H Hasan MM 《Journal of chromatographic science》2012,50(4):358-367
A simple, fast, repeatable and less laborious sample preparation protocol was developed and applied for the analysis of biocontrol fungus Trichoderma harzianum strain FA1132 by using gas chromatography-mass spectrometry. The match factors for sample spectra with respect to the mass spectra library of fungal volatile compounds were determined and used to study the complex hydrocarbons and other volatile compounds, which were separated by using different capillary columns with nonpolar, medium polar and high polar stationary phases. To date, more than 278 volatile compounds (with spectral match factor at least 90%) such as normal saturated hydrocarbons (C7-C30), cyclohexane, cyclopentane, fatty acids, alcohols, esters, sulfur-containing compounds, simple pyrane and benzene derivatives have been identified. Most of these compounds have not previously been reported. The method described in this paper is a more convenient research tool for the detection of volatile compounds from the cultures of T. harzianum. 相似文献
128.
H. R. H. Ali H. G. M. Edwards J. Kendrick T. Munshi I. J. Scowen 《Journal of Raman spectroscopy : JRS》2007,38(7):903-908
The Raman spectrum of budesonide is reported for the first time, and molecular assignments are proposed on the basis of ab initio BLYP DFT calculations with a 6‐31 G* basis set and vibrational wavenumbers predicted on a quasi‐harmonic approximation. Comparison with previously published infrared data has explained several spectral features, and the relative band intensities in the CO and CC stretching regions are interpreted. The results from this study provide data that can be used for the preparative process monitoring of budesonide, an important steroidal pharmaceutical in various dosage forms, and its interaction with excipients and other components. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
129.
Kazi Zakir Hossain Cristina T. Camagong Takaharu Honjo 《Analytical and bioanalytical chemistry》2001,369(6):543-545
A new method for the quantitative extraction and determination of trace amounts of iridium from hydrochloric acid media has been established based on the formation of an ion-association complex of iridium hexachloro anion IrCl6 2– with dicyclohexyl-18-crown-6 (DC18C6) oxonium cation in chloroform, then determination by inductively coupled plasma atomic emission spectrometry (ICP–AES). The effect of various factors (solvent, acid concentration, crown ether, reagent concentration, shaking time, composition of the extracted species, foreign ions, etc.) on the extraction and back-extraction of iridium has been investigated. The procedure was used to determine traces of iridium in palladium chloride and rhodium chloride. 相似文献
130.
A. H. Mahmoudi S. Hossain C. E. Truman D. J. Smith M. J. Pavier 《Experimental Mechanics》2009,49(4):595-604
Mechanical strain relief techniques for estimating the magnitude of residual stress work by measuring strains or displacements
when part of the component is machined away. The underlying assumption is that such strain or displacement changes result
from elastic unloading. Unfortunately, in components containing high levels of residual stress, elastic-plastic unloading
may well occur, particularly when the residual stresses are highly triaxial. This paper examines the performance of one mechanical
strain relief technique particularly suitable for large section components, the deep hole drilling (DHD) technique. The magnitude
of error is calculated for different magnitudes of residual stress and can be substantial for residual stress states close
to yield. A modification to the technique is described to allow large magnitudes of residual stress to be measured correctly.
The new technique is validated using the case of a quenched cylinder where use of the standard DHD technique leads to unacceptable
error. The measured residual stresses using the new technique are compared with the results obtained using the neutron diffraction
technique and are shown to be in excellent agreement. 相似文献